1,2-bis(hexyloxy)-4-methylbenzene | 67698-90-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1,2-bis(hexyloxy)-4-methylbenzene
• 英文别名: 1,2-Di(n-hexyloxy)-4-methylbenzene；1,2-dihexoxy-4-methylbenzene
• CAS: 67698-90-2
• 化学式: C₁₉H₃₂O₂
• 分子量: 292.462
• InChiKey: DXDUYQIFXAZCIO-UHFFFAOYSA-N

物化性质

• 沸点：
  160-165 °C(Press: 0.5 Torr)
• 密度：
  0.917±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  21
• 可旋转键数：
  12
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.68
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,2-bis(hexyloxy)-4-methylbenzene 在 N-氯代丁二酰亚胺 、 二甲基亚砜 作用下， 以 氯仿 为溶剂， 以95 %的产率得到1-chloro-4,5-bis(hexyloxy)-2-methylbenzene
  参考文献：
  名称：

  钯催化 2,6-二卤代联苯与邻氯芳香族羧酸的二次成环反应生成 (Aza) 二苯并[fg,op]并四苯

  摘要：

  已开发出一种钯催化的 2,6-二卤代联苯与邻氯芳香族羧酸的双重环化反应。该方法能够合成各种二苯并[fg,op]并四苯和氮杂二苯并[fg,op]并四苯。初步研究表明，所得产物二甲基5,6,12,13-四(己氧基)二苯并[fg,op]并四苯-2,9-二羧酸酯，表现出良好的液晶特性。

  DOI：

  10.1002/adsc.202400271
• 作为产物：
  描述：

  溴己烷 、 3,4-二羟基甲苯 在 potassium carbonate 、 potassium iodide 作用下， 以 乙醇 为溶剂， 反应 30.0h， 以95%的产率得到1,2-bis(hexyloxy)-4-methylbenzene
  参考文献：
  名称：

  取代的5,6,11,12-四氢加氢二苯并[ a，e ]环辛烯：取代的桑德海默-黄迪因斯的合成，性质和DFT研究

  摘要：

  高应变环乙炔5,6,11,12-四氢二苯并[ a，e在苯环上具有各种取代基的]环辛烯（Sondheimer-Wong diynes）是通过用氯代磷酸二乙酯/六甲基二硅化锂（LiHMDS）然后二异丙基氨基化锂（LDA）一锅法处理相应的甲砜而成功合成的。当将带有不同取代基的两种类型的甲砜混合物进行此操作时，不对称取代的Sondheimer-Wong diynes可以通过逐步分离杂化的乙烯基砜中间体，然后用LDA处理来逐步合成。记录了取代的Sondheimer-Wong diynes的UV-vis吸收光谱和循环伏安图。通过其点击反应以及亲核和亲电加成，研究了取代基对二炔的电子效应。

  DOI：

  10.1021/jo502248p

文献信息

• Novel sulfonyldiazomethanes, photoacid generators, resist compositions, and patterning process
  申请人：——

  公开号：US20040166432A1

  公开（公告）日：2004-08-26

  A chemical amplification type resist composition comprising a specific sulfonyldiazomethane containing long-chain alkoxyl groups has many advantages including improved resolution, improved focus latitude, minimized line width variation or shape degradation even on long-term PED, minimized debris left after coating, development and peeling, and improved pattern profile after development and is thus suited for microfabrication.

  一种化学放大型抗蚀组合物，包括具有长链烷氧基基团的特定磺酰二氮甲烷，具有许多优点，包括改善分辨率、改善焦点宽度、即使在长期PED上也减少线宽变化或形状退化、涂覆、显影和剥离后减少残留的碎屑，并在显影后改善图案轮廓，因此适用于微细加工。
• Organic electroluminescent polymer having 9,9-di(fluorenyl)-2,7-fluorenyl unit and organic electroluminescent device manufactured using the same
  申请人：You Hong

  公开号：US20070093643A1

  公开（公告）日：2007-04-26

  Disclosed herein is an organic electroluminescent polymer having 9,9-di(fluorenyl)-2,7-fluorenyl unit and an electroluminescent device using the same. Specifically, the current invention provides an organic electroluminescent polymer having 9,9-di(fluorenyl)-2,7-fluorenyl unit, which can be used as a blue electroluminescent polymer and host material by introducing the substituted fluorenyl group at the 9-position of fluorene, and an electroluminescent device using the electroluminescent polymer. The electroluminescent polymer is applicable as a host material for highly pure blue, green and red, having high solubility, high heat stability and high quantum efficiency.

