silver benzimidazole | 42880-01-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: silver benzimidazole
• 英文别名: [Ag(Benz-im)]；[Ag(1H-benzimidazole(-H))]；1H-benzimidazole; silver-salt；1H-Benzimidazol; Silber-Salz；Silver;benzimidazol-1-ide
• CAS: 42880-01-3
• 化学式: C₇H₅AgN₂
• 分子量: 224.998
• InChiKey: IWQFMSXYOSAMAZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.19
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  13.9
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  silver benzimidazole 在 碘 作用下， 以 苯 为溶剂， 反应 18.0h， 生成 1-iodobenzimidazole
  参考文献：
  名称：

  NN连接的联唑。第2部分。尝试连接苯并咪唑-1-基的方法。2,2'-二甲基-1,1'-联苯并咪唑的合成

  摘要：

  据报道，通过在2,2'-偶氮苯胺上连续两次杂环化，合成了1,1'-联苯并咪唑（2； R = Me）。通过适当的N-取代的苯并咪唑类化合物直接形成N-N键而形成（2）的替代方法是不成功的。二聚体（2）表现出极强的热和光化学稳定性，对氢的提取和向烯烃的添加均具有稳定性。尽管N–N键很容易在乙醇中被辐射裂解，但从（2）中检测中性自由基苯并咪唑-1-基（1; R = Me）的所有尝试均未成功。但是，以1-碘代苯并咪唑为前体观察到了由（1）提取的氢。

  DOI：

  10.1039/p19810000403
• 作为产物：
  描述：

  苯并咪唑 、 [Ag₂(9-aca)₂] 以 甲醇 为溶剂， 反应 0.5h， 以68%的产率得到silver benzimidazole
  参考文献：
  名称：

  Synthesis, structure and biological activity of silver(I) complexes of substituted imidazoles

  摘要：

  [Ag-2(9-aca)(2)] (9-acaH = 9-anthracenecarboxylic acid) interacts with DMSO and a selection of substituted imidazoles giving [Ag-4(DMSO)(4)(9-aca)(4)] (1), [Ag(2-Me-imH)(2)(9-aca)] (2), [Ag(4-Ph-imH)(2)(9-aca)] (3), [Ag(2-Mebenz-imH)2(()9-aca)] (4), [Ag(2-Mebenz-im)] (6), [Ag(Benz-im)] (7), [Ag(2-Ph-im)] (8) and [Ag(4,5-CN-im)] (9) (2-Me-imH = 2-methylimidazole; 4-Ph-imH = 4-phenylimidazole; 2-Mebenz-imH = 2-methylbenzimidazole; Benz-imH = benzimidazole; 2-Ph-imH = 2-phenylbenzimidazole; 4,5-CN-imH = 4,5-dicyanoimidazole). In the carboxylate/imidazole complexes 2-4, the imidazole ligand is in the neutral form, whilst in complexes 6-9 the imidazolate ligand is deprotonated and no carboxylate ligand is present. Attempted recrystallization of 4 from EtOH gives the metal-free, imidazolium salt, 2-Mebenz-imH(2))(9-aca)center dot H2O (5). The X-ray crystal structures of complexes 1 and 2 and the salt 5 were determined. Antimicrobial screening showed that the Ag(l) complexes were substantially more active against the fungus Candida albicans than the bacterial species, methicillin-resistant Staphylococcus aureus (MRSA) and Escherichia coli. Some of the complexes offer a good prognosis for Galleria mellonella (larvae of the greater wax moth) infected with a lethal dose of C. albicans cells. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.03.057
• 作为试剂：
  描述：

  silver benzimidazole 在 碘 、 silver benzimidazole 作用下， 以 苯 为溶剂， 反应 22.0h， 生成 1-(3-methylbenzyl)benzimidazole
  参考文献：
  名称：

  NN连接的联唑。第2部分。尝试连接苯并咪唑-1-基的方法。2,2'-二甲基-1,1'-联苯并咪唑的合成

  摘要：

  据报道，通过在2,2'-偶氮苯胺上连续两次杂环化，合成了1,1'-联苯并咪唑（2； R = Me）。通过适当的N-取代的苯并咪唑类化合物直接形成N-N键而形成（2）的替代方法是不成功的。二聚体（2）表现出极强的热和光化学稳定性，对氢的提取和向烯烃的添加均具有稳定性。尽管N–N键很容易在乙醇中被辐射裂解，但从（2）中检测中性自由基苯并咪唑-1-基（1; R = Me）的所有尝试均未成功。但是，以1-碘代苯并咪唑为前体观察到了由（1）提取的氢。

  DOI：

  10.1039/p19810000403

文献信息

• Ligand effects on the structural dimensionality and antibacterial activities of silver-based coordination polymers
  作者：Xinyi Lu、Junwei Ye、Yuan Sun、Raji Feyisa Bogale、Limei Zhao、Peng Tian、Guiling Ning

