2-[4-[(E)-2-[4,6-二(三氯甲基)-1,3,5-三嗪-2-基]乙烯基]苯氧基]乙醇 | 79771-30-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 中文名称: 2-[4-[(E)-2-[4,6-二(三氯甲基)-1,3,5-三嗪-2-基]乙烯基]苯氧基]乙醇
• 英文名称: 2,4-bis(trichloromethyl)-6-[4-(2-hydroxyethoxy)styryl]-1,3,5-triazine
• 英文别名: 2,4-bis(trichloromethyl)-6-[p-(2-hydroxyethoxy)styryl]-1,3,5-triazine；Ethanol, 2-(4-(2-(4,6-bis(trichloromethyl)-1,3,5-triazin-2-yl)ethenyl)phenoxy)-；2-[4-[(E)-2-[4,6-bis(trichloromethyl)-1,3,5-triazin-2-yl]ethenyl]phenoxy]ethanol
• CAS: 79771-30-5
• 化学式: C₁₅H₁₁Cl₆N₃O₂
• 分子量: 477.989
• InChiKey: DYNCQGWLQDAERY-ZZXKWVIFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  26
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  68.1
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  2,4-双(三氯甲基)-6-甲基-1,3,5-三嗪 、 4-(2-羟基乙氧基)苯甲醛 在 乙酸铵 作用下， 以 甲醇 为溶剂， 生成 2-[4-[(E)-2-[4,6-二(三氯甲基)-1,3,5-三嗪-2-基]乙烯基]苯氧基]乙醇
  参考文献：
  名称：

  Migration-resistant halomethyl-1,3,5-triazine photoinitiator

  摘要：

  一种含色团取代卤甲基-1,3,5-三嗪光聚合引发剂。该引发剂最好由三个分子组成-含羟基取代、含色团取代、卤甲基-1,3,5-三嗪化合物的残基；具有不同反应性的异氰酸酯化合物残基；羟基取代化合物的残基，例如聚氧乙烯烷基酚的残基。

  公开号：

  US05484919A1

文献信息

• POLYMERIZABLE COMPOSITION FOR COLOR FILTER, COLOR FILTER, AND SOLID-STATE IMAGING DEVICE
  申请人：Shimada Kazuto

  公开号：US20110217637A1

  公开（公告）日：2011-09-08

  A polymerizable composition for a color filter, including (A) a polymerizable compound, (B) a polymerization initiator, (C) a coloring agent, and (D) a polymer including at least a group having polymerization inhibiting ability and a group having surface localizability.

  一种可聚合的彩色滤光片组合物，包括（A）一种可聚合化合物，（B）一种聚合引发剂，（C）一种着色剂和（D）至少包括具有聚合抑制能力和表面定位能力的基团的聚合物。
• Halomethyl-1,3,5-triazines containing a monomeric moiety
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0359430A2

  公开（公告）日：1990-03-21

  The present invention relates to photosensitive compound, more particularly, derivatives of halomethyl-1,3,5-triazines. Halomethyl-1,3,5-triazines are known to be initiators for a number of photochemical reactions. They are employed to produce free radicals for initiating polymerization or color changes and for initiating secondary reactions upon liberation of acid by the interaction of the free-radicals when hydrogen donors are present. It would be desirable to provide a photopolymerizable monomeric compound that does not require a separate photoinitator to initiate polymerization of the compound. This invention provides radiation-sensitive organo-halogen compounds having a photo-labile halomethyl-1,3,5-triazine moiety and at least one polymerizable moiety within one molecule. The compounds of this invention have at least one halomethyl substituent attached to a carbon atom of the triazine moiety and at least one polymerizable monomeric moiety attached to another atom of the triazine moiety. The compounds of this invention can be used to prepare polymers having 1,3,5-triazine substituents attached thereto. The compounds of this invention are good photoinitiators, and compositions containing them can be used in printing, duplicating, copying, and other imaging systems. The compounds of this invention are capable of stimulation by actinic radiation at a wavelength of about 250 to 900 nanometers to generate free radicals.

  本发明涉及光敏化合物，特别是卤甲基-1,3,5-三嗪的衍生物。 众所周知，卤甲基-1,3,5-三嗪是许多光化学反应的引发剂。它们被用来产生自由基，以引发聚合或颜色变化，并在有氢供体存在时，通过自由基的相互作用释放出酸，从而引发二级反应。 最好能提供一种不需要单独的光引发剂来引发化合物聚合的可光聚合单体化合物。 本发明提供了对辐射敏感的有机卤素化合物，在一个分子中具有光致弱的卤甲基-1,3,5-三嗪分子和至少一个可聚合分子。本发明的化合物至少有一个卤甲基取代基连接在三嗪分子的一个碳原子上，至少有一个可聚合单体连接在三嗪分子的另一个原子上。 本发明的化合物可用于制备具有 1,3,5-三嗪取代基的聚合物。本发明的化合物是良好的光引发剂，含有这些化合物的组合物可用于印刷、复制、复印和其他成像系统。本发明的化合物能够在波长约为 250 至 900 纳米的光辐射刺激下产生自由基。
• Polymers containing halomethyl-1,3,5-triazine moieties
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0441524A2

