N,N'-bis(thiazol-2-ylmethylene)cyclohexane-trans-1,2-diamine | 353797-81-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: N,N'-bis(thiazol-2-ylmethylene)cyclohexane-trans-1,2-diamine
• 英文别名: 1-(1,3-thiazol-2-yl)-N-[(1S,2S)-2-(1,3-thiazol-2-ylmethylideneamino)cyclohexyl]methanimine
• CAS: 353797-81-6
• 化学式: C₁₄H₁₆N₄S₂
• 分子量: 304.44
• InChiKey: AECAHUJQWOVGIF-RYUDHWBXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  20
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  107
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  N,N'-bis(thiazol-2-ylmethylene)cyclohexane-trans-1,2-diamine 在 sodium tetrahydroborate 作用下， 以 乙醇 为溶剂， 反应 18.0h， 以1.01 g的产率得到trans-N,N'-bis(thiazol-2-ylmethylene)-1,2-diaminocyclohexane
  参考文献：
  名称：

  Molybdenum complexes of chiral C2-symmetric picchxn-type ligands: Synthesis, characterization, and structural studies

  摘要：

  A series of molybdenum complexes based on chiral C-2-symmetric picchxn-type ligands (N-4 ligands, defined as trans-N,N'-bis(heterocycl-2-ylmethyl)-1,2-diaminocyclohexanes) has been synthesized and characterized. Reported and novel picchxn-type ligands form (kappa(3)-N4)Mo(CO)(3), [(kappa(4)-N-4)Mo(NO)(CO)] PF6, and [(kappa(4)-N-4)Mo(NO)X]PF6 (X = Br, I) compounds. Multiple tridentate (kappa(3)) and tetradentate (kappa(4)) ligand configurations were observed, and the favored kappa(4) configuration was found to vary with N-4 heterocycle identity. Heterocycle variation allowed for directed modification of the molybdenum electronic characteristics, but none of the studied {(kappa(4)-N-4)Mo(NO)}(+) fragments was found to be a suitable pi-base for dearomatization chemistry. The crystal structures of eight molybdenum complexes with picchxn-type ligands were determined. (C) 2015 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2015.09.005
• 作为产物：
  描述：

  2-醛基噻唑 、 trans-1,2-Diaminocyclohexane 以 水 、 N,N-二甲基甲酰胺 为溶剂， 反应 144.0h， 以84.3%的产率得到N,N'-bis(thiazol-2-ylmethylene)cyclohexane-trans-1,2-diamine
  参考文献：
  名称：

  Molybdenum complexes of chiral C2-symmetric picchxn-type ligands: Synthesis, characterization, and structural studies

  摘要：

  A series of molybdenum complexes based on chiral C-2-symmetric picchxn-type ligands (N-4 ligands, defined as trans-N,N'-bis(heterocycl-2-ylmethyl)-1,2-diaminocyclohexanes) has been synthesized and characterized. Reported and novel picchxn-type ligands form (kappa(3)-N4)Mo(CO)(3), [(kappa(4)-N-4)Mo(NO)(CO)] PF6, and [(kappa(4)-N-4)Mo(NO)X]PF6 (X = Br, I) compounds. Multiple tridentate (kappa(3)) and tetradentate (kappa(4)) ligand configurations were observed, and the favored kappa(4) configuration was found to vary with N-4 heterocycle identity. Heterocycle variation allowed for directed modification of the molybdenum electronic characteristics, but none of the studied {(kappa(4)-N-4)Mo(NO)}(+) fragments was found to be a suitable pi-base for dearomatization chemistry. The crystal structures of eight molybdenum complexes with picchxn-type ligands were determined. (C) 2015 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2015.09.005

文献信息

• Electrochemical Assembling/Disassembling of Helicates with Hysteresis
  作者：Valeria Amendola、Luigi Fabbrizzi、Luca Gianelli、Cristina Maggi、Carlo Mangano、Piersandro Pallavicini、Michele Zema

  DOI：10.1021/ic001155a

  日期：2001.7.1

  their complexes with Cu(I) and Cu(II), have been studied in CH(3)CN solution, by means of (1)H NMR, mass, and UV/vis spectroscopy, while the crystal and molecular structure of the Cu(II) complexes [Cu(3)](CF(3)SO(3))(2) and [Cu(4)](CF(3)SO(3))(2) and of the Cu(I) complexes [Cu(2)(4)(2)](ClO(4))(2) and [Cu(2)(5)(2)](ClO(4))(2) have been determined by X-ray diffraction methods. The Cu(II) complexes are

  借助（1）H NMR在CH（3）CN溶液中研究了一系列八种四齿，对位，双环双歧双歧环配体（1-8）及其与Cu（I）和Cu（II）的配合物，质量和紫外/可见光谱，而Cu（II）配合物的晶体和分子结构[Cu（3）] [CF（3）SO（3））（2）和[Cu（4）]（CF （3）SO（3））（2）和Cu（I）络合物的[Cu（2）（4）（2）]（ClO（4））（2）和[Cu（2）（5）（ 2）]（ClO（4））（2）已通过X射线衍射法测定。Cu（II）络合物是单体的，几乎呈正方形的结构，无论是在溶液中还是在固态，而Cu（I）络合物是两种金属，两个配体的二聚体，它们可以是螺旋形，也可以是“盒状”在固体中，而它们在乙腈溶液中采用简单的螺旋构型。由配体1-8和铜构成的系统是双稳态的，如在相同条件下，可以获得Cu（I）螺旋二聚体或Cu（II）单体并且它们是稳定的。通过循环伏安法研究了16种铜配合物在乙腈溶液