(3-(Vinyloxy)propoxy)benzene | 157840-15-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: (3-(Vinyloxy)propoxy)benzene
• 英文别名: 3-ethenoxypropoxybenzene
• CAS: 157840-15-8
• 化学式: C₁₁H₁₄O₂
• 分子量: 178.231
• InChiKey: DWJFYMOGCRXAJA-UHFFFAOYSA-N

物化性质

• 沸点：
  265.5±23.0 °C(Predicted)
• 密度：
  0.985±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  13
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (3-(Vinyloxy)propoxy)benzene 以 正戊烷 为溶剂， 反应 44.0h， 以19%的产率得到
  参考文献：
  名称：

  Stereocontrolled intramolecular meta-arene–alkene photocycloaddition reactions using chiral tethers: efficiency of the tether derived from 2,4-pentanediol

  摘要：

  Photochemical reactions of substrates consisting of phenyl and vinyl groups, which are tethered with a chiral diol, resulted in intramolecular meta-arene-alkene cycloaddition; the reaction efficiency as well as the stereoselectivity was studied. 1,3-Butanediol, 2-substituted 1,3-propanediols, 2-methyl-2,4-penetanediol, and 2,6-dimethyl-3,5-heptanediol were employed as tethers, and the results are compared with those obtained with 2,4-pentanediol (PD) tether, which are known to show high stereoselectivity and moderate efficiency. All the reactions with the lower analogues were less efficient than with PD, although one of the butanediol-tethered reactions afforded a single stereoisomer as PD did. The dimethylheptanediol tether showed similar efficiency but lower stereoselectivity than PD. The results suggest that the PD tether has an optimized structure having a proper flexibility. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetasy.2004.11.086
• 作为产物：
  描述：

  3-cyclohexyloxypropyl alcohol 在 mercury(II) diacetate 、 pyridinium hydrobromide perbromide 作用下， 以 二甲基亚砜 为溶剂， 生成 (3-(Vinyloxy)propoxy)benzene
  参考文献：
  名称：

  Regio- and diastereo-chemically controlled photocycloaddition of an arene and an alkene linked by a chiral auxiliary

  摘要：

  Intramolecular meta-arene-alkene photocycloaddition of 1b, the substrate having a chiral auxiliary as a linking bridge between the arene and the alkene, resulted in high diastereofacial differentiation of the alkene at the addition step and sufficient regiocontrol of the subsequent ring closure step to give a single diastereomer 4.

  DOI：

  10.1016/0957-4166(94)80147-9

文献信息

• [EN] ETHYLENE-TETRAFLUOROETHYLENE CARBOXYLIC ACIDS AND SALTS<br/>[FR] ACIDES ÉTHYLÈNE-TÉTRAFLUOROÉTHYLÈNE CARBOXYLIQUES ET SELS CORRESPONDANTS
  申请人：DU PONT

  公开号：WO2010075354A1

  公开（公告）日：2010-07-01

  Polyfluorinated carboxylic acids and their salts containing an ethylene-tetrafluoroethylene moiety, which are useful as surfactants in a process for the dispersion polymerization of fluorinated monomer in an aqueous polymerization medium.

  聚氟碳羧酸及其盐含有乙烯四氟乙烯基团，可用作在含水聚合介质中进行氟单体分散聚合过程中的表面活性剂。
• Stabilized fluoroelastomer compositions
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0038535A2

  公开（公告）日：1981-10-28

  Vulcanizates of certain fluoroelastomer terpolymer compositions, wherein the terpolymer is derived from tetrafluoroethylene, perfluoro (methyl vinyl ether), and a cure-site monomer, and further wherein the composition contains non-black filler, exhibit significantly improved stability upon heat aging when small quantities of quinacridone-type pigments are incorporated therein.

  某些氟弹性体三元共聚物组合物的硫化胶，其中的三元共聚物由四氟乙烯、全氟（甲基乙烯基醚）和固化位点单体衍生而成，而且组合物中含有非黑色填料，当其中加入少量喹吖啶酮类颜料时，其热老化稳定性会显著提高。
• Perfluoroelastomer blends
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0105445A1

  公开（公告）日：1984-04-18

  Co-vulcanizable fluoroelastomer blends of tetra- fluoroethylene/perfluoro-(methylvinyl-ether)/cure-site monomer terpolymer and hexafluoropropylene oxide/cure-site monomer dipolymer.

  四氟乙烯/全氟（甲基乙烯基醚）/固位单体三元共聚物和六氟环氧丙烷/固位单体二元共聚物的可共硫化氟橡胶混合物。
• Fluorinated thermoplastic elastomer compositions
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0168020A2

  公开（公告）日：1986-01-15

  A two-phase fluorocarbon composition in which the continuous phase is a crystalline thermoplastic, and the discontinuous phase is a crosslinked elastomer. The disper- sal phase constitutes 50 to 90% of the total. The composition is prepared by dynamic curing.

  一种两相碳氟化合物组合物，其中连续相为结晶热塑性塑料，不连续相为交联弹性体。 分散相占总量的 50%至 90%。 该组合物通过动态固化制备而成。
• Fluorinated phenolic polymer and process for its preparation
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0028161B1

  公开（公告）日：1984-03-21