(undec-10-en-1-yl) methyl malonate | 1582276-29-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (undec-10-en-1-yl) methyl malonate
• 英文别名: 1-O-methyl 3-O-undec-10-enyl propanedioate
• CAS: 1582276-29-6
• 化学式: C₁₅H₂₆O₄
• 分子量: 270.369
• InChiKey: GHXCCBPGHQVEQO-UHFFFAOYSA-N

物化性质

• 沸点：
  321.6±15.0 °C(predicted)
• 密度：
  0.971±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  19
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  (undec-10-en-1-yl) methyl malonate 、 足球烯 在 四溴化碳 、 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 甲苯 为溶剂， 反应 0.08h， 以59%的产率得到{1-methoxycarbonyl-1-[(undec-10-enyloxy)carbonyl]-1,2-methano}-1,2-dihydro-C₆₀-fullerene
  参考文献：
  名称：

  New monomers for fullerene-containing polymers

  摘要：

  By reaction of 2-(acryloyloxyethyl) and (undecen-10-en-1-yl) methylmalonates with fullerene C-60 in the system toluene-CBr4-DBU, and also by reaction of 2-(2,2-dichloroacetoxy)ethyl acrylate with C-60 in the system toluene-DBU the corresponding products of fullerene monocyclopropanation were synthesized.

  DOI：

  10.1134/s1070428014020067
• 作为产物：
  描述：

  10-十一烯-1-醇 、 丙二酸甲酯酰氯 在 吡啶 作用下， 以78%的产率得到(undec-10-en-1-yl) methyl malonate
  参考文献：
  名称：

  New monomers for fullerene-containing polymers

  摘要：

  By reaction of 2-(acryloyloxyethyl) and (undecen-10-en-1-yl) methylmalonates with fullerene C-60 in the system toluene-CBr4-DBU, and also by reaction of 2-(2,2-dichloroacetoxy)ethyl acrylate with C-60 in the system toluene-DBU the corresponding products of fullerene monocyclopropanation were synthesized.

  DOI：

  10.1134/s1070428014020067

文献信息

• New monomers for fullerene-containing polymers
  作者：S. A. Torosyan、Yu. N. Biglova、V. V. Mikheev、F. A. Gimalova、A. G. Mustafin、M. S. Miftakhov

  DOI：10.1134/s1070428014020067

  日期：2014.2

  By reaction of 2-(acryloyloxyethyl) and (undecen-10-en-1-yl) methylmalonates with fullerene C-60 in the system toluene-CBr4-DBU, and also by reaction of 2-(2,2-dichloroacetoxy)ethyl acrylate with C-60 in the system toluene-DBU the corresponding products of fullerene monocyclopropanation were synthesized.