methallyl-succinic acid | 5703-12-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: methallyl-succinic acid
• 英文别名: 4-Methyl-penten-(4)-dicarbonsaeure-(1.2)；(2-Methyl-allyl)-bernsteinsaeure；Methallyl-bernsteinsaeure；2-(2-Methylprop-2-enyl)butanedioic acid
• CAS: 5703-12-8
• 化学式: C₈H₁₂O₄
• 分子量: 172.181
• InChiKey: WNENHCOMPPRJHN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  12
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  methallyl-succinic acid 在 sodium carbonate 、 臭氧 作用下， 生成 丁二酸,2-(2-羰基丙基)-
  参考文献：
  名称：

  Alder; Soell, Justus Liebigs Annalen der Chemie, 1949, vol. 565, p. 66

  摘要：

  DOI：
• 作为产物：
  描述：

  (2-甲基-2-丙烯-1-基)琥珀酸酐 生成 methallyl-succinic acid
  参考文献：
  名称：

  Alder; Pascher; Schmitz, Chemische Berichte, 1943, vol. 76, p. 27,48

  摘要：

  DOI：

文献信息

• Organosiloxane mit SiC-gebundenen Estergruppen, Verfahren zu ihrer Herstellung und ihre Verwendung
  申请人：Consortium für elektrochemische Industrie GmbH

  公开号：EP0004074B1

  公开（公告）日：1981-09-02
• BIOCONVERSION OF SHORT-CHAIN HYDROCARBONS TO FUELS AND CHEMICALS
  申请人：Gonzales Ramon

  公开号：US20180355394A1

  公开（公告）日：2018-12-13

  An engineered microorganism(s) with novel pathways for the conversion of short-chain hydrocarbons to fuels and chemicals (e.g. carboxylic acids, alcohols, hydrocarbons, and their alpha-, beta-, and omega-functionalized derivatives) is described. Key to this approach is the use of hydrocarbon activation enzymes able to overcome the high stability and low reactivity of hydrocarbon compounds through the cleavage of an inert C—H bond. Oxygen-dependent or oxygen-independent activation enzymes can be exploited for this purpose, which when combined with appropriate pathways for the conversion of activated hydrocarbons to key metabolic intermediates, enables the generation of product precursors that can subsequently be converted to desired compounds through established pathways. These novel engineered microorganism(s) provide a route for the production of fuels and chemicals from short chain hydrocarbons such as methane, ethane, propane, butane, and pentane.
• Bioconversion of Short-Chain Hydrocarbons to Fuels and Chemicals
  申请人：Gonzalez Ramon

  公开号：US20200347423A1

  公开（公告）日：2020-11-05

  An engineered microorganism(s) with novel pathways for the conversion of short-chain hydrocarbons to fuels and chemicals (e.g. carboxylic acids, alcohols, hydrocarbons, and their alpha-, beta-, and omega-functionalized derivatives) is described. Key to this approach is the use of hydrocarbon activation enzymes able to overcome the high stability and low reactivity of hydrocarbon compounds through the cleavage of an inert C—H bond. Oxygen-dependent or oxygen-independent activation enzymes can be exploited for this purpose, which when combined with appropriate pathways for the conversion of activated hydrocarbons to key metabolic intermediates, enables the generation of product precursors that can subsequently be converted to desired compounds through established pathways. These novel engineered microorganism(s) provide a route for the production of fuels and chemicals from short chain hydrocarbons such as methane, ethane, propane, butane, and pentane.
• US4207246A
  申请人：——

  公开号：US4207246A

  公开（公告）日：1980-06-10
• US4322473A
  申请人：——

  公开号：US4322473A

  公开（公告）日：1982-03-30