  DOI：10.1039/c4dt00270a

  日期：——

  Four Ag-based coordination polymers [Ag(Bim)] (1), [Ag2(NIPH)(HBim)] (2), [Ag6(4-NPTA)(Bim)4] (3) and [Ag2(3-NPTA)(bipy)0.5(H2O)] (4) (HBim = 1H-benzimidazole, bipy = 4,4′-bipyridyl, H2NIPH = 5-nitroisophthalic acid, H2NPTA = 3-/4-nitrophthalic acid) have been synthesized by hydrothermal reaction of Ag(I) salts with N-/O-donor ligands. Single-crystal X-ray diffraction indicated that these coordination polymers constructed from mononuclear or polynuclear silver building blocks exhibit three typical structure features from 1-D to 3-D frameworks. These compounds favour a slow release of Ag+ ions leading to excellent and long-term antimicrobial activities, which is distinguished by their different topological structures, towards both Gram-negative bacteria, Escherichia coli (E. coli) and Gram-positive bacteria, Staphylococcus aureus (S. aureus). In addition, these compounds show good thermal stability and light stability under UV-vis and visible light, which are important characteristics for their further application in antibacterial agents.

  四种基于银的配位聚合物[Ag(Bim)] (1)、[Ag2(NIPH)(HBim)] (2)、[Ag6(4-NPTA)(Bim)4] (3)和[Ag2(3-NPTA)(bipy)0.5(H2O)] (4)（HBim = 1H-苯并咪唑，bipy = 4,4′-联吡啶，H2NIPH = 5-硝基间苯二甲酸，H2NPTA = 3-/4-硝基邻苯二甲酸）是通过银（I）盐与N-/O-供体配体的水热反应合成的。单晶X射线衍射表明，这些由单核或多核银构建的配位聚合物具有从1-D到3-D框架的三个典型结构特征。这些化合物有利于Ag+离子的缓慢释放，从而对革兰氏阴性细菌大肠杆菌（E. coli）和革兰氏阳性细菌金黄色葡萄球菌（S. aureus）表现出优异的长期抗菌活性，这是由它们不同的拓扑结构决定的。此外，这些化合物在紫外可见光和可见光下具有良好的热稳定性和光稳定性，这是它们进一步应用于抗菌剂的重要特征。
• Prolonging the lifetimes of plasmonic hot electrons for efficient hydrogen evolution by Ag@N,O-C interfaces with a unique ginkgo-leaf hierarchical structure
  作者：Yun Yang、Guilin Zhuang、Liming Sun、Xibo Zhang、Xiaoqin Yan、Wenwen Zhan、Xiaojun Wang、Xiguang Han

  DOI：10.1039/d0ta06308h

  日期：——

  N,O-doped C layers fully-coated Ag nanoparticles have assembled to form into a three-level hierarchical structure, which have shown highly-improved photocatalytic activity toward hydrogen production reaction from water.

  掺氮氧化物的C层完全包覆银纳米颗粒，组装成三层分级结构，表现出对水中氢产生反应具有高度改进的光催化活性。
• Borate compound, and photopolymerizable composition and recording material which contain the same
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP1035124A1

  公开（公告）日：2000-09-13

  The present invention provides a novel borate compound and a recording material comprising thereof in a photopolymerizable composition in a recording layer. The novel borate compound is represented by the following general formula (I): General formula (I) wherein R1 represents an alkyl group which may have a substituent; R2, R3 and R4 each represents an aryl group represented by the following general formula (II); and Z+ represents a group capable of forming a cation, General formula (II) wherein R5 represents an electron donative group; and R6 to R9 each represents a substituent, the total Hammett substituent σ constant of R5 to R9 being from 0 to 1.

  本发明提供了一种新型硼酸盐化合物和一种记录材料，在记录层中的可光聚合组合物中含有该化合物。新型硼酸盐化合物由以下通式（I）表示： 通式（I） 其中 R1 代表可具有取代基的烷基；R2、R3 和 R4 分别代表由以下通式（II）表示的芳基；Z+ 代表可形成阳离子的基团、 通式 (II) 其中 R5 代表一个电子捐赠基团；R6 至 R9 各代表一个取代基，R5 至 R9 的总 Hammett 取代基 σ 常数为 0 至 1。
• Photopolymerizable composition, recording material and image forming method
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：US20030077542A1

  公开（公告）日：2003-04-24

  A photopolymerizable composition and a recording material containing the composition. The composition include at least a radical-polymerizable compound and a photopolymerization initiator, in which the photopolymerization initiator contains a borate compound, having a melting point of not more than 140° C., of the following general formula (I) in which R 1 , R 2 , R 3 and R 4 each independently represent an alkyl group, aryl group, heterocyclic group, or silyl group; and Z + represents a cation. 1

  一种可光聚合的组合物和含有该组合物的记录材料。该组合物至少包括一种可自由基聚合的化合物和一种光聚合引发剂，其中光聚合引发剂包含一种硼酸盐化合物，熔点不超过 140 摄氏度，其通式如下（I），其中 R 1 , R 2 , R 3 和 R 4 各自独立地代表烷基、芳基、杂环基或硅烷基；以及 Z 代表阳离子； 代表阳离子。 1
• Hoffmann, Siegfried; Hartung, Klaus-Juergen; Hanh, Nguyen thi, Zeitschrift fur Chemie, 1986, vol. 26, # 3, p. 105 - 106
  作者：Hoffmann, Siegfried、Hartung, Klaus-Juergen、Hanh, Nguyen thi、Mewes, Reinhard、Baluzow, Wenelin

  DOI：——

  日期：——