3-n-Propyl-hex-2-en-saeure | 59117-27-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 3-n-Propyl-hex-2-en-saeure
• 英文别名: 3-Propylhex-2-enoic acid
• CAS: 59117-27-0
• 化学式: C₉H₁₆O₂
• mdl: MFCD01723183
• 分子量: 156.225
• InChiKey: LMCKTTNJLDJGTQ-UHFFFAOYSA-N

物化性质

• 熔点：
  9 °C
• 沸点：
  144 °C(Press: 17 Torr)
• 密度：
  0.93624 g/cm3(Temp: 20.0 °C)

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  11
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.666
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-n-Propyl-hex-2-en-saeure 、 alkaline earth salt of/the/ methylsulfuric acid 生成 4-庚酮
  参考文献：
  名称：

  Linstead; May, Journal of the Chemical Society, 1927, p. 2572

  摘要：

  DOI：
• 作为产物：
  描述：

  3-Hydroxy-3-n-propyl-hexansaeure 在 乙酸酐 作用下， 生成 3-n-Propyl-hex-2-en-saeure
  参考文献：
  名称：

  二丙乙酸系列、C8和C9支链乙烯酸和酰胺的研究

  摘要：

  制备2-丙基-2-戊烯酸。使用 ASIS 效应确定其立体化学。一些N-取代的2-溴-2,2-二丙基-乙酰胺经N,N-二乙基苯胺脱卤得到相应的不饱和酰胺。这些化合物的构型是根据与三（二新戊酰基甲烷）铕[Eu (DPM) 3] 络合和未络合而获得的 NMR 数据进行讨论的。

  DOI：

  10.1002/ardp.19773100509

文献信息

• Acetic acid derivatives having pharmacological activity and compositions
  申请人：Labaz

  公开号：US04025649A1

  公开（公告）日：1977-05-24

  Acetic acid derivatives of the formula: ##STR1## and pharmaceutically acceptable alkali metal salts thereof, wherein R represents the radical ##STR2## in which R.sub.1 and R.sub.2, which may be the same or different, each represent an alkyl radical having from 1 to 4 carbon atoms, R.sub.3 represents a hydrogen atom or a methyl radical and n is an integer in the range of from 0 to 3 inclusive. They possess a competitive inhibitory activity with respect to .gamma.-aminobutyric .alpha.-ketoglutaric transaminase as well as antianoxic and anticonvulsant properties and they are useful for treating central neurological disorders whether resulting or not from cerebral ischemia.

  乙酸衍生物的化学式为：##STR1##及其在药学上可接受的碱金属盐，其中R代表基团##STR2##其中R.sub.1和R.sub.2，可以相同也可以不同，每个代表具有1至4个碳原子的烷基基团，R.sub.3代表氢原子或甲基基团，n是在0至3范围内的整数。它们具有相对于γ-氨基丁酸α-酮戊二酸转氨酶的竞争性抑制活性，以及抗缺氧和抗抽搐特性，可用于治疗中枢神经系统疾病，无论是由脑缺血引起还是其他原因。
• Process for Preparing an Overbased Detergent
  申请人：Kocsis A. Jody

  公开号：US20060178278A1

  公开（公告）日：2006-08-10

  The invention relates to a process for preparing an overbased metal detergent in an oil medium comprising the steps of: (1) providing a metal salt selected from the group consisting of a hydrocarbyl-substituted organic acid; a hydrocarbyl-substituted phenol, a phenate, a hydrocarbyl-substituted carboxylate and mixtures thereof; (2) further providing methanol and a mixture of alcohols containing 2 to about 7 carbon atoms, wherein the mole ratio of methanol to the mixture of alcohols is about 2.2 or less, to form a mixture; (3) further providing a basic metal compound; (4) reacting the mixture of step (3) with carbon dioxide to form a carbonated overbased metal sulphonate; (5) performing steps (3) and (4) at least three additional times upon the product of step (4); (6) thereafter removing at least a portion of the water produced in steps (1)-(5) and of the alcohols introduced in step (2); (7) performing step (2) again, upon the product of step (6); (8) performing steps (3) and (4) at least two additional times upon the product of step (7); and (9) thereafter removing a substantial portion of the water and of the alcohols from the composition; wherein the oil medium is present in an amount such that the weight ratio of the acid corresponding to the metal salt of (1) to the oil medium is 0.3 to 1.4; and wherein step (6) is required when the hydrocarbyl-substituted organic acid is a hydrocarbyl-substituted sulphonic acid. The invention further relates to its use in internal combustion engines.