  本文公开了一种具有9,9-二(芴基)-2,7-芴基单元的有机电致发光聚合物及其使用的电致发光装置。具体来说，本发明提供了一种具有9,9-二(芴基)-2,7-芴基单元的有机电致发光聚合物，通过在芴的9位引入取代芴基团，可用作蓝色电致发光聚合物和主体材料，并提供使用该电致发光聚合物的电致发光装置。该电致发光聚合物可作为高纯度蓝、绿和红的主体材料，具有高溶解度、高热稳定性和高量子效率。
• ANTIALLERGIC AGENTS
  申请人：Muto Susumu

  公开号：US20080090779A1

  公开（公告）日：2008-04-17

  A medicament for the preventive and/or therapeutic treatment of allergic diseases and/or endometriosis and/or hysteromyoma which comprises as an active ingredient a substance selected from the group consisting of a compound represented by the following general formula (I) and a pharmacologically acceptable salt thereof, and a hydrate thereof and a solvate thereof: wherein X represents a connecting group whose number of atoms in the main chain is 2 to 5 (said connecting group may be substituted), A represents hydrogen atom or acetyl group, E represents an aryl group which may be substituted or a hetero aryl group which may be substituted, ring Z represents an arene which may have one or more substituents in addition to the group represented by formula —O-A wherein A has the same meaning as that defined above and the group represented by formula —X-E wherein each of X and E has the same meaning as that defined above, or a heteroarene which may have one or more substituents in addition to the group represented by formula —O-A wherein A has the same meaning as that defined above and the group represented by formula —X-E wherein each of X and E has the same meaning as that defined above.

  一种预防和/或治疗过敏性疾病和/或子宫内膜异位症和/或子宫肌瘤的药物，其包括以下通式（I）所表示的化合物或其药学上可接受的盐、水合物和溶剂化物作为活性成分，其中X表示连接基，其主链中原子数为2至5（该连接基可以被取代），A表示氢原子或乙酰基，E表示芳基或取代的杂芳基，环Z表示苯环，除了由公式-O-A表示的基团，该苯环还可以具有一个或多个取代基团，其中A的含义与上述定义相同，而由公式-X-E表示的基团中，每个X和E的含义也与上述定义相同，或者是一个杂环，除了由公式-O-A表示的基团，该杂环还可以具有一个或多个取代基团，其中A的含义与上述定义相同，而由公式-X-E表示的基团中，每个X和E的含义也与上述定义相同。
• Antiallergic agents
  申请人：Muto Susumu

  公开号：US20070185059A1

  公开（公告）日：2007-08-09

  A medicament for the preventive and/or therapeutic treatment of allergic diseases and/or endometriosis and/or hysteromyoma which comprises as an active ingredient a substance selected from the group consisting of a compound represented by the following general formula (I) and a pharmacologically acceptable salt thereof, and a hydrate thereof and a solvate thereof: wherein X represents a connecting group whose number of atoms in the main chain is 2 to (said connecting group may be substituted), A represents hydrogen atom or acetyl group, E represents an aryl group which may be substituted or a hetero aryl group which may be substituted, ring Z represents an arene which may have one or more substitutents in addition to the group represented by formula —O-A wherein A has the same meaning as that defined above and the group represented by formula —X-E wherein each of X and E has the same meaning as that defined above, or a heteroarene which may have one or more substitutents in addition to the group represented by formula —O-A wherein A has the same meaning as that defined above and the group represented by formula —X-E wherein each of X and E has the same meaning as that defined above.

  一种用于预防和/或治疗过敏性疾病和/或子宫内膜异位症和/或子宫肌瘤的药物，其活性成分包括以下通式（I）表示的化合物或其药学上可接受的盐、水合物和溶剂化物中的一种，其中X代表连接基，其主链中的原子数为2到（该连接基可以被取代），A代表氢原子或乙酰基，E代表芳基或取代的杂环芳基，环Z代表芳烃，除了由公式-O-A表示的基团外，还可以有一个或多个取代基，其中A具有上述定义的相同含义，并且由公式-X-E表示的基团，其中X和E的每个都具有上述定义的相同含义，或者可以有一个或多个取代基的杂芳烃，其中A具有上述定义的相同含义，并且由公式-X-E表示的基团，其中X和E的每个都具有上述定义的相同含义。
• Sulfonyldiazomethanes, photoacid generators, resist compositions, and patterning process
  申请人：Shin-Etsu Chemical Co.,Ltd.

  公开号：US07101651B2

  公开（公告）日：2006-09-05

  A chemical amplification type resist composition comprising a specific sulfonyldiazomethane containing long-chain alkoxyl groups has many advantages including improved resolution, improved focus latitude, minimized line width variation or shape degradation even on long-term PED, minimized debris left after coating, development and peeling, and improved pattern profile after development and is thus suited for microfabrication.

  一种化学扩增型光阻组合物，包括一种具有长链烷氧基的特定磺酰基重氮甲烷，具有许多优点，包括提高分辨率，提高焦距宽度，即使在长期PED上也能最小化线宽变化或形状退化，涂覆、开发和剥离后最小化残留物，以及在开发后改善图案轮廓，因此非常适合微纳加工。