triphenylene-2-carboxamide | 859323-17-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: triphenylene-2-carboxamide
• 英文别名: Triphenylen-2-carbamid；Triphenylene-2-carboxamide
• CAS: 859323-17-4
• 化学式: C₁₉H₁₃NO
• 分子量: 271.318
• InChiKey: WYMKZGLJRSZREN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  21
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  43.1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  甲醇 、 triphenylene-2-carboxamide 在 sodium hypobromide 作用下， 生成 triphenylen-2-yl-carbamic acid methyl ester
  参考文献：
  名称：

  Barker et al., Journal of the Chemical Society, 1955, p. 4482,4484

  摘要：

  DOI：
• 作为产物：
  描述：

  Triphenylene-2-carboxylic acid chloride 在 ammonium hydroxide 作用下， 生成 triphenylene-2-carboxamide
  参考文献：
  名称：

  Barker et al., Journal of the Chemical Society, 1955, p. 4482,4484

  摘要：

  DOI：

文献信息

• Hopff; Ohlinger, Angewandte Chemie, 1949, vol. 61, p. 183
  作者：Hopff、Ohlinger

  DOI：——

  日期：——
• POLYMER COMPLEX HAVING CHANNELS AND METHOD FOR CHEMICALLY MODIFYING INNER SURFACES OF CHANNELS OF POLYMER COMPLEX
  申请人：Fujita Makoto

  公开号：US20100324249A1

  公开（公告）日：2010-12-23

  The present invention is to provide a method for chemically modifying the inner surfaces of channels capable of further regulating characteristics of the internal environment of channels, by forming a polymer complex having a specific channel group B, the channel environmental characteristics of which are regulated by a specific substituent A, followed by utilizing the channels of the channel group B as a reaction field to convert the substituent A to a different substituent, and also to provide a polymer complex having highly specific channel environmental characteristics obtained by the chemical modification method. A method for chemically modifying inner surfaces of channels of at least one kind of channel group in a polymer complex provided with two or more kinds of channel groups each composed of channels identical with one another and having inherent affinity for a guest molecule, wherein the polymer complex comprises an aromatic compound; has two or more coordinating sites as a ligand, a metal ion as a central metal, and an uncoordinating aromatic compound, has a three-dimensional lattice-like structure containing a stack structure comprising the uncoordinating aromatic compound intercalated between aromatic compound ligands in a three-dimensional coordination network formed by coordinating the aromatic compound ligands to the central metal ion, and is provided with two or more kinds of the channel groups in the three-dimensional coordination network, and the uncoordinating aromatic compound has a specific substituent A at a specific position on the aromatic ring thereof, and is arranged regularly such that the substituent A is directed to the inside of a specific channel group B out of the two or more kinds of channel groups, the method comprising the steps of: including the guest molecule in the channel of the channel group B in which the substituent A is arranged; and reacting the guest molecule with the substituent A in the channel to convert the substituent A to a substituent A′, and to arrange the substituent A′ regularly directing to the inside of the channel of the channel group B or any channel of other channel groups.
• US8236867B2
  申请人：——

  公开号：US8236867B2

  公开（公告）日：2012-08-07
• Barker et al., Journal of the Chemical Society, 1955, p. 4482,4484
  作者：Barker et al.

  DOI：——

  日期：——