2-十六烷基苯酚 | 25401-86-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 中文名称: 2-十六烷基苯酚
• 英文名称: mono-hexadecylphenol
• 英文别名: 2-n-hexadecylphenol；2-hexadecylphenol；hexadecylphenol；cetylphenol；2-Hexadecyl-phenol；2-Hydroxy-1-hexadecyl-benzol；o-Hexadecylphenol
• CAS: 25401-86-9
• 化学式: C₂₂H₃₈O
• 分子量: 318.543
• InChiKey: HMWIHOZPGQRZLR-UHFFFAOYSA-N

物化性质

• 熔点：
  59-60 °C(Solv: methanol (67-56-1); water (7732-18-5); ligroine (8032-32-4))
• 沸点：
  210 °C(Press: 42 Torr)
• 密度：
  0.905±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  10
• 重原子数：
  23
• 可旋转键数：
  15
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

安全信息

• 海关编码：
  2907199090

反应信息

• 作为反应物：
  描述：

  2-十六烷基苯酚 在 lead(IV) acetate 、 sodium carbonate 、 对甲苯磺酸 作用下， 以 苯 为溶剂， 反应 19.0h， 生成 methyl 6-oxo-4(E)-docosenoate
  参考文献：
  名称：

  Snider, Barry B.; Shi, Zhongping, Journal of the American Chemical Society, 1992, vol. 114, # 5, p. 1790 - 1800

  摘要：

  DOI：
• 作为产物：
  描述：

  溴代十六烷 在 正丁基锂 、 四甲基乙二胺 、 对甲苯磺酸 作用下， 以 甲醇 为溶剂， 反应 25.0h， 生成 2-十六烷基苯酚
  参考文献：
  名称：

  Snider, Barry B.; Shi, Zhongping, Journal of the American Chemical Society, 1992, vol. 114, # 5, p. 1790 - 1800

  摘要：

  DOI：

文献信息

• Phosphocholine derivatives having antihypertensive action
  申请人：American Cyanamid Company

  公开号：US04640913A1

  公开（公告）日：1987-02-03

  Phosphocholine derivatives and compositions are described which are useful as hypotensive agents and in the treatment of hypertension in warm-blooded animals.

  磷酸胆碱衍生物和组合物被描述为在温血动物中作为降压剂和治疗高血压的有用药物。
• POLYORGANOSILOXANE COMPOUND, METHOD FOR PREPARING THE SAME, AND COPOLYCARBONATE RESIN COMPRISING THE SAME
  申请人：LG CHEM, LTD.

  公开号：US20160145187A1

  公开（公告）日：2016-05-26

  A polyorganosiloxane compound, a method of preparing the same, and a copolycarbonate resin comprising the same are disclosed. Particularly, a copolycarbonate resin, which may be applied to a variety of applications, and in particular, comprises a polyorganosiloxane compound used as an impact modifier, a modifier, or a comonomer of a copolycarbonate resin and has improved mechanical properties such as low-temperature impact strength, is disclosed.

  公开了一种聚有机硅氧烷化合物、其制备方法以及包含该化合物的共聚碳酸酯树脂。特别地，公开了一种共聚碳酸酯树脂，可应用于各种应用中，特别是包含用作冲击改性剂、改性剂或共聚碳酸酯树脂的共聚物的共聚碳酸酯树脂，并具有改善的机械性能，如低温冲击强度的聚有机硅氧烷化合物。
• Alkylated phenol series in lacustrine black shales from the Nördlinger Ries, southern Germany
  作者：Assem O. Barakat、Susan Baumgart、Peter Brocks、Barbara M. Scholz-Böttcher、Jürgen Rullkötter

  DOI：10.1002/jms.3049

  日期：2012.8

  Several series of alkylated phenols were detected for the first time in the extractable bitumens of organic matter-rich sediments from the Nördlinger Ries (southern Germany). Most abundant and significant constituents comprise those with n-octadecyl, n-eicosanyl, phytanyl, and iso-pentadecyl and anteiso-pentadecyl substituents. The structures of these compounds are suggested from mass spectrometric and retention time data and coinjection with synthetic standards. Diagenetic alteration of phenolic algal lipids is suggested as a possible way to the formation of these compounds in the Nördlinger Ries sediments. Copyright © 2012 John Wiley & Sons, Ltd.

