2-(2,6-bis((E)-4-(diethylamino)-2-((6-hydroxyhexyl)oxy)styryl)-4H-pyran-4-ylidene)malononitrile | 1358918-78-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2-(2,6-bis((E)-4-(diethylamino)-2-((6-hydroxyhexyl)oxy)styryl)-4H-pyran-4-ylidene)malononitrile
• 英文别名: 2-[2,6-bis[(E)-2-[4-(diethylamino)-2-(6-hydroxyhexoxy)phenyl]ethenyl]pyran-4-ylidene]propanedinitrile
• CAS: 1358918-78-1
• 化学式: C₄₄H₅₈N₄O₅
• 分子量: 722.968
• InChiKey: IHOXOHYOACVOBE-BLVCXSLXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.3
• 重原子数：
  53
• 可旋转键数：
  24
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  122
• 氢给体数：
  2
• 氢受体数：
  9

反应信息

• 作为反应物：
  描述：

  2-(2,6-bis((E)-4-(diethylamino)-2-((6-hydroxyhexyl)oxy)styryl)-4H-pyran-4-ylidene)malononitrile 、 异氰酸丙基三乙氧基硅烷 反应 6.0h， 生成 6-[2-[(E)-2-[4-(dicyanomethylidene)-6-[(E)-2-[4-(diethylamino)-2-[6-(3-triethoxysilylpropylcarbamoyloxy)hexoxy]phenyl]ethenyl]pyran-2-yl]ethenyl]-5-(diethylamino)phenoxy]hexyl N-(3-triethoxysilylpropyl)carbamate
  参考文献：
  名称：

  Thermally Stable, Dye-Bridged Nanohybrid-Based White Light-Emitting Diodes

  摘要：

  Thermally stable red and green light-emitting nanohybrids are introduced as an organic luminescent converter with broad color tunability and a high color rendering index for white light-emitting diodes (LEDs). Nanohybrid-based white LEDs are thermally stable and the color coordination is not changed by heat exposure.

  DOI：

  10.1002/adma.201103077
• 作为产物：
  描述：

  6-溴正己醇 在 哌啶 、 potassium hydroxide 作用下， 以 四氢呋喃 、 乙腈 为溶剂， 反应 15.0h， 生成 2-(2,6-bis((E)-4-(diethylamino)-2-((6-hydroxyhexyl)oxy)styryl)-4H-pyran-4-ylidene)malononitrile
  参考文献：
  名称：

  Thermally Stable, Dye-Bridged Nanohybrid-Based White Light-Emitting Diodes

  摘要：

  Thermally stable red and green light-emitting nanohybrids are introduced as an organic luminescent converter with broad color tunability and a high color rendering index for white light-emitting diodes (LEDs). Nanohybrid-based white LEDs are thermally stable and the color coordination is not changed by heat exposure.

  DOI：

  10.1002/adma.201103077

文献信息

• Thermally Stable, Dye-Bridged Nanohybrid-Based White Light-Emitting Diodes
  作者：Seung-Yeon Kwak、SeungCheol Yang、Na Ree Kim、Jae Hong Kim、Byeong-Soo Bae

  DOI：10.1002/adma.201103077

  日期：2011.12.22

  Thermally stable red and green light-emitting nanohybrids are introduced as an organic luminescent converter with broad color tunability and a high color rendering index for white light-emitting diodes (LEDs). Nanohybrid-based white LEDs are thermally stable and the color coordination is not changed by heat exposure.