9-bromo-10-(phthalimidomethyl)anthracene | 357213-91-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 9-bromo-10-(phthalimidomethyl)anthracene
• 英文别名: 2-[(10-Bromoanthracen-9-yl)methyl]isoindole-1,3-dione
• CAS: 357213-91-3
• 化学式: C₂₃H₁₄BrNO₂
• 分子量: 416.274
• InChiKey: HHNKJTZZXBFUAV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  27
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  37.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  9-bromo-10-(phthalimidomethyl)anthracene 在 tris(dibenzylideneacetone)dipalladium (0) 、 三苯胂 、 碘化1,2-二甲基吡啶鎓 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 216.0h， 生成 tert-butyl N-[N'-[(10-bromoanthracen-9-yl)methyl]-N-[(2-methylpropan-2-yl)oxycarbonyl]carbamimidoyl]carbamate
  参考文献：
  名称：

  9-(Guanidinomethyl)-10-vinylanthracene: a suitable fluorescent monomer for MIPs

  摘要：

  9-(Guanidinomethyl)anthracene derivatives with a bromo (6) or a vinyl group (10) at the 10-position have been prepared starting from 9-bromoanthracene (1). They show 1:1 complexation with carboxylic acids or carboxylates with K-values of 1.2-1.4 x 10(5) M-1 in deuteriomethanol. Copolymerization of 9-vinylanthracene, 9-(guanidinomethyl)-10-vinylanthracene hydrochloride (10), and the 1:1 complex of 10 and ammonium benzoate with ethyleneglycol dimethacrylate (EDMA) gave the polymers in 77-92% yield. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(01)00738-9
• 作为产物：
  描述：

  9-溴蒽 、 N-(hydroxymethyl)phthalimide 在 硫酸 、 溶剂黄146 作用下， 反应 24.0h， 以52%的产率得到9-bromo-10-(phthalimidomethyl)anthracene
  参考文献：
  名称：

  9-(Guanidinomethyl)-10-vinylanthracene: a suitable fluorescent monomer for MIPs

  摘要：

  9-(Guanidinomethyl)anthracene derivatives with a bromo (6) or a vinyl group (10) at the 10-position have been prepared starting from 9-bromoanthracene (1). They show 1:1 complexation with carboxylic acids or carboxylates with K-values of 1.2-1.4 x 10(5) M-1 in deuteriomethanol. Copolymerization of 9-vinylanthracene, 9-(guanidinomethyl)-10-vinylanthracene hydrochloride (10), and the 1:1 complex of 10 and ammonium benzoate with ethyleneglycol dimethacrylate (EDMA) gave the polymers in 77-92% yield. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(01)00738-9

文献信息

• [EN] OPTICAL SENSOR<br/>[FR] CAPTEUR OPTIQUE
  申请人：UNIV CITY

  公开号：WO2012098240A1

  公开（公告）日：2012-07-26

  An optical sensor (1) for in-situ monitoring of chloride ion concentration in concrete structures, the sensor (1) comprising: a sensor body (3) that fluoresces when illuminated by light, the sensor body (3) being configured to exhibit a change in fluorescence when illuminated in the presence of chloride ions, and means (5) for optically coupling said sensor body to a source of illumination. A system (11) is also disclosed, along with methods of synthesising chloride sensitive polymerisable fluorescent dyes, and chloride sensitive polymerisable fluorescent dyes.