4,5-Dipentylbenzene-1,2-diol | 162131-32-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 4,5-Dipentylbenzene-1,2-diol
• CAS: 162131-32-0
• 化学式: C₁₆H₂₆O₂
• 分子量: 250.381
• InChiKey: YUQOPYBFYQJNOE-UHFFFAOYSA-N

物化性质

• 沸点：
  389.8±37.0 °C(Predicted)
• 密度：
  0.997±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  18
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4-(N-壬基氧基)苯硼酸 、 4,5-Dipentylbenzene-1,2-diol 在 原甲酸三甲酯 作用下， 以52%的产率得到2-(4-Nonoxyphenyl)-5,6-dipentyl-1,3,2-benzodioxaborole
  参考文献：
  名称：

  TOWARD BORONATE ESTER MESOGENIC STRUCTURES

  摘要：

  This article describes efforts toward the development of a new core for calamitic mesogens based upon the introduction of an extended heteroaromatic boron-containing ring. A series of tri-catenar mesogenic boronate ester derivatives of the 2-phenyl-1,3,2-benzodioxaborole has been synthesized and characterized. The flat central core appeared to be a suitable feature for these derivatives to support anisotropic alignment. Additionally, these derivatives should possess an inherent dipole in the core. However, thermal analysis (polarized optical microscopy and differential scanning calorimetry) did not reveal any mesophases.

  DOI：

  10.1080/15421400390223158
• 作为产物：
  描述：

  胡椒环 在 palladium on activated charcoal aluminum tri-bromide 、 氢溴酸 、 氢气 、 乙醇锂 、 溶剂黄146 、 乙硫醇 作用下， 以 甲醇 、 乙醇 、 氯仿 、 N,N-二甲基甲酰胺 为溶剂， 反应 83.0h， 生成 4,5-Dipentylbenzene-1,2-diol
  参考文献：
  名称：

  TOWARD BORONATE ESTER MESOGENIC STRUCTURES

  摘要：

  This article describes efforts toward the development of a new core for calamitic mesogens based upon the introduction of an extended heteroaromatic boron-containing ring. A series of tri-catenar mesogenic boronate ester derivatives of the 2-phenyl-1,3,2-benzodioxaborole has been synthesized and characterized. The flat central core appeared to be a suitable feature for these derivatives to support anisotropic alignment. Additionally, these derivatives should possess an inherent dipole in the core. However, thermal analysis (polarized optical microscopy and differential scanning calorimetry) did not reveal any mesophases.

  DOI：

  10.1080/15421400390223158

文献信息

• Soluble late transition metal catalysts for olefin oligomerizations III
  申请人：Zhao Baiyi

  公开号：US20060036049A1

  公开（公告）日：2006-02-16

  A series of soluble α-diimine late transition metal catalysts has been invented comprising a substituted or unsubstituted catecholate ligand. The catalysts demonstrate high activity and selectivity for linear α-olefins. As such, these catalysts conveniently oligomerize ethylene. Typical activators as known to those of ordinary skill in the art are used to activate these transition metal catalysts. These catalysts can be used in a supported or unsupported form.

  一系列可溶性的α-二亚胺后过渡金属催化剂已经被发明，其中包括取代或未取代的邻苯二酚配体。这些催化剂表现出高活性和线性α-烯烃的高选择性。因此，这些催化剂方便地可以使乙烯寡聚化。通常的活化剂，如对于普通技术人员而言是已知的，被用来激活这些过渡金属催化剂。这些催化剂可以以支持或不支持的形式使用。
• SOLUBLE LATE TRANSITION METAL CATALYSTS FOR OLEFIN OLIGOMERIZATIONS III
  申请人：ExxonMobil Chemical Patents Inc.

  公开号：EP1620447A1

  公开（公告）日：2006-02-01
• [EN] SOLUBLE LATE TRANSITION METAL CATALYSTS FOR OLEFIN OLIGOMERIZATIONS III<br/>[FR] CATALYSEURS A BASE DE METAUX DE TRANSITION TARDIFS SOLUBLES POUR OLIGOMERISATIONS III D'OLEFINES
  申请人：EXXONMOBIL CHEM PATENTS INC

  公开号：WO2003102006A1

  公开（公告）日：2003-12-11

  A series of soluble a-diimine late transition metal catalysts has been invented comprising a substituted or unsubstituted catecholate ligand. The catalysts demon­strate high activity and selectivity for linear a-olefins. As such, these catalysts con­veniently oligomerize ethylene. Typical activators as known to those of ordinary skill in the art are used to activate these transition metal catalysts. These catalysts can be used in a supported or unsupported form.
• TOWARD BORONATE ESTER MESOGENIC STRUCTURES
  作者：Maura Belloni、M. Manickam、Zehn-He Wang、Jon A. Preece

  DOI：10.1080/15421400390223158

  日期：2003.1.1

  This article describes efforts toward the development of a new core for calamitic mesogens based upon the introduction of an extended heteroaromatic boron-containing ring. A series of tri-catenar mesogenic boronate ester derivatives of the 2-phenyl-1,3,2-benzodioxaborole has been synthesized and characterized. The flat central core appeared to be a suitable feature for these derivatives to support anisotropic alignment. Additionally, these derivatives should possess an inherent dipole in the core. However, thermal analysis (polarized optical microscopy and differential scanning calorimetry) did not reveal any mesophases.