2-diacetoxymethyl-anthraquinone | 85637-31-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 2-diacetoxymethyl-anthraquinone
• 英文别名: 2-Diacetoxymethyl-anthrachinon；anthraquinone-2-aldehyde diacetate；(Acetyloxy)(9,10-dioxo-9,10-dihydroanthracen-2-YL)methyl acetate；[acetyloxy-(9,10-dioxoanthracen-2-yl)methyl] acetate
• CAS: 85637-31-6
• 化学式: C₁₉H₁₄O₆
• mdl: MFCD00808663
• 分子量: 338.317
• InChiKey: QAJVGHLJWHZZRU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  25
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.16
• 拓扑面积：
  86.7
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2-diacetoxymethyl-anthraquinone 在 硫酸 、 对甲苯磺酸 作用下， 以 乙醇 、 二氯甲烷 、 氯仿 、 水 为溶剂， 反应 2.0h， 生成 2-[15-(4-Dimethylamino-phenyl)-2,8,12,18-tetraethyl-3,7,13,17-tetramethyl-porphyrinogen-5-yl]-anthraquinone
  参考文献：
  名称：

  Zhang, Jie; Yang, Guo-Yu; Wen, Ke, Gazzetta Chimica Italiana, 1997, vol. 127, # 10, p. 613 - 618

  摘要：

  DOI：
• 作为产物：
  描述：

  乙酸酐 、 alkaline earth salt of/the/ methylsulfuric acid 在 硫酸 作用下， 生成 2-diacetoxymethyl-anthraquinone
  参考文献：
  名称：

  Sunthankar; Venkataraman, Proceedings - Indian Academy of Sciences, Section A, 1947, # 25, p. 467,478

  摘要：

  DOI：

文献信息

• Double-spiro organic compounds and organic electroluminescent devices using the same
  申请人：LG Chem, Ltd.

  公开号：US06998487B2

  公开（公告）日：2006-02-14

  Disclosed are double-spiro organic compounds and an organic electroluminescence (EL) device using the same. The double-spiro organic compounds are configured to have at least three planar and substantially linear moieties, such that one planar moiety is located between two neighboring planar moieties and that the intervening planar moiety shares an atom with each of the two neighboring planar moieties. The double-spiro compounds generally have high melting point above about 300 degree C. and low crystallinity, which provide thermal stability to the organic EL devices. These organic compounds have good sublimability. They also have light-emitting, hole-injecting, hole-transporting, electron injection, electron-transporting properties and characteristics, which are favorable in the organic EL devices.

  揭示了双螺环有机化合物及其使用的有机电致发光（EL）器件。这些双螺环有机化合物被设计为至少具有三个平面且基本线性的基团，使得一个平面基团位于两个相邻的平面基团之间，并且介于两个相邻平面基团之间的中间基团与这两个相邻的平面基团中的每一个共享一个原子。双螺环化合物通常具有高于约300摄氏度的高熔点和低结晶度，这为有机EL器件提供了热稳定性。这些有机化合物具有良好的升华性能。它们还具有发光、注入正空穴、正空穴传输、注入电子、电子传输性能和特性，在有机EL器件中具有优势。
• Regioselective Carboxylation of 9-Xanthenones with Manganese(III) Acetate
  作者：Hiroshi Nishino、Kazu Kurosawa

  DOI：10.1246/bcsj.56.474

  日期：1983.2

  Seven 9-xanthenones were oxidized with manganese(III) acetate to give carboxy-, dicarboxy-, (acetoxymethyl)(carboxy)-, (carboxy)(hydroxymethyl)-, and acetoxymethyl-9-xanthenones, and to yield small amounts of (carboxymethyl)(carboxy)-, carboxymethyl-, (acetoxymethyl)(carboxymethyl)-, bis(acetoxymethyl)-, and diacetoxymethyl-9-xanthenones. The carboxyl group was preferentially introduced into the peri positions and the acetoxymethyl groups were located at positions ortho to the methoxyl or methyl group. The regioselectivity and mechanism of the carboxylation reaction is discussed briefly.

  用乙酸锰（III）氧化 7 种 9-氧杂蒽酮，得到羧基、二羧基、(乙酰氧甲基)(羧基)-、(羧基)(羟甲基)- 和乙酰氧甲基-9-氧杂蒽酮、并生成少量(羧甲基)(羧基)-、羧甲基-、(乙酰氧甲基)(羧基甲基)-、双(乙酰氧甲基)-和双乙酰氧甲基-9-氧杂蒽酮。羧基被优先引入周边位置，乙酰氧甲基则位于甲氧基或甲基的正交位置。本文简要讨论了羧化反应的区域选择性和机理。
• Sunthankar; Venkataraman, Proceedings - Indian Academy of Sciences, Section A, 1947, # 25, p. 467,478
  作者：Sunthankar、Venkataraman

  DOI：——

  日期：——
• Zhang, Jie; Yang, Guo-Yu; Wen, Ke, Gazzetta Chimica Italiana, 1997, vol. 127, # 10, p. 613 - 618
  作者：Zhang, Jie、Yang, Guo-Yu、Wen, Ke、Sun, Hao-Ran、Yu, Lian-Xiang、Cao, Xi-Zhang

  DOI：——

  日期：——