2-叔丁基过氧乙酸 | 34511-06-3

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 中文名称: 2-叔丁基过氧乙酸
• 英文名称: tert-Butylperoxy-essigsaeure
• 英文别名: (tert-Butylperoxy)acetic acid；2-tert-butylperoxyacetic acid
• CAS: 34511-06-3
• 化学式: C₆H₁₂O₄
• 分子量: 148.159
• InChiKey: HDJFYCBNCRSUJO-UHFFFAOYSA-N

物化性质

• 沸点：
  67-68 °C(Press: 1 Torr)
• 密度：
  1.0752 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  55.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-叔丁基过氧乙酸 在 草酰氯 作用下， 生成 tert-Butylperoxyacetylchlorid
  参考文献：
  名称：

  Rakhimov,A.I.; Baklanov,A.V., Journal of Organic Chemistry USSR (English Translation), 1979, vol. 15, p. 832 - 838

  摘要：

  DOI：
• 作为产物：
  描述：

  2-[叔丁基二氧基]-乙醇 在 potassium permanganate 作用下， 生成 2-叔丁基过氧乙酸
  参考文献：
  名称：

  Rakhimov,A.I.; Baklanov,A.V., Journal of Organic Chemistry USSR (English Translation), 1979, vol. 15, p. 832 - 838

  摘要：

  DOI：

文献信息

• Photopolymerizable composition and use thereof
  申请人：Imai Masao

  公开号：US20060003261A1

  公开（公告）日：2006-01-05

  A photopolymerizable composition comprising a polymerizable compound and a photopolymerization initiator, wherein the polymerizable compound is characterized by comprising (a) a bifunctional (meth)acrylic acid (thio)ester compound containing a sulfur atom in the molecule and (b) at least one of a (meth)acrylic acid ester compound represented by the general formula (1) or a bifunctional (meth)acrylic acid ester compound having a urethane linkage: wherein R 1 and R 2 are each independently a hydrogen atom or a methyl group; R 3 and R 4 are each independently an alkyl group, an aralkyl group, an aryl group or a halogen atom; m and n are each an integer of 0 to 2; X 1 is an alkylidene group having 1 to 3 carbon atoms; and Y 1 and Y 2 are each independently a poly(oxyalkylene) group with the proviso that at least one of Y 1 and Y 2 is a poly(oxyalkylene) group having a hydroxy group.

  一种光聚合物组合物，包括可聚合化合物和光聚合引发剂，其中可聚合化合物的特征在于包含(a)一种含有分子中硫原子的双官能基（甲基）丙烯酸（硫）酯化合物和(b)至少一种由通式（1）表示的（甲基）丙烯酸酯化合物或具有脲链的双官能基（甲基）丙烯酸酯化合物：其中R1和R2各自独立地表示氢原子或甲基基团；R3和R4各自独立地表示烷基基团、芳基烷基基团、芳基基团或卤素原子；m和n各自为0到2的整数；X1表示具有1到3个碳原子的烷基亚基团；Y1和Y2各自独立地表示聚（氧烷基）基团，但至少其中之一为具有羟基的聚（氧烷基）基团。
• Process for the preparation of polymer particles
  申请人：Nova Chemicals (International) S.A.

  公开号：EP1057838A2

  公开（公告）日：2000-12-06

  Process for the preparation of polyvinylarene polymer particles by suspension polymerisation, wherein (a) vinylarene monomers are suspended in an aqueous medium to yield a suspension; (b) the temperature of the suspension is adjusted to a temperature above 50°C, at which temperature an initiator is added; (c) subsequently, the reaction temperature is increased by 5 to 30°C per hour until a temperature of at least 120°C has been reached; and (d) the temperature is retained at a temperature of at least 120°C until the polymerisation is complete.

  用悬浮聚合法制备聚乙烯醇聚合物颗粒的工艺，其中 (a) 乙烯基单体悬浮在水介质中，形成悬浮液； (b) 将悬浮液的温度调节到 50°C 以上，在此温度下加入引发剂； (c) 随后，每小时将反应温度提高 5 至 30°C，直至温度达到至少 120°C；以及 (d) 温度保持在至少 120 摄氏度，直至聚合反应完成。
• PHOTOPOLYMERIZABLE COMPOSITION AND USE THEREOF
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1548039A1

  公开（公告）日：2005-06-29

  A photopolymerizable composition comprising a polymerizable compound and a photopolymerization initiator, wherein the polymerizable compound is characterized by comprising (a) a bifunctional (meth)acrylic acid (thio)ester compound containing a sulfur atom in the molecule and (b) at least one of a (meth)acrylic acid ester compound represented by the general formula (1) or a bifunctional (meth)acrylic acid ester compound having a urethane linkage:    wherein R1 and R2 are each independently a hydrogen atom or a methyl group; R3 and R4 are each independently an alkyl group, an aralkyl group, an aryl group or a halogen atom; m and n are each an integer of 0 to 2; X1 is an alkylidene group having 1 to 3 carbon atoms; and Y1 and Y2 are each independently a poly(oxyalkylene) group with the proviso that at least one of Y1 and Y2 is a poly(oxyalkylene) group having a hydroxy group.

