4,4'''-dihydroxy-1,1':4',1'':4'',1'''-quaterphenyl | 10508-41-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,4'''-dihydroxy-1,1':4',1'':4'',1'''-quaterphenyl
• 英文别名: [1,1';4',1'';4'',1''']quaterphenyl-4,4'''-diol；4,4'''-Dihydroxy-p-quaterphenyl；4,4'''-Dihydroxy-[4',4'']quaterphenyl；p-Quaterphenyldiol-(4,4''')；4-[4-[4-(4-Hydroxyphenyl)phenyl]phenyl]phenol
• CAS: 10508-41-5
• 化学式: C₂₄H₁₈O₂
• 分子量: 338.406
• InChiKey: AMBWAOVSEACQJG-UHFFFAOYSA-N

物化性质

• 熔点：
  419-422 °C
• 沸点：
  588.8±35.0 °C(Predicted)
• 密度：
  1.199±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  26
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4,4'''-dihydroxy-1,1':4',1'':4'',1'''-quaterphenyl 、 氯乙酸酐 生成 4,4'''-bis-chloroacetoxy-[1,1';4',1'';4'',1''']quaterphenyl
  参考文献：
  名称：

  The Next Unseen Revolution Pension Fund Investment and Sustainability

  摘要：

  DOI：

  10.1080/00139150109604511
• 作为产物：
  描述：

  4-iodo-4'-methoxybiphenyl 在 氢碘酸 、 铜 作用下， 生成 4,4'''-dihydroxy-1,1':4',1'':4'',1'''-quaterphenyl
  参考文献：
  名称：

  The Next Unseen Revolution Pension Fund Investment and Sustainability

  摘要：

  DOI：

  10.1080/00139150109604511
• 作为试剂：
  描述：

  、 4-羟基-4'-溴联苯 、 sodium hydroxide 在 palladium-carbon 、 钯 disodium 、 4,4'''-dihydroxy-1,1':4',1'':4'',1'''-quaterphenyl 、 N,N-二甲基甲酰胺 、 硫酸 作用下， 以 甲醇 为溶剂， 反应 4.0h， 以gave white crystalline powder of 4,4"'-dihydroxy-p-quaterphenyl (DHQ), which的产率得到4,4'''-dihydroxy-1,1':4',1'':4'',1'''-quaterphenyl
  参考文献：
  名称：

  Polyester and an article made of the same

  摘要：

  提供一种聚酯，其主要单体组分包括二羧酸和二醇，其中包括特定公式的p-四苯基衍生物。使用适当种类的二羧酸制备聚酯，可以获得热塑性弹性体或工程塑料材料（即液晶聚合物）。

  公开号：

  US05235024A1

文献信息

• AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENCE DEVICE USING THE SAME
  申请人：MORISHITA Hironobu

  公开号：US20080091025A1

  公开（公告）日：2008-04-17

  The present invention provides an organic electroluminescence device which can be driven at a reduced voltage, hardly causes the crystallization of a molecule, can be produced in improved yield, and has a long lifetime because of difficulty of molecular crystallization, and aromatic amine derivatives for realizing the device. The aromatic amine derivatives are novel aromatic amine derivatives having a specific structure. The organic electroluminescence device includes an organic thin film layer formed of one or more layers including at least a light emitting layer, the organic thin film layer being interposed between a cathode and an anode. In the organic electroluminescence device, at least one layer of the organic thin film layer, especially a hole transporting layer, contains the aromatic amine derivative alone or as a component of a mixture.