  在 Nördlinger Ries（德国南部）富含有机物质的沉积物的可萃取沥青中首次检测到了几个系列的烷基酚。最丰富和最重要的成分包括具有正十八烷基、正二十烷基、植烷基、异十五烷基和前异十五烷基取代基的苯酚。这些化合物的结构是根据质谱和保留时间数据以及与合成标准品的比对而得出的。酚类藻脂的二基因改变被认为是这些化合物在 Nördlinger Ries 沉积物中形成的可能途径。版权所有 © 2012 John Wiley & Sons, Ltd. 保留所有权利。
• BISBENZOXAZINONE COMPOUND
  申请人：Ibusuki Shun

  公开号：US20120252941A1

  公开（公告）日：2012-10-04

  It is an object of the present invention to provide a bisbenzoxazinone compound which does not substantially contain an alkali metal salt, has high purity and provides a resin composition having excellent resistance to hydrolysis when it is contained in a resin, a production method thereof, and a resin composition comprising the compound. The present invention is a bisbenzoxazinone compound represented by the following formula (4): (R 1 and R 2 are each independently a hydrogen atom, hydroxyl group, alkyl group having 1 to 3 carbon atoms, or the like), and has (i) a purity of 98% or more, (ii) a content of a compound represented by the following formula (7) of less than 0.15 wt %: (iii) a maximum peak in the measurement of the light reflectance at a visible range of its powder at 380 to 480 nm and a maximum light reflectance of 100 to 120%, (iv) a metal sodium content of less than 50 ppm and (v) a YI value of −10 to 10.

  本发明的目的是提供一种双苯并噁唑酮化合物，其基本不含碱金属盐，具有高纯度并在树脂中含有时提供具有优异的耐水解性的树脂组合物，以及其生产方法和包含该化合物的树脂组合物。本发明是由以下公式（4）表示的双苯并噁唑酮化合物：（其中R1和R2各自独立地表示氢原子，羟基，具有1至3个碳原子的烷基或类似物），具有（i）98％或更高的纯度，（ii）少于0.15重量％的以下公式（7）所表示的化合物含量，（iii）在可见光范围内在380至480 nm处的粉末的光反射测量中具有最大峰值，并具有100至120％的最大光反射率，（iv）钠金属含量低于50 ppm和（v）YI值为-10至10。
• Overbased sulfurized alkaline earth metal phenates and process for preparing same
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0486893A1

  公开（公告）日：1992-05-27

  Overbased sulfurized alkaline earth metal phenates which are oil soluble, excellent in detergency dispersancy and have high base value, and an effective process for production of said overbased sulfurized alkaline earth metal phenates under conditions providing less sludge and less raw material recovery, and further a lubricating oil additives containing said overbased sulfurized alkaline earth metal phenates as a main ingredient and a lubricating oil composition which comprises said lubricating oil additive compounded in a lubricating oil are disclosed. Since the resulting overbased sulfurized alkaline earth metal phenates have high base value and excellent oil-solubility, they can be effectively utilized as lubricating oil additives.

  过基硫化碱土金属酚酸盐是油溶性的，具有优异的清洁分散性和高碱值，并且提供了在条件下生产所述过基硫化碱土金属酚酸盐的有效工艺，该条件下可减少泥渣和原料回收，进一步揭示了含有所述过基硫化碱土金属酚酸盐作为主要成分的润滑油添加剂和润滑油组合物，该润滑油添加剂混合在润滑油中。由于所得的过基硫化碱土金属酚酸盐具有高碱值和优异的油溶性，因此它们可以有效地用作润滑油添加剂。

表征谱图