  该发明涉及一种在油介质中制备过基金属清洁剂的方法，包括以下步骤：（1）提供一种选自羟烃基取代有机酸、羟烃基取代酚、酚酸盐、羟烃基取代羧酸盐及其混合物的金属盐；（2）进一步提供甲醇和含有2至约7个碳原子的醇混合物，其中甲醇与醇混合物的摩尔比约为2.2或更低，形成混合物；（3）进一步提供一种碱性金属化合物；（4）将步骤（3）的混合物与二氧化碳反应，形成碳酸盐过基金属磺酸盐；（5）对步骤（4）的产物至少进行三次以上的步骤（3）和（4）；（6）随后至少去除步骤（1）至（5）中产生的部分水和步骤（2）中引入的醇；（7）对步骤（6）的产物再次执行步骤（2）；（8）对步骤（7）的产物至少进行两次以上的步骤（3）和（4）；（9）随后从组合物中去除大部分水和醇；其中油介质的量使得步骤（1）中金属盐对应的酸与油介质的重量比为0.3至1.4；当羟烃基取代有机酸为羟烃基取代磺酸时，需要步骤（6）。该发明还涉及该方法在内燃机中的应用。
• Slipping property imparting agent for clear coating and clear coating paper having the agent applied thereon
  申请人：Ono Hiroshi

  公开号：US20050176908A1

  公开（公告）日：2005-08-11

  Produce a slipping property imparting agent for clear coat that reduces scum production: wherein, (1) the agent comprises a copolymer whose constituents are unsaturated olefin (constituent (a)) and unsaturated carboxylic acid (carboxylate) (constituent (b)); (2) constituent (a) accounts for 50 to 99 mol percent and constituent (b) accounts for 50 to 1 mol percent, respectively, of the total mol number of constituents (a) and (b) combined; and (3) a constituent (c) that can be polymerized with the constituents (a) and (b) is contained, as necessary, by up to 20 mol percent of the total mol number of constituents (a) and (b) combined.

  生产一种可减少浮渣产生的透明涂层滑爽性赋予剂：其中，(1)该剂包括一种共聚物，其成分为不饱和烯烃（成分(a)）和不饱和羧酸（羧酸盐）（成分(b)）；(2)成分(a)分别占成分(a)和(b)总和摩尔数的50%至99%，成分(b)分别占50%至1%；(3) 可与成分(a)和(b)聚合的成分(c)必要时最多占成分(a)和(b)总摩尔数的 20%。
• Agents containing carboxylic acid and the use of the same in plant cultivation
  申请人：Kober Reiner

  公开号：US20060100105A1

  公开（公告）日：2006-05-11

  The present invention relates to carboxylic-acid-comprising compositions based on bioregulatory active ingredients from the triazole class and to their use as bioregulator in plant cultivation.

  本发明涉及以三唑类生物调节活性成分为基础的羧酸成分组合物及其在植物栽培中作为生物调节剂的用途。
• Carbonyl Homologation via β-Trimethylsilyl β-Lactone Rearrangements. A Nonbasic Alternative to the Wittig Reaction
  作者：T. Howard Black、Yong Zhang、Jianhua Huang、Douglas C. Smith、Bryan E. Yates

  DOI：10.1080/00397919508010783

  日期：1995.1

  Saturated and unsaturated aldehydes and ketones, when treated with trimethylsilylketene and BF3 for 16 hours, form beta-lactones which spontaneously rearrange to alpha, beta-unsaturated TMS esters; these hydrolyze during workup to form the corresponding carboxylic acids.