trans,trans-bis(2-phenylvinyl) ether | 98760-55-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: trans,trans-bis(2-phenylvinyl) ether
• 英文别名: bis-styrene oxide；styryl oxide；[(E)-2-[(E)-2-phenylethenoxy]ethenyl]benzene
• CAS: 98760-55-5
• 化学式: C₁₆H₁₄O
• 分子量: 222.287
• InChiKey: VNDFYDZORAPFSA-PHEQNACWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1,4-二苯基-1,3丁二烯 在 ammonium hydroxide 、 碳酸氢钠 、 溶剂黄146 、 间氯过氧苯甲酸 、 copper dichloride 、 锌 作用下， 以 氯仿 、 甲苯 为溶剂， 反应 76.5h， 生成 trans,trans-bis(2-phenylvinyl) ether
  参考文献：
  名称：

  The photochemistry of bis(2,2-diphenylvinyl) ether: a search for the 3-oxadi-.pi.-methane rearrangement

  摘要：

  DOI：

  10.1021/jo00224a050

文献信息

• RECYCLABLE METATHESIS CATALYSTS
  申请人：Trustees of Boston College, The

  公开号：US20160168181A1

  公开（公告）日：2016-06-16

  Highly active, recoverable and recyclable transition metal-based metathesis catalysts and their organometallic complexes including dendrimeric complexes are disclosed, including a Ru complex bearing a 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene and styrenyl ether ligand. The heterocyclic ligand significantly enhances the catalytic activity, and the styrenyl ether allows for the easy recovery of the Ru complex. Derivatized catalysts capable of being immobilized on substrate surfaces are also disclosed. The present catalysts can be used to catalyze ring-closing metathesis (RCM), ring-opening (ROM) and cross metatheses (CM) reactions, and promote the efficient formation of various trisubstituted olefins at ambient temperature in high yield.

  高度活性、可回收和可循环使用的过渡金属基催化剂及其有机金属络合物，包括树枝状络合物被披露，包括一种带有1,3-二甲基-4,5-二氢咪唑-2-亚基和苯乙烯基醚配体的钌络合物。杂环配体显著提高了催化活性，而苯乙烯基醚使得钌络合物易于回收。还披露了能够固定在底物表面的衍生催化剂。所述催化剂可用于催化环闭合烯烃复分解反应(RCM)、环开环反应(ROM)和交叉复分解反应(CM)，并在室温下高效地促进各种三取代烯烃的高产形成。
• COMPOUNDS FOR ELECTRONIC DEVICES
  申请人：Parham Amir Hossain

  公开号：US20120292576A1

  公开（公告）日：2012-11-22

  The present invention relates to compounds of the formula (I) and to the use thereof in organic electronic devices, and to organic electronic devices which comprise compounds of the formula (I), preferably as hole-transport materials and/or as matrix materials, in particular in combination with a further matrix material.

  本发明涉及式(I)的化合物及其在有机电子器件中的应用，以及包括式(I)化合物的有机电子器件，优选作为空穴传输材料和/或作为基质材料，特别是与另一种基质材料结合使用。
• BRIDGED TRIARYLAMINES AND -PHOSPHINES AS MATERIALS FOR ELECTRONIC DEVICES
  申请人：Parham Amir Hossain

  公开号：US20130026422A1

  公开（公告）日：2013-01-31

  The present invention relates to a compound according to formula (I), to the use thereof in an electronic device and to an electronic device which comprises one or more compounds according to formula (I).

  本发明涉及根据公式(I)的化合物，其在电子设备中的用途，以及包含一个或多个根据公式(I)的化合物的电子设备。
• Hydrosilylation Reaction Catalysts and Curable Compositions and Methods for Their Preparation and Use
  申请人：Dow Corning Corporation

  公开号：US20140296468A1

  公开（公告）日：2014-10-02

  A composition contains (A) a hydrosilylation reaction catalyst and (B) an aliphatically unsaturated compound having an average, per molecule, of one or more aliphatically unsaturated organic groups capable of undergoing hydrosilylation reaction. The composition is capable of reacting via hydrosilylation reaction to form a reaction product, such as a silane, a gum, a gel, a rubber, or a resin. Ingredient (A) contains an iron-organosilicon ligand complex that can be prepared by reacting an iron carbonyl compound and an organosilicon ligand.

  一种组合物包含（A）一个氢硅烷基化反应催化剂和（B）一种脂肪族不饱和化合物，每个分子平均含有一个或多个能够进行氢硅烷基化反应的脂肪族不饱和有机基团。该组合物能够通过氢硅烷基化反应反应形成反应产物，如硅烷、树脂、凝胶、橡胶或树脂。成分（A）包含一种铁-有机硅配体络合物，可通过反应铁羰基化合物和有机硅配体制备。
• [EN] NANOPARTICLES FOR DRUG DELIVERY COMPRISING ALBUMIN HAVING A POLYMER CHAIN COUPLED THERETO<br/>[FR] NANOPARTICULES POUR ADMINISTRATION DE MÉDICAMENT COMPRENANT DE L'ALBUMINE POSSÉDANT UNE CHAÎNE POLYMÈRE COUPLÉE À CELLE-CI
  申请人：NEWSOUTH INNOVATIONS PTY LTD

  公开号：WO2014161031A1

  公开（公告）日：2014-10-09

  The invention provides a dispersion of assemblies. The assemblies comprise an albumin derivative comprising albumin having a polymer chain coupled thereto, wherein the assemblies comprise a core comprising the polymer chains and a shell comprising the albumin. A process for making the dispersion and methods of using the dispersion are also described.

  该发明提供了一种组装体的分散体。这些组装体包括一种白蛋白衍生物，其中白蛋白上连接有聚合物链，其中这些组装体包括一个核心，包括聚合物链，和一个外壳，包括白蛋白。还描述了制备该分散体的过程和使用该分散体的方法。