phenoxy-acetaldehyde-oxime | 135360-48-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: phenoxy-acetaldehyde-oxime
• 英文别名: Phenoxyacetaldoxim；Glykolaldehyd-phenylaether-oxim；Phenoxy-acetaldehyd-oxim；(NE)-N-(2-phenoxyethylidene)hydroxylamine
• CAS: 135360-48-4
• 化学式: C₈H₉NO₂
• 分子量: 151.165
• InChiKey: QWXILSSGGQEZDE-RMKNXTFCSA-N

物化性质

• 沸点：
  299.3±23.0 °C(Predicted)
• 密度：
  1.07±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  41.8
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  phenoxy-acetaldehyde-oxime 在 4-二甲氨基吡啶 、 吡啶硼烷 、 三乙胺 作用下， 以 甲醇 为溶剂， 反应 7.17h， 生成 N-Hydroxy-N-(2-phenoxy-ethyl)-acetamide
  参考文献：
  名称：

  Svoboda, Jiri; Palecek, Jaroslav, Collection of Czechoslovak Chemical Communications, 1991, vol. 56, # 6, p. 1317 - 1332

  摘要：

  DOI：
• 作为产物：
  描述：

  苯氧基乙醛乙酸二乙酯 在 硫酸 、 水 、 羟胺 作用下， 生成 phenoxy-acetaldehyde-oxime
  参考文献：
  名称：

  Pomeranz, Monatshefte fur Chemie, 1894, vol. 15, p. 740

  摘要：

  DOI：

文献信息

• AMINOETHYLATION PROCESS HAVING IMPROVED YIELD OF ARYLOXYALKYLENE AMINE COMPOUNDS AND REDUCED UREA BY-PRODUCTS
  申请人：McDougall Patrick J.

  公开号：US20140073814A1

  公开（公告）日：2014-03-13

  Disclosed is a process for preparing an aryloxyalkylene amine compound via an aminoethylation reaction comprising: a) reacting an aromatic hydroxyl compound in the presence of a basic catalyst with a 2-oxazolidinone compound of the formula II to form an intermediate reaction product; wherein R 3 is selected from the group consisting of hydrogen or lower alkyl having 1 to 6 carbon atoms, R 4 is selected from the group consisting of hydrogen, straight or branched chain alkyl having from one to six carbon atoms, phenyl, alkaryl, or arylalkyl; and b) reacting the intermediate product of step a) with a polyalkylene polyamine.

  揭示了一种通过氨基乙基化反应制备芳基氧基烷胺化合物的过程，包括：a)在碱性催化剂存在下，将芳香羟基化合物与式II的2-噁唑烷酮化合物反应，形成中间反应产物；其中R3选自氢或1至6个碳原子的较低烷基，R4选自氢、一元或分支链烷基（含1至6个碳原子）、苯基、烷基芳基或芳基烷基；b)将步骤a）中间产物与聚烷基聚胺反应。
• Substituted isoxazole alkylamine derivative and agri-and horticultural fungicide
  申请人：Shimozono Noriko

  公开号：US20050171358A1

  公开（公告）日：2005-08-04

  An agri-horticultural fungicide containing a substituted isoxazole alkylamine derivative represented by the formula (I) as an active ingredient exhibits no crossreaction with known drug resistant fungi and exerts a sufficient activity for preventing plant disease damages: wherein R 1 and R 2 each represent a hydrogen atom, a (substituted) alkyl, or the like; X is a single bond, alkylene, or the like; Y 1 represents a (substituted) lower alkyl, (substituted) cycloalkyl, (substituted) phenyl, (substituted) heteroaryl, or the like; Y 2 represents a (substituted) cycloalkyl, (substituted) phenyl, (substituted) heteroaryl, or the like; and Z represents a (substituted) alkylene, —O-((substituted)alkylene)-, —NR-((substituted)alkylene)- or the like.

