2-十六烷基噻吩 | 83027-72-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 中文名称: 2-十六烷基噻吩
• 英文名称: 2-hexadecylthiophene
• 英文别名: 2-hexadecyl-thiophene；2-Hexadecyl-thiophen；2-cetylthiophene；2-Hexadecylthiophen
• CAS: 83027-72-9
• 化学式: C₂₀H₃₆S
• 分子量: 308.572
• InChiKey: PJBTZAOJLKQEES-UHFFFAOYSA-N

物化性质

• 熔点：
  23 °C
• 沸点：
  367.8±5.0 °C(Predicted)
• 密度：
  0.903 g/cm3(Temp: 18 °C)
• 保留指数：
  2289;2328

计算性质

• 辛醇/水分配系数(LogP)：
  9.8
• 重原子数：
  21
• 可旋转键数：
  15
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-十六烷基噻吩 在 1,4-二氧六环 、 镍 作用下， 生成 分析纯正二十烷
  参考文献：
  名称：

  Studies in the Synthesis of Long-chain Compounds^1,2

  摘要：

  DOI：

  10.1021/ja01590a054
• 作为产物：
  描述：

  1-[2]thienyl-hexadecan-1-one 在 盐酸 、 amalgamated zinc 、 溶剂黄146 作用下， 生成 2-十六烷基噻吩
  参考文献：
  名称：

  Studies in the Synthesis of Long-chain Compounds^1,2

  摘要：

  DOI：

  10.1021/ja01590a054

文献信息

• Synthesis and Mesophase Behavior of Phenylthiophene Based Amphiphilic Molecules
  作者：Shan Jing、Ruilin Zhang、Heng Dai、Chao Du、Xiaohong Cheng

  DOI：10.1002/cjoc.201280021

  日期：2012.3

  and solvent induced liquid crystalline behavior of these substances was investigated by polarized optical microscopy, differential scanning calorimetry and X‐ray diffraction. Thereby the influence of the terminal groups attached to the tri(oxylethylene) moities as well as the influence of the length and the number of the alkyl chains on the mesophase behavior were investigated. The single alkyl chain

  使用Ni（II）合成了由刚性2-苯基噻吩核组成的新型两亲分子，该分子具有连接在苯环上的极性柔性三（氧化乙烯）部分和另一侧连接到噻吩环的一个或两个烷基链Pd（0）催化偶联反应为关键步骤。三（氧亚乙基）部分分别被羟基，羧酸钠基团和羧酸锂基团封端。通过偏振光学显微镜，差示扫描量热法和X射线衍射研究了这些物质的热致和溶剂诱导的液晶行为。因此，研究了连接至三（氧化乙烯）部分的端基的影响以及烷基链的长度和数目对中间相行为的影响。单烷基链碳酸钠盐端基的衍生物显示近晶A相，双烷基链碳酸钠盐端基的衍生物显示热六方六角柱状中间相，而在单链和双烷基碳酸锂端基衍生物中均发现柱状中间相。建立了六方柱状中间相的分子组织模型。
• Bent-core mesogens with thiophene units
  作者：Karina Geese、Marko Prehm、Carsten Tschierske

  DOI：10.1039/c0jm01919d

  日期：——

  Bent-core mesogens with thiophene and 2,2′-bithiophene units at the periphery of the aromatic core were synthesized and investigated by polarizing microscopy, XRD and electrooptical methods. Resorcinol, 2,7-naphthalenediol and 3,4′-biphenyldiol were used as bent units, phenyl thiophene-2-carboxylates form the rod-like wings and n-alkyl chains as well as olefin- and silylated-terminated alkyl chains were attached as flexible end-groups. A broad variety of different mesophase structures, incorporating ferroelectric and antiferroelectric switching smectic as well as modulated smectic phases, was obtained. Compared with the corresponding benzoates, these thiophene derived compounds form nearly identical LC phase structures, but have significantly reduced transition temperatures, which make them advantageous for applications.

  具有噻吩和2,2'-双噻吩单元位于芳香核边缘的弯曲核心介晶被合成并通过偏光显微镜、XRD和电光方法进行了研究。间苯二酚、萘-2,7-二醇和3,4'-联苯二醇被用作弯曲单元，苯基噻吩-2-羧酸酯形成棒状翼，以及作为柔性末端基团的正烷基链、烯烃和硅烷化的烷基链被附加。获得了包含铁电和反铁电开关层状以及调制层状相的多种不同的介相结构。与相应的苯甲酸酯相比，这些来源于噻吩的化合物形成了几乎相同的液晶相结构，但具有显著降低的转变温度，这使得它们在应用上具有优势。
• Process for the preparation of polyether polyols
  申请人：——

  公开号：US20010053866A1

  公开（公告）日：2001-12-20

  The present invention relates to a process for the preparation of polyether polyols by the reaction of alkylene oxides and compounds containing active hydrogens, in the presence of specific Lewis acid metal compounds as catalysts, novel bis(perfluoroalkylsulfonic acid) compounds of Group 13 of the Periodic Table of the Elements, and to a process for the preparation thereof and the use thereof as catalysts for ring-opening polymerization of cyclic ethers.

  本发明涉及一种通过在特定Lewis酸金属化合物存在下，通过烷氧基氧化物和含有活性氢的化合物的反应制备聚醚多元醇的方法，以及周期表元素第13组的新型双(全氟烷基磺酸)化合物，以及其制备方法和用作环氧烷环开聚合的催化剂的方法。
• Synthesis and Surface Functionalization of Particles
  申请人：Board of Trustees of The University of Alabama

  公开号：US20140179941A1

  公开（公告）日：2014-06-26

  Provided are methods of controlling the shape and surface chemistry of nanoparticles, particularly ferrite nanoparticles. Methods for preparing non-spherical ferrite nanoparticles, including nanocubes, nanobars, nanoplates, and nanoflowers, are described. Also provided are methods of functionalizing the surface of metal and metal oxide particles. The surface functionalization methods do not require the use of chemical linkers and/or additional reagents, and permit the facile conjugation of a range of molecules, including bioactive agents, to the surface of particles.

  提供了控制纳米颗粒形状和表面化学性质的方法，特别是铁氧体纳米颗粒。描述了制备非球形铁氧体纳米颗粒的方法，包括纳米立方体、纳米棒、纳米板和纳米花。还提供了功能化金属和金属氧化物颗粒表面的方法。表面功能化方法不需要使用化学连接剂和/或额外试剂，并允许轻松地将一系列分子，包括生物活性剂，连接到颗粒表面。
• Amino Silane-Modified Polymers
  申请人：Döring Christian

  公开号：US20160060368A1

  公开（公告）日：2016-03-03

  Modified macromolecular compounds obtainable by using specific amino silane polymerization initiator compounds and optionally chain end-modifying compounds are described. Polymer compositions including such modified macromolecular compounds and the use of such compositions in the preparation of vulcanized (crosslinked) elastomeric polymer compositions and articles are described.

  描述了通过使用特定氨基硅烷聚合引发剂化合物和可选的链端修饰化合物可获得的改性高分子化合物。描述了包括这种改性高分子化合物的聚合物组合物以及在制备硫化（交联）弹性聚合物组合物和制品中使用这种组合物的用途。