  本发明提供了一种有机电致发光器件，可以在降低电压的情况下驱动，几乎不会导致分子结晶，可以提高产量生产，并且由于分子结晶困难，具有长寿命，以及用于实现该器件的芳香胺衍生物。这些芳香胺衍生物是具有特定结构的新型芳香胺衍生物。该有机电致发光器件包括由一个或多个层组成的有机薄膜层，至少包括一个发光层，该有机薄膜层位于阴极和阳极之间。在该有机电致发光器件中，至少有一个有机薄膜层的层，特别是一个传输孔层，单独或作为混合物的组分包含该芳香胺衍生物。
• AROMATIC AMINE COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICE USING SAME
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：EP1806334A1

  公开（公告）日：2007-07-11

  An aromatic amine compound of a specific structure having at least one fluorene structure. An organic electroluminescence device which comprises one or more organic thin film layers comprising at least one light emitting layer sandwiched between a cathode and an anode, wherein at least one of the thin film layers comprises the aromatic amine compound according to claim 1 singly or as its mixture component. Such an organic electroluminescence device has various luminescent hues, high heat resistance, long lifetime, high luminance and high luminous efficiency. The above-mentioned novel aromatic amine compound enables to realize such an organic electroluminescence device.

  一种具有至少一个芴结构的特定结构的芳香胺化合物。一种有机电致发光装置，其包括至少一个有机薄膜层，包括夹在阴极和阳极之间的至少一个发光层，其中至少一个薄膜层以权利要求1中的芳香胺化合物单独或作为其混合组分组成。这样的有机电致发光装置具有各种发光色调，高耐热性，长寿命，高亮度和高发光效率。上述新型芳香胺化合物使得实现这样的有机电致发光装置成为可能。
• Polyester and an article made of the same comprising a p-quaterphenyl
  申请人：Sekisui Kagaku Kogyo Kabushiki Kaisha

  公开号：US05191057A1

  公开（公告）日：1993-03-02

  A polyester is provided that comprises as main monomer components thereof a dicarboxylic acid and a diol, including a p-quaterphenyl derivative of specific formula. The use of appropriate kinds of dicarboxylic acid for the polyester makes it possible to obtain a thermoplastic elastomer or an engineering plastic material (i.e., liquid-crystal polymer).

  提供一种聚酯，其主要单体组分包括二羧酸和二元醇，包括特定公式的p-四苯基衍生物。使用适当种类的二羧酸可以获得热塑性弹性体或工程塑料材料（即液晶聚合物）。
• Engineering plastic composition and an article made of the same
  申请人：Sekisui Kagaku Kogyo Kabushiki Kaisha

  公开号：US05011879A1

  公开（公告）日：1991-04-30

  An engineering plastic composition with excellent flowability, heat stability, and desirable mechanical properties is provided. The composition comprises an engineering plastic material and at least one p-quaterphenyl derivative of specific formula.

  提供了一种具有良好流动性、热稳定性和理想机械性能的工程塑料组合物。该组合物包括一种工程塑料材料和至少一种特定配方的p-四苯基衍生物。
• Aromatic Amine Compound and Organic Electroluminescent Device Using Same
  申请人：Kawamura Masahiro

  公开号：US20070287029A1

  公开（公告）日：2007-12-13

  An aromatic amine compound of a specific structure having at least one fluorene structure. An organic electroluminescence device which comprises one or more organic thin film layers comprising at least one light emitting layer sandwiched between a cathode and an anode, wherein at least one of the thin film layers comprises the aromatic amine compound according to claim 1 singly or as its mixture component. Such an organic electroluminescence device has various luminescent hues, high heat resistance, long lifetime, high luminance and high luminous efficiency. The above-mentioned novel aromatic amine compound enables to realize such an organic electroluminescence device.

  一种具有至少一个芴结构的特定结构的芳香胺化合物。一种有机电致发光装置，包括至少一个发光层夹在阴极和阳极之间的一个或多个有机薄膜层，其中至少一个薄膜层包含根据权利要求1所述的芳香胺化合物，单独或作为其混合成分。这样的有机电致发光装置具有各种发光色调，高耐热性，长寿命，高亮度和高光效。上述新型芳香胺化合物使得实现这样的有机电致发光装置成为可能。