  一种由可聚合化合物和光聚合引发剂组成的可光聚合组合物，其中可聚合化合物的特征在于包括(a)分子中含有一个硫原子的双官能团(甲基)丙烯酸(硫)酯化合物和(b)通式(1)代表的(甲基)丙烯酸酯化合物或具有氨基甲酸酯连接的双官能团(甲基)丙烯酸酯化合物中的至少一种： 其中 R1 和 R2 各自独立地为氢原子或甲基；R3 和 R4 各自独立地为烷基、芳烷基、芳基或卤素原子；m 和 n 各自为 0 至 2 的整数；X1 为具有 1 至 3 个碳原子的亚烷基；Y1 和 Y2 各自独立地为聚氧亚烷基，但 Y1 和 Y2 中至少有一个为具有羟基的聚氧亚烷基。
• A method for manufacturing poly(2-hydroxyalkanoic acid), and the poly(2-hydroxyalkanoic acid)) obtainable thereby
  申请人：Sulzer Chemtech AG

  公开号：EP2832762A1

  公开（公告）日：2015-02-04

  A method for manufacturing poly(2-hydroxyalkanoic acid), preferably a poly(lactic acid), is disclosed, The method comprises the steps of: mixing a cyclic diester of a 2-hydroxyalkanoic acid and a polymerization catalyst, polymerizing the cyclic diester to form poly(2-hydroxyalkanoic acid) in liquid phase, adding a peroxide-based compound as a catalyst deactivating agent to the liquid phase, applying a devolatilisation step to the liquid phase, and allowing the poly(2-hydroxyalkanoic acid) to solidify, characterized in that an end-capping agent is added to the poly(2-hydroxyalkanoic acid) in the liquid phase. The present invention also relates to a poly(2-hydroxyalkanoic acid), preferably a poly(lactic acid), obtainable with said method characterized in that the polymer has a Mn abs ranging between 10000 and 250000 g/mol, preferably between 20000 and 85000 g/mol. [FIG. 1]

  本发明公开了一种制造聚（2-羟基烷酸），最好是聚（乳酸）的方法，该方法包括以下步骤：将 2-羟基烷酸的环状二酯和聚合催化剂混合，聚合环状二酯形成液相中的聚 2-羟基烷酸，在液相中加入过氧化物基化合物作为催化剂失活剂，在液相中进行脱胶步骤，使聚 2-羟基烷酸凝固，其特征在于在液相中的聚 2-羟基烷酸中加入端盖剂。本发明还涉及一种聚（2-羟基烷酸），最好是一种聚（乳酸），可通过上述方法获得，其特征在于聚合物的 Mn abs 在 10000 至 250000 g/mol 之间，最好在 20000 至 85000 g/mol 之间。[图 1］
• THERMOPLASTIC COPOLYMER PREPARATION METHOD, THERMOPLASTIC COPOLYMER PREPARED THEREBY, AND THERMOPLASTIC RESIN COMPOSITION COMPRISING SAME
  申请人：LG CHEM, LTD.

  公开号：EP3747917A1

  公开（公告）日：2020-12-09

  The present invention relates to a method for preparing a thermoplastic copolymer using monomer droplets, a thermoplastic copolymer prepared therefrom and a thermoplastic resin composition including the same. In the preparation method, monomer droplets including an aromatic vinyl-based monomer are injected after reaching a polymerization conversion ratio of 10% to participate in the reaction after initiating polymerization, and a thermoplastic copolymer having an increased average particle diameter may be prepared in high yield.

  本发明涉及一种使用单体液滴制备热塑性共聚物的方法、由此制备的热塑性共聚物以及包括其在内的热塑性树脂组合物。在该制备方法中，包括芳香乙烯基单体在内的单体液滴在聚合转化率达到 10%后注入，在引发聚合后参与反应，可以高产率制备出平均粒径增大的热塑性共聚物。