nonanoic acid ; silver pelargonate | 32461-92-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: nonanoic acid ; silver pelargonate
• 英文别名: Nonansaeure; Silberpelargonat；Silver;nonanoate
• CAS: 32461-92-0
• 化学式: Ag*C₉H₁₇O₂
• 分子量: 265.101
• InChiKey: AOGSHTKRZIBXPE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.48
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  40.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  nonanoic acid ; silver pelargonate 在 亚硝酰氯 作用下， 生成 Nonanoylnitrit
  参考文献：
  名称：

  Pritzkow,W.; Nitzer,H., Journal fur praktische Chemie (Leipzig 1954), 1964, vol. 25, p. 69 - 78

  摘要：

  DOI：
• 作为产物：
  描述：

  壬酸 、 silver nitrate 在 NaOH 作用下， 以 乙醇 、 水 为溶剂， 生成 nonanoic acid ; silver pelargonate
  参考文献：
  名称：

  一系列无水链烷酸银（i）的 结构，奇偶链交替和热研究

  摘要：

  从X射线粉末衍射，固态自旋解耦13 C-NMR和可变温度傅立叶变换红外光谱法确定银（I）n-链烷酸酯的同源系列（n c = 8–20，包括Nc）的分子和晶格结构。这些化合物在单斜晶体系统中结晶，该链具有完全延伸的全反式构象的烃链。此外，链条大约倾斜。相对于金属基面为75°，在层状结构中以甲基（尾）-甲基（尾）双层形式排列。来自双层中不同层的甲基链末端不重叠，但如此接近以引起甲基-甲基相互作用。在一个分子中，两个羧酸根基团以顺式-顺式结合型将双齿模式桥接至两个银原子以形成八元结构。分子内的银-银和分子间的Ag-O-Ag相互作用稳定了头基并促进了层状聚合物片的形成。尽管这些化合物几乎是同构的，但由于晶格内烃链的堆积差异，在甲基，不寻常的羧酸根（头部）基团的密度，反对称拉伸振动中观察到了奇偶链交替。这些是由不在同一平面上的聚合物片之间的相对垂直距离引起的。因此，对于奇数链长的化合物，其中这些距离

  DOI：

  10.1039/c2dt11638c

文献信息

• Hydrates of Organic Compounds. VIII. The Effect of Carboxylate Anions on the Formation of Clathrate Hydrates of Tetrabutylammonium Carboxylates
  作者：Haruo Nakayama、Shigeru Torigata

  DOI：10.1246/bcsj.57.171

  日期：1984.1

  clathrate-like hydrates. The results can be summarized as follows: (1) for 14 carboxylates the formation of a clathrate-like hydrate is newly confirmed; (2) judging from melting points and hydration numbers, the hydrates can be classified into three groups: I, II, and III; (3) the group I hydrates, formed by the carboxylates with R=H, CH3, C2H5, n-C3H7, i-C3H7, and t-C4H9, have hydration numbers around

  检查了四丁基羧酸铵 (n-C4H9)4 NOOCR（R=Hn-C10H21，包括被甲基或乙基取代的各种烷基）与水的二元混合物的固液相图，以确认形成笼状水合物。结果可概括如下： (1) 14 种羧酸盐形成了笼形水合物；(2)从熔点和水合数判断，水合物可分为I、II、III三类；(3) 由 R=H、CH3、C2H5、n-C3H7、i-C3H7 和 t-C4H9 的羧酸盐形成的 I 组水合物的水合数约为 30，是本研究中最稳定的水合物实验，除了 2-甲基丙酸酯和 2,2-二甲基丙酸酯水合物；(4) II组水合物，水合数约为 39，由 R=n-C4H9、s-C4H9、i-C4H9 和所有 C5H11 的盐形成，并且相对不稳定（mp=5–11 °C）；(5) III 组水合物，...
• Process for producing photochromic titanium oxide compounds
  申请人：SUMITOMO CHEMICAL COMPANY LIMITED

  公开号：EP0624553A1

  公开（公告）日：1994-11-17

  Disclosed are a process for producing a photochromic titanium oxide compound, which comprises (i) dissolving at least one organotitanium compound and at least one organic compound containing at least one metal selected from the group consisting of sodium, iron, chromium, copper, nickel, vanadium, manganese, silicon, zinc, aluminum, cerium, cobalt, niobium, zirconium, molybdenum and silver in an organic solvent to form a homogeneous solution, and if desired, partially removing said organic solvent, (ii) substantially simultaneously hydrolyzing the organotitanium compound and the metal-containing organic compound in the solution obtained in step (i), (iii) separating the organic solvent from the resultant hydrolysate, and (iv) calcining the hydrolyzate, wherein said steps (ii) and (iii) may be carried out concurrently, as well as a photochromic titanium oxide compound prepared by the process.

