2-(thiophen-3-yl)ethyl 4-cyano-4-(phenylcarbonothioylthio)pentanoate | 1188309-56-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 2-(thiophen-3-yl)ethyl 4-cyano-4-(phenylcarbonothioylthio)pentanoate
• 英文别名: (Thiophen-3-yl)ethyl-4-cyano-4-(phenylcarbonothioylthio)pentanoate；2-thiophen-3-ylethyl 4-(benzenecarbonothioylsulfanyl)-4-cyanopentanoate
• CAS: 1188309-56-9
• 化学式: C₁₉H₁₉NO₂S₃
• 分子量: 389.563
• InChiKey: MQYROGFJRBTQOZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  25
• 可旋转键数：
  10
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  136
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2-(thiophen-3-yl)ethyl 4-cyano-4-(phenylcarbonothioylthio)pentanoate 、 4,4'-偶氮双(4-氰基戊酸) 、 双(硫代苯甲酰基)二硫化物 在 4-氰基-4-(硫代苯甲酰)戊酸 、 氮气 、 crude product 、 silica gel 作用下， 以 乙酸乙酯 为溶剂， 反应 20.0h， 以the red fraction gives 4-cyano-4-((thiobenzoyl)sulfanyl)-pentanoic acid as a red oil的产率得到4-氰基-4-(硫代苯甲酰)戊酸
  参考文献：
  名称：

  Methods for preparing polymer coatings by electrochemical grafting of polymer brushes, compositions prepared thereby and compositions for preparing the coatings

  摘要：

  本发明公开了一种将复杂聚合物涂层嫁接到导电表面的新方法，新的嫁接组合物和嫁接组合物的嫁接涂层的新基板。该方法通过电化学嫁接和反应性交联和/或嫁接聚合的新颖和方便的方法来制备聚合物涂层。

  公开号：

  US09079999B2
• 作为产物：
  描述：

  噻吩-3-乙醇 、 4-氰基-4-(硫代苯甲酰)戊酸 在 4-二甲氨基吡啶 、 N,N'-二环己基碳二亚胺 作用下， 以 二氯甲烷 为溶剂， 以36.3%的产率得到2-(thiophen-3-yl)ethyl 4-cyano-4-(phenylcarbonothioylthio)pentanoate
  参考文献：
  名称：

  Grafting of polymers from electrodeposited macro-RAFT initiators on conducting surfaces

  摘要：

  A novel route for grafting polymers via electropolymerization of a macro-reversible addition fragmentation chain-transfer (RAFT) agent onto a conducting surface is reported. The electro-deposition of the chain transfer agent (CTA) on the conducting surface was done using cyclic voltammetry (CV). The statistically exposed dithiobenzoate moieties served as a CTA for the polymerization of styrene on a matrix of an electrodeposited conjugated polymer. The polystyrene (PS)-modified substrate was then used as the macro-CTA for the synthesis of the second block of poly-tert-butyl acrylate (PTBA) on the surface. The polymerization from the surface was characterized by surface analytical methods including AFM, XPS, and contact angle measurements. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.reactfunctpolym.2011.05.013

文献信息

• METHODS FOR PREPARING POLYMER COATINGS BY ELECTROCHEMICAL GRAFTING OF POLYMER BRUSHES, COMPOSITIONS PREPARED THEREBY AND COMPOSITIONS FOR PREPARING THE COATINGS
  申请人：Advincula Rigoberto

  公开号：US20090236229A1

  公开（公告）日：2009-09-24

  New methods for the grafting of complex polymer coatings onto conducting surfaces, new grafting compositions and new substrates with grafted coating of the grafting compositions are disclosed. The method offers a new and convenient approach for the preparation of polymer coatings by electrochemically grafting and reactive crosslinking, and/or graft polymerizing.

  本发明公开了将复杂聚合物涂层移植到导电表面的新方法，新的移植组合物和移植组合物移植到基底上的新涂层。该方法通过电化学移植和反应性交联和/或移植聚合的新颖和便捷的方法，提供了制备聚合物涂层的新方法。
• US9079999B2
  申请人：——

  公开号：US9079999B2

  公开（公告）日：2015-07-14
• Grafting of polymers from electrodeposited macro-RAFT initiators on conducting surfaces
  作者：Carlos D. Grande、Maria Celeste Tria、Guoqian Jiang、Ramakrishna Ponnapati、Yushin Park、Fabio Zuluaga、Rigoberto Advincula

  DOI：10.1016/j.reactfunctpolym.2011.05.013

  日期：2011.9

  A novel route for grafting polymers via electropolymerization of a macro-reversible addition fragmentation chain-transfer (RAFT) agent onto a conducting surface is reported. The electro-deposition of the chain transfer agent (CTA) on the conducting surface was done using cyclic voltammetry (CV). The statistically exposed dithiobenzoate moieties served as a CTA for the polymerization of styrene on a matrix of an electrodeposited conjugated polymer. The polystyrene (PS)-modified substrate was then used as the macro-CTA for the synthesis of the second block of poly-tert-butyl acrylate (PTBA) on the surface. The polymerization from the surface was characterized by surface analytical methods including AFM, XPS, and contact angle measurements. (C) 2011 Elsevier Ltd. All rights reserved.
• Methods for preparing polymer coatings by electrochemical grafting of polymer brushes, compositions prepared thereby and compositions for preparing the coatings
  申请人：Advincula Rigoberto

  公开号：US09079999B2

  公开（公告）日：2015-07-14

  New methods for the grafting of complex polymer coatings onto conducting surfaces, new grafting compositions and new substrates with grafted coating of the grafting compositions are disclosed. The method offers a new and convenient approach for the preparation of polymer coatings by electrochemically grafting and reactive crosslinking, and/or graft polymerizing.

  本发明公开了一种将复杂聚合物涂层嫁接到导电表面的新方法，新的嫁接组合物和嫁接组合物的嫁接涂层的新基板。该方法通过电化学嫁接和反应性交联和/或嫁接聚合的新颖和方便的方法来制备聚合物涂层。