  一种农业园艺杀菌剂，包含一种以式(I)表示的取代异噁唑烷基胺衍生物作为活性成分，不与已知的耐药真菌发生交叉反应，并具有足够的活性以预防植物疾病损害：其中R1和R2分别表示氢原子，（取代）烷基或类似物；X表示单键，烷基或类似物；Y1表示（取代）低级烷基，（取代）环烷基，（取代）苯基，（取代）杂环芳基或类似物；Y2表示（取代）环烷基，（取代）苯基，（取代）杂环芳基或类似物；Z表示（取代）烷基，-O-（（取代）烷基）-，-NR-（（取代）烷基）-或类似物。
• VISCOSITY IMPROVER GRAFTED WITH UNSATURATED ACYLATING AGENT AND AN ARYLOXYALYLKENE MONOAMINE
  申请人：McDougall Patrick J.

  公开号：US20140024567A1

  公开（公告）日：2014-01-23

  Disclosed is an oil-soluble lubricating oil additive composition, suitable for use as a dispersant viscosity index improver in lubricating oils; prepared by the process which comprises reacting a hydrocarbon polymer having a number average molecular weight (M n ) between about 7,000 and about 500,000 wherein the polymer backbone has been functionalized with an ethylenically unsaturated acylating agent and an aryloxy-alkylene amine.

  本发明公开了一种油溶性润滑油添加剂组合物，适用于用作润滑油中的分散剂粘度指数改进剂；所述组合物是通过以下过程制备的：反应具有约7,000至约500,000的数均分子量（Mn）的烃基聚合物，其中聚合物骨架已经被乙烯基不饱和酰化剂和芳基氧基-烷基胺官能化。
• Process for producing substituted phenoxyethylamines and intermediates
  申请人：UBE INDUSTRIES, LTD.

  公开号：EP0357310A1

  公开（公告）日：1990-03-07

  Disclosed are a process for producing a substituted phenoxyacetaldehyde oxime of the formula: (wherein R¹, R² and R³ are as defined in the specificat­ion), which comprises allowing a substituted phenoxyacet­aldehyde dialkylacetal of the formula: (wherein R¹, R², R³, R⁴ and R⁵ are as defined in the specification) to react with hydroxylamine; a process for producing a substituted phenoxyethylamine of the formula: (wherein R¹, R² and R³ are as defined in the specificat­ion), which comprises reducing a substituted phenoxyacet­aldehyde oxime of the formula (II) with hydrogen in the presence of a Raney-nickel catalyst; and a substituted phenoxyacetaldehyde oxime of the formula: (wherein R¹, R² and R⁶ are as defined in the specificat­ion).

  本发明公开了一种生产式如下的取代苯氧基乙醛肟的工艺： 其中R¹、R²和R³如说明书中所定义）的工艺，该工艺包括允许式中的取代的苯氧基乙醛二烷基乙缩醛(其中R¹、R²、R³、R⁴和R⁵如说明书中所定义)： (其中 R¹、R²、R³、R⁴ 和 R⁵ 如说明书中所定义）与羟胺反应； 一种生产式如下的取代苯氧基乙胺的工艺 (其中 R¹、R² 和 R³ 如说明书中所定义），该工艺包括在雷尼-镍催化剂存在下用氢还原式 (II) 的取代的苯氧基乙醛肟；以及 式中的取代苯氧基乙醛肟： (其中 R¹、R² 和 R⁶ 如说明书中所定义）。
• Synergistic lubricating oil composition containing a mixture of olefin copolymer dispersant-type viscosity improver and amine compound
  申请人：Chevron Oronite Company LLC

  公开号：US10414999B2

  公开（公告）日：2019-09-17

  Disclosed is an internal combustion engine lubricating oil composition which comprises (a) a major amount of an oil of lubricating viscosity; (b) a dispersant-type olefin copolymer VI improver; and (c) a secondary hydrocarbylamine compound, a tertiary hydrocarbylamine compound, or combinations thereof. A method for reducing cam wear using same is also disclosed.

  本发明公开了一种内燃机润滑油组合物，它包含：(a) 一种润滑粘度油的主要成分；(b) 一种分散剂型烯烃共聚物 VI 改良剂；以及 (c) 一种仲烃基胺化合物、一种叔烃基胺化合物或它们的组合。此外，还公开了一种使用该制剂减少凸轮磨损的方法。