  公开了一种生产光致变色氧化钛化合物的工艺，其中包括 (i) 将至少一种有机钛化合物和至少一种含有选自钠、铁、铬、铜、镍、钒、锰、硅、锌、铝、铈、钴、铌、锆、钼和银所组成的组中的至少一种金属的有机化合物溶解在有机溶剂中，形成均匀溶液，如果需要，部分除去所述有机溶剂、 (ii) 基本同时水解步骤(i)中所得溶液中的有机钛化合物和含金属有机化合物、 (iii) 从水解产物中分离出有机溶剂，以及 (iv) 煅烧水解物，其中所述步骤(ii)和(iii)可同时进行，以及通过该工艺制备的光致变色氧化钛化合物。
• METHOD OF MANUFACTURING AN ELECTROMAGNETIC INTERFERENCE SHIELDING LAYER
  申请人：Heraeus Deutschland GmbH & Co KG

  公开号：EP3648161A1

  公开（公告）日：2020-05-06

  The present invention relates to a method of manufacturing a semiconductor package, which is at least in part covered by an electromagnetic interference shielding layer, comprising at least these steps: i. Providing the semiconductor package and an ink composition; wherein the ink composition comprises at least these constituents: a) A compound comprising at least one metal precursor; b) At least one organic compound; and ii. Applying at least a part of the ink composition onto the semiconductor package, wherein a precursor layer is formed; iii. Treating the precursor layer with an irradiation of a peak wavelength in the range from 100 nm to 1 mm, and to a semiconductor package comprising an electromagnetic interference shielding layer comprising at least one metal, wherein the semiconductor package is obtainable by the aforementioned method. The present invention relates also to a semiconductor package comprising a electromagnetic interference shielding layer, wherein the specific conductance of the first layer of electromagnetic interference shielding material is in the range from 5 to 90 % of bulk metal; and wherein the thickness of the first layer of electromagnetic interference shielding material is in the range from 5 nm to 5 µm. The present invention relates further to some uses of an ink composition.

  本发明涉及一种至少部分由电磁干扰屏蔽层覆盖的半导体封装的制造方法，该方法至少包括以下步骤： i. 提供半导体封装和油墨组合物；其中油墨组合物至少包括以下成分： a) 由至少一种金属前体组成的化合物； b) 至少一种有机化合物；以及 ii.将至少一部分油墨组合物涂在半导体封装上，其中形成前驱体层； iii.用峰值波长在 100 nm 至 1 mm 范围内的辐照处理前驱体层，以及包含由至少一种金属组成的电磁干扰屏蔽层的半导体封装，其中半导体封装可通过上述方法获得。本发明还涉及一种包含电磁干扰屏蔽层的半导体封装，其中第一层电磁干扰屏蔽材料的比电导率在块状金属的 5% 至 90% 之间；第一层电磁干扰屏蔽材料的厚度在 5 nm 至 5 µm 之间。本发明还涉及油墨组合物的一些用途。
• Conductive ink compositions
  申请人：ELECTRONINKS INCORPORATED

  公开号：US10301497B2

  公开（公告）日：2019-05-28

  A conductive structure is provided. The conductive ink composition includes a silver complex formed by mixing a silver carboxylate, at least one dissolving agent that dissolves the silver carboxylate, and a catalyst. The catalyst includes an amine that decarboxylates the silver carboxylate to make the conductive ink composition. The catalyst decarboxylates the silver carboxylate at a temperature of 100° C. or less. An ink composition comprising a metallic salt with a sterically bulky counter ion and a ligand is also provided. An ink composition for making a conductive structure, comprising a reducible metal complex formed by mixing: a reducing agent, wherein the reducing agent is dissolved in a dissolving agent; and at least one metal salt or metal complex comprising a Group 4, 5, 6, 7, 8, 9, 10, 11, or 12 metal, wherein the reducing agent reduces the metal to form the conductive structure is further provided.

  提供了一种导电结构。导电油墨组合物包括由羧酸银、至少一种溶解羧酸银的溶解剂和催化剂混合形成的银络合物。催化剂包括一种胺，它能使羧酸银脱羧，从而制成导电油墨组合物。催化剂在 100 摄氏度或更低的温度下使羧酸银脱羧。此外，还提供了一种油墨组合物，该组合物由带有固态笨重反离子的金属盐和配体组成。还提供了一种用于制造导电结构的油墨组合物，该组合物包含通过混合以下物质形成的可还原金属复合物：还原剂，其中还原剂溶解在溶解剂中；以及至少一种金属盐或金属复合物，其中金属盐或金属复合物包含第 4、5、6、7、8、9、10、11 或 12 族金属，其中还原剂还原金属以形成导电结构。
• CONDUCTIVE INK COMPOSITIONS
  申请人：ELECTRONINKS INCORPORATED

  公开号：US20170210930A1

  公开（公告）日：2017-07-27

  A conductive structure is provided. The conductive ink composition includes a silver complex formed by mixing a silver carboxylate, at least one dissolving agent that dissolves the silver carboxylate, and a catalyst. The catalyst includes an amine that decarboxylates the silver carboxylate to make the conductive ink composition. The catalyst decarboxylates the silver carboxylate at a temperature of 100° C. or less. An ink composition comprising a metallic salt with a sterically bulky counter ion and a ligand is also provided. An ink composition for making a conductive structure, comprising a reducible metal complex formed by mixing: a reducing agent, wherein the reducing agent is dissolved in a dissolving agent; and at least one metal salt or metal complex comprising a Group 4, 5, 6, 7, 8, 9, 10, 11, or 12 metal, wherein the reducing agent reduces the metal to form the conductive structure is further provided.