  公开（公告）日：1991-08-14

  The present invention relates to photosensitive compounds, more particularly polymers containing halomethyl-1,3,5-triazine moieties and to radiation-sensitive compositions and elements utilizing these polymers. Migration typically occurs in photopolymerizable compositions containing low molecular weight monomers and plasticizers, which tend to diffuse between layers, carrying along other ingredients such as the photoinitiator. This invention provides radiation-sensitive organo-halogen compounds that have a photo-labile halomethyl-1,3,5-triazine moiety and a polymeric moiety within the same molecule. The compounds of this invention are comprised of a polymeric moiety having attached or incorporated within its structure at least one 1,3,5-triazine nucleus, said triazine nucleus having at least one halomethyl substituent attached to a carbon atom of the triazine nucleus. These compounds are capable of being stimulated by actinic radiation at wavelengths of from about 250 to about 900 nanometers to generate free radicals and/or acids. The compounds of this invention are useful as photoinitiators in free radical polymerization reactions, oxidation-reduction reactions, or reactions sensitive to acid, and they also exhibit the capability to crosslink upon exposure to light. The polymers of this invention are less susceptible to migration on account of the anchoring or ballasting of the halomethyl-1,3,5-triazine.

  本发明涉及光敏化合物，特别是含有卤代甲基-1,3,5-三嗪分子的聚合物，以及利用这些聚合物的辐射敏感组合物和元件。迁移通常发生在含有低分子量单体和增塑剂的可光聚合组合物中，这些单体和增塑剂容易在层间扩散，并携带光引发剂等其他成分。本发明提供了对辐射敏感的有机卤素化合物，这些化合物在同一分子中具有光敏卤甲基-1,3,5-三嗪分子和聚合分子。本发明的化合物由聚合分子组成，聚合分子的结构中连接或包含至少一个 1,3,5-三嗪核，所述三嗪核的碳原子上连接有至少一个卤代甲基。这些化合物能够在波长为 250 纳米到 900 纳米的光辐射刺激下生成自由基和/或酸。本发明的化合物在自由基聚合反应、氧化还原反应或对酸敏感的反应中可用作光引发剂，它们还能在光照下交联。由于卤甲基-1,3,5-三嗪的锚定或压载作用，本发明的聚合物不易迁移。
• High speed aqueous solvent developable photopolymer compositions
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0500321A1

  公开（公告）日：1992-08-26

  Novel photosensitive compositions based on azlactone derived polymers are described. The polymers have a hydrocarbyl backbone and pendant peptide groups with free-radically polymerizable functionality attached thereto, said polymer further comprising at least one oxyacid group or salt thereof, and optionally quaternary ammonium salt groups. A high speed durable printing plate having a mild pH aqueous developability is disclosed which incorporates these polymers in combination with a photoinitiator. The polymers are also useful as proofing films in graphic arts applications.

  本文描述了基于氮内酯衍生聚合物的新型光敏组合物。这些聚合物具有烃基骨架和附有可自由基聚合官能团的悬垂肽基，所述聚合物还包括至少一个氧酸基团或其盐，以及可选的季铵盐基团。本发明公开了一种具有温和 pH 值水性显影能力的高速耐久印版，它将这些聚合物与光引发剂结合在一起。这些聚合物还可用作图形艺术应用中的打样薄膜。
• Processed pigment, pigment-dispersed composition, colored photosensitive composition, color filter, liquid crystal display element, and solid image pickup element
  申请人：FUJIFILM Corporation

  公开号：EP2048539A1

  公开（公告）日：2009-04-15

  Provided are a processed pigment excellent in dispersibility and dispersion stability, a pigment-dispersed composition excellent in dispersibility and dispersion stability of a pigment that uses the processed pigment, a colored photosensitive composition using the pigment-dispersed composition, and a color filter having improved color properties that uses the colored photosensitive composition, in which a pigment is covered with at least one of a specific polymer compound selected from the following (SP-1) to (SP-3); (SP-1) A polymer compound having a heterocycle on a side chain, (SP-2) A graft polymer compound having a weight average molecular weight of from 1,000 to 100000, (SP-3) A polymer compound represented by the following formula (3-1), wherein, RC , RD, A1 and P1 respectively represent an organic linkage group, a single bond or a divalent organic linkage group, a monovalent organic group containing such as an organic dye structure, and a polymer skeleton.

  本发明提供了一种分散性和分散稳定性优异的加工颜料、一种使用该加工颜料的分散性和分散稳定性优异的颜料分散组合物、一种使用该颜料分散组合物的彩色感光组合物以及一种使用该彩色感光组合物的颜色特性得到改善的滤色片，其中，颜料被至少一种选自以下(SP-1)至(SP-3)的特定高分子化合物覆盖； (SP-1) 侧链上有杂环的聚合物化合物、 (SP-2) 一种接枝聚合物化合物，其重量平均分子量为 1,000 至 100000、 (SP-3) 下式(3-1)所代表的聚合物化合物、 其中，RC、RD、A1 和 P1 分别代表有机连接基团、单键或二价有机连接基团、含有诸如有机染料结构的一价有机基团和聚合物骨架。