6,6',6''-(((2,4,6-trimethylbenzene-1,3,5-triyl)tris(methylene))tris(oxy))tris(hexan-1-ol) | 911854-34-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 6,6',6''-(((2,4,6-trimethylbenzene-1,3,5-triyl)tris(methylene))tris(oxy))tris(hexan-1-ol)
• 英文别名: 6-[[3,5-Bis(6-hydroxyhexoxymethyl)-2,4,6-trimethylphenyl]methoxy]hexan-1-ol；6-[[3,5-bis(6-hydroxyhexoxymethyl)-2,4,6-trimethylphenyl]methoxy]hexan-1-ol
• CAS: 911854-34-7
• 化学式: C₃₀H₅₄O₆
• 分子量: 510.755
• InChiKey: PWDVZLZZLWVZOT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  36
• 可旋转键数：
  24
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  88.4
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  6,6',6''-(((2,4,6-trimethylbenzene-1,3,5-triyl)tris(methylene))tris(oxy))tris(hexan-1-ol) 在 18-冠醚-6 、 potassium carbonate 、 三乙胺 作用下， 以 二氯甲烷 、 丁酮 为溶剂， 反应 20.0h， 生成 [4-[6-[[3,5-Bis[6-(4-diphenylphosphanylphenoxy)hexoxymethyl]-2,4,6-trimethylphenyl]methoxy]hexoxy]phenyl]-diphenylphosphane
  参考文献：
  名称：

  Novel 3D Coordination Palladium−Network Complex:  A Recyclable Catalyst for Suzuki−Miyaura Reaction^†

  摘要：

  A novel solid-phase 3D metal-organic coordination network catalyst was prepared via self-assembly from PdCl2(CH3CN)(2) and a trisphosphine hub with three flexible alkyl-chain linkers. This insoluble network complex efficiently catalyzed the Suzuki-Miyaura reaction under atmospheric conditions in water. This catalyst was reused without loss of catalytic activity.

  DOI：

  10.1021/ol0615026
• 作为产物：
  描述：

  2,4,6-三溴甲基三甲基苯 在 sodium hydride 、 对甲苯磺酸 作用下， 以 四氢呋喃 、 甲醇 为溶剂， 反应 30.0h， 生成 6,6',6''-(((2,4,6-trimethylbenzene-1,3,5-triyl)tris(methylene))tris(oxy))tris(hexan-1-ol)
  参考文献：
  名称：

  Novel 3D Coordination Palladium−Network Complex:  A Recyclable Catalyst for Suzuki−Miyaura Reaction^†

  摘要：

  A novel solid-phase 3D metal-organic coordination network catalyst was prepared via self-assembly from PdCl2(CH3CN)(2) and a trisphosphine hub with three flexible alkyl-chain linkers. This insoluble network complex efficiently catalyzed the Suzuki-Miyaura reaction under atmospheric conditions in water. This catalyst was reused without loss of catalytic activity.

  DOI：

  10.1021/ol0615026

文献信息

• Novel 3D Coordination Palladium−Network Complex:  A Recyclable Catalyst for Suzuki−Miyaura Reaction^†
  作者：Yoichi M. A. Yamada、Yasunari Maeda、Yasuhiro Uozumi

  DOI：10.1021/ol0615026

  日期：2006.9

  A novel solid-phase 3D metal-organic coordination network catalyst was prepared via self-assembly from PdCl2(CH3CN)(2) and a trisphosphine hub with three flexible alkyl-chain linkers. This insoluble network complex efficiently catalyzed the Suzuki-Miyaura reaction under atmospheric conditions in water. This catalyst was reused without loss of catalytic activity.