1-Adamantyl crotonate | 134690-47-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 1-Adamantyl crotonate
• 英文别名: 1-adamantyl (E)-but-2-enoate
• CAS: 134690-47-4
• 化学式: C₁₄H₂₀O₂
• 分子量: 220.312
• InChiKey: WYLTXRDVVWFURE-NSCUHMNNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  trans-crotonic anhydride 、 1-金刚烷醇 在 Acidic catalyst 作用下， 以 环己烷 为溶剂， 以95%的产率得到1-Adamantyl crotonate
  参考文献：
  名称：

  Otsu, Takayuki; Matsumoto, Akikazu; Horie, Atsushi, Chemistry Letters, 1991, # 7, p. 1145 - 1148

  摘要：

  DOI：

文献信息

• Polymer latex of high acrylonitrile content, film, pattern forming material and lithographic printing plate precursor using the same, and method for production of polymer latex
  申请人：FUJIFILM Corporation

  公开号：EP1905787A2

  公开（公告）日：2008-04-02

  A method for producing a polymer latex includes: mixing a polymerizable monomer in which acrylonitrile accounts for 70% by weight or more of a total of the polymerizable monomer, water and a polymerization initiator to conduct emulsion polymerization; and distilling off a monomer unpolymerized in the emulsion polymerization.

  生产聚合物胶乳的方法包括：混合可聚合单体（其中丙烯腈占可聚合单体总重量的 70% 或以上）、水和聚合引发剂，以进行乳液聚合；以及蒸馏掉乳液聚合中未聚合的单体。
• Process for producing acrylonitrile-containing polymer latex
  申请人：FUJIFILM Corporation

  公开号：EP1935910A2

  公开（公告）日：2008-06-25

  A process for producing a polymer latex includes a step of mixing at least one kind of polymerizable monomer with water and a polymerization initiator to perform a polymerization, wherein the at least one kind of polymerizable monomer includes an acrylonitrile in an amount of 50 mass% or more based on a total amount of the at least one kind of polymerizable monomer.

  一种生产聚合物胶乳的工艺包括将至少一种可聚合单体与水和聚合引发剂混合以进行聚合的步骤，其中至少一种可聚合单体包括丙烯腈，其用量为至少一种可聚合单体总量的 50 质量%或以上。
• ORGANOPOLYSILOXANE GRAFT POLYMER
  申请人：Kao Corporation

  公开号：EP2927253A1

  公开（公告）日：2015-10-07

  The present invention relates to an organopolysiloxane graft polymer including an organopolysiloxane segment as a main chain thereof and an unsaturated monomer-derived polymer segment as a side chain thereof, in which a content of the organopolysiloxane segment in the organopolysiloxane graft polymer is not less than 35% by mass and not more than 70% by mass, and the unsaturated monomer-derived polymer segment contains a repeating unit derived from a nonionic unsaturated monomer having a glass transition temperature Tg of 60°C or higher (except for a repeating unit derived from an unsaturated monomer containing an amino group) in an amount of not less than 40% by mass and not more than 90% by mass, and further contains a repeating unit derived from a cationic unsaturated monomer in an amount of not less than 10% by mass and not more than 60% by mass.

  本发明涉及一种有机聚硅氧烷接枝聚合物，包括作为其主链的有机聚硅氧烷段和作为其侧链的不饱和单体衍生聚合物段，其中有机聚硅氧烷段在有机聚硅氧烷接枝聚合物中的含量不低于35%（质量百分比）且不超过70%（质量百分比）、不饱和单体衍生的聚合物段含有由玻璃化转变温度 Tg 为 60°C 或更高的非离子不饱和单体衍生的重复单元（由含有氨基的不饱和单体衍生的重复单元除外），其含量不低于 40%（按质量计）且不超过 90%（按质量计），还含有由阳离子不饱和单体衍生的重复单元，其含量不低于 10%（按质量计）且不超过 60%（按质量计）。
• Pneumatic object provided with a gastight layer containing a thermoplastic elastomer and a thermoplastic
  申请人：Abad Vincent

  公开号：US10030131B2

  公开（公告）日：2018-07-24

  A pneumatic object or inflatable article is provided with a gastight elastomer layer. The gastight elastomer layer includes a thermoplastic polyisobutylene block elastomer and hot-melt polymer microdomains based on at least one thermoplastic material.

  气动物体或充气物品具有气密弹性体层。气密弹性体层包括热塑性聚异丁烯嵌段弹性体和基于至少一种热塑性材料的热熔聚合物微域。
• Organopolysiloxane graft polymer
  申请人：KAO CORPORATION

  公开号：US10195135B2

  公开（公告）日：2019-02-05

  The present invention relates to an organopolysiloxane graft polymer including an organopolysiloxane segment as a main chain thereof and an unsaturated monomer-derived copolymer segment containing a repeating unit derived from an unsaturated monomer containing a carboxylic acid or a carboxylic acid salt as a side chain thereof, in which a content of the organopolysiloxane segment in the organopolysiloxane graft polymer is 35 to 59% by mass, a content of the repeating unit derived from the unsaturated monomer containing a carboxylic acid or a carboxylic acid salt in the organopolysiloxane graft polymer is 4 to 17% by mass, and a content of a repeating unit derived from an unsaturated monomer whose homopolymer has a glass transition point of not lower than 150° C. (except for the unsaturated monomer containing a carboxylic acid or a carboxylic acid salt) in the organopolysiloxane graft polymer is not more than 14% by mass, and a number-average molecular weight of the organopolysiloxane segment is not less than 8,000 and not more than 200,000.

  本发明涉及一种有机聚硅氧烷接枝聚合物，包括作为主链的有机聚硅氧烷段和作为侧链的不饱和单体衍生共聚物段，其中不饱和单体衍生共聚物段含有从含有羧酸或羧酸盐的不饱和单体衍生的重复单元、其中有机聚硅氧烷接枝聚合物中有机聚硅氧烷段的含量为 35% 至 59%（按质量计），有机聚硅氧烷接枝聚合物中由含有羧酸或羧酸盐的不饱和单体衍生的重复单元的含量为 4% 至 17%（按质量计），以及由不饱和单体衍生的重复单元的含量，其均聚物的玻璃化转变点不低于 150°C。(有机聚硅氧烷接枝聚合物中不饱和单体（含有羧酸或羧酸盐的不饱和单体除外）的含量不超过 14% （以质量计），且有机聚硅氧烷段的数均分子量不低于 8,000 且不超过 200,000。