4-[2-(3-pentadecylphenoxy)-ethoxy]-benzaldehyde | 699008-87-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 4-[2-(3-pentadecylphenoxy)-ethoxy]-benzaldehyde
• 英文别名: 4-[2-(3-Pentadecylphenoxy)ethoxy]benzaldehyde；4-[2-(3-pentadecylphenoxy)ethoxy]benzaldehyde
• CAS: 699008-87-2
• 化学式: C₃₀H₄₄O₃
• 分子量: 452.678
• InChiKey: AVXZNKFFSBNHDA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.9
• 重原子数：
  33
• 可旋转键数：
  20
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N-苯基甘氨酸 、 足球烯 、 4-[2-(3-pentadecylphenoxy)-ethoxy]-benzaldehyde 以 甲苯 为溶剂， 以30%的产率得到
  参考文献：
  名称：

  Synthesis of Fullerene-Cardanol Derivatives

  摘要：

  论文介绍了含有万卡醇替代衍生物的富勒吡咯烷的合成过程，万卡醇是一种易于获得的可再生原料。

  DOI：

  10.1055/s-2004-820014
• 作为产物：
  描述：

  3-十五烷基苯酚 在 氢氧化钾 、 potassium carbonate 作用下， 以 丙酮 为溶剂， 反应 30.0h， 生成 4-[2-(3-pentadecylphenoxy)-ethoxy]-benzaldehyde
  参考文献：
  名称：

  Synthesis of Fullerene-Cardanol Derivatives

  摘要：

  论文介绍了含有万卡醇替代衍生物的富勒吡咯烷的合成过程，万卡醇是一种易于获得的可再生原料。

  DOI：

  10.1055/s-2004-820014

文献信息

• Synthesis, Characterization and Dielectric Properties of New 5-(4-Hydroxyphenyl)-10,15,20-tri-4-[2-(3-pentadecylphenoxy)ethoxy]phenyl porphyrin and Their Ni, Co and Cu Complexes
  作者：João Mota、Antônio da Costa Júnior、Viviane Ribeiro、Samuel Sampaio、Nayane Lima、Fernando da Silva、Claudenilson Clemente、Giuseppe Mele、Diego Lomonaco、Selma E. Mazzetto

  DOI：10.21577/0103-5053.20160261

  日期：——

  New asymmetric cardanol-based porphyrins, free-base and coordinated with Ni, Co and Cu, were synthesized and completely characterized as A3B type. Such porphyrins were obtained aiming improved solubility in polar solvents due insertion of an -OH phenolic group. Their thermal and dielectric properties were also evaluated. Changes in the synthetic route reduced the reaction time and improved the yields of the aldehyde precursor obtainment. Electronic absorption spectra of the new porphyrins in CH2Cl2, EtOH and acetone, indicated a decrease in the epsilon (molar absorptivity) values with increasing solvent polarity, except for the nickel complex which, in acetone, showed a slight increase of 2% in the e value. The dielectric measurements showed that the conductivity (sigma) and the loss tangent (tan delta) increased with frequency, but the permittivity (epsilon') decreased. The results showed that the coordination of the porphyrin promoted a significant change in thermal and dielectric properties, specially for to the Ni-complex compound, which presented the best dielectric properties with interesting values of permittivity and loss tangent at 100 MHz (19.46 and 0.011 a.u., respectively).
• Synthesis of Fullerene-Cardanol Derivatives
  作者：Giuseppe Mele、Orazio A. Attanasi、Roberta Del Sole、Paolino Filippone、Roberto Ianne、Selma E. Mazzetto、Giuseppe Vasapollo

  DOI：10.1055/s-2004-820014

  日期：——

  The paper describes the synthesis of fulleropyrrolidines containing substituted derivatives of cardanol - a readily available renewable raw material.

  论文介绍了含有万卡醇替代衍生物的富勒吡咯烷的合成过程，万卡醇是一种易于获得的可再生原料。