3-Ethyl-4-methyl-pentansaeure-ethylester | 6570-84-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 3-Ethyl-4-methyl-pentansaeure-ethylester
• 英文别名: Ethyl 3-ethyl-4-methylpentanoate；ethyl 3-ethyl-4-methylpentanoate
• CAS: 6570-84-9
• 化学式: C₁₀H₂₀O₂
• 分子量: 172.268
• InChiKey: HMMHDMNHBCSFFX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-甲基-3-戊酮 在 palladium on activated charcoal 氢气 作用下， 以 乙醇 为溶剂， 生成 3-Ethyl-4-methyl-pentansaeure-ethylester
  参考文献：
  名称：

  Synthesis of cholesteol analogs with modified side-chains

  摘要：

  DOI：

  10.1016/0039-128x(66)90069-9

文献信息

• HERBICIDAL AND FUNGICIDAL 5-OXY-SUBSTITUTED 3-PHENYLISOXAZOLINE-5-CARBOXAMIDES AND 5-OXY-SUBSTITUTED 3-PHENYLISOXAZOLINE-5-THIOAMIDES
  申请人：BAYER CROPSCIENCE AG

  公开号：US20150245616A1

  公开（公告）日：2015-09-03

  Herbicidally and fungicidally active 5-oxy-substituted 3-phenylisoxazoline-5-carboxamides and 5-oxy-substituted 3-phenylisoxazoline-5-thioamides of the formula (I) are described. In this formula (I), X, X 2 to X 6 , R 1 to R 4 are radicals such as hydrogen, halogen and organic radicals such as substituted alkyl. A is a bond or a divalent unit. Y is a chalcogen.

  具有除草和杀菌活性的5-氧代取代的3-苯基异噁唑啉-5-羧酰胺和5-氧代取代的3-苯基异噁唑啉-5-硫酰胺的化合物如下式（I）所述。 在这个式子（I）中，X，X2至X6，R1至R4是氢、卤素和有机基团，如取代烷基等。A是一个键或二价基团。Y是硫族元素。
• HERBICIDALLY AND FUNGICIDALLY ACTIVE 3-HETEROARYL-ISOXAZOLINE-5-CARBOXAMIDES AND 3-HETEROARYL-ISOXAZOLINE-5-THIOAMIDES
  申请人：BAYER CROPSCIENCE AG

  公开号：US20150223461A1

  公开（公告）日：2015-08-13

  Herbicidally and fungicidally active 3-heteroaryl-isoxazoline-5-carboxamides and 3-heteroaryl-isoxazoline-5-thioamides Herbicidally and fungicidally active 3-heteroarylisoxazoline-5-carboxamides and 3-heteroarylisoxazoline-5-thioamides of the formula (I) are described. In this formula (I), R represents radicals such as hydrogen, halogen and organic radicals such as substituted alkyl. A is a bond or a divalent unit. Y is a chalcogen.

  具有除草和杀菌活性的3-杂环芳基异噁唑啉-5-羧酰胺和3-杂环芳基异噁唑啉-5-硫酰胺被描述为具有除草和杀菌活性的化合物。在公式（I）中，R代表氢，卤素和有机基团，例如取代的烷基。 A是一个键或二价基团。 Y是硫族元素。
• Intermetallic coinage metal-catalyzed functionalization of alkanes with ethyl diazoacetate: Gold as a ligand
  作者：M. Ángeles Fuentes、María Rodríguez-Castillo、Miguel Monge、M. Elena Olmos、Jose M. López-de-Luzuriaga、Ana Caballero、Pedro J. Pérez

  DOI：10.1016/j.ica.2011.01.012

  日期：2011.4

  The complexes [Au2M2(C6F5)(4)(NCMe)(2)](n) (M = Cu, 1; M = Ag, 2) have been tested as catalysts for the functionalization of alkanes by the carbene insertion methodology, using ethyl diazoacetate as the carbene source. Moderate to high conversions have been obtained. The observed selectivities seem to favor the proposal that the active metal for catalysis is the Cu/Ag center, the Au(C6F5)(2) unit acting as a spectator ligand in both cases. (C) 2011 Elsevier B.V. All rights reserved.
• US9516880B2
  申请人：——

  公开号：US9516880B2

  公开（公告）日：2016-12-13
• Synthesis of cholesteol analogs with modified side-chains
  作者：Ernst D. Bergmann、Shoshana Blum、Zvi H. Levinson

  DOI：10.1016/0039-128x(66)90069-9

  日期：1966.5