diethyl 2,5-di(naphth-1-yl)terephthalate | 913175-30-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: diethyl 2,5-di(naphth-1-yl)terephthalate
• 英文别名: Diethyl 2,5-dinaphth-1-ylterephthalate；diethyl 2,5-dinaphthalen-1-ylbenzene-1,4-dicarboxylate
• CAS: 913175-30-1
• 化学式: C₃₂H₂₆O₄
• 分子量: 474.556
• InChiKey: HTAMMNVVCBGHJT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.1
• 重原子数：
  36
• 可旋转键数：
  8
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  diethyl 2,5-di(naphth-1-yl)terephthalate 在 盐酸 、 正丁基锂 、 溶剂黄146 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 16.0h， 生成 14,14,28,28-Tetrakis(4-methylphenyl)heptacyclo[15.11.0.03,15.04,13.05,10.018,27.019,24]octacosa-1(17),2,4(13),5,7,9,11,15,18(27),19,21,23,25-tridecaene
  参考文献：
  名称：

  Coplanarity in the Backbones of Ladder-type Oligo(p-phenylene) Homologues and Derivatives

  摘要：

  p-Tolyl-substituted ladder-type oligo(p-phenylene) s containing three, four, and five phenylene rings were readily synthesized. The uniform aryl substitution of these systems allowed us to determine the coplanarity of the d-conjugated backbones crystallographically. The intramolecular annulations eliminate almost all of the conformational disorder and enhance the degree of d-conjugation of the backbones, resulting in significant red shifts in the absorption and emission maxima and lower oxidation potentials in the higher homologues.

  DOI：

  10.1021/ol061762n
• 作为产物：
  描述：

  2,5-二溴对苯二甲酸二乙酯 、 1-萘硼酸频呐醇酯 在 potassium phosphate 、 四(三苯基膦)钯 、 三叔丁基膦 作用下， 以 甲苯 为溶剂， 反应 2.0h， 以94%的产率得到diethyl 2,5-di(naphth-1-yl)terephthalate
  参考文献：
  名称：

  Coplanarity in the Backbones of Ladder-type Oligo(p-phenylene) Homologues and Derivatives

  摘要：

  p-Tolyl-substituted ladder-type oligo(p-phenylene) s containing three, four, and five phenylene rings were readily synthesized. The uniform aryl substitution of these systems allowed us to determine the coplanarity of the d-conjugated backbones crystallographically. The intramolecular annulations eliminate almost all of the conformational disorder and enhance the degree of d-conjugation of the backbones, resulting in significant red shifts in the absorption and emission maxima and lower oxidation potentials in the higher homologues.

  DOI：

  10.1021/ol061762n

文献信息

• Materials for organic electroluminescent devices
  申请人：Buesing Arne

  公开号：US08932732B2

  公开（公告）日：2015-01-13

  The present invention relates to organic electroluminescent devices, in particular blue-emitting devices, in which compounds of the formulae (1) to (4) are used as host material or dopant in the emitting layer and/or as hole-transport material and/or as electron-transport material.

  本发明涉及有机电致发光器件，特别是蓝色发光器件，其中式（1）至（4）的化合物被用作发射层中的主体材料或掺杂剂，或作为空穴传输材料和/或电子传输材料。
• MATERIALS FOR ORGANIC ELECTROLUMINESCENT DEVICES
  申请人：Buesing Arne

  公开号：US20090184313A1

  公开（公告）日：2009-07-23

  The present invention relates to organic electroluminescent devices, in particular blue-emitting devices, in which compounds of the formulae (1) to (4) are used as host material or dopant in the emitting layer and/or as hole-transport material and/or as electron-transport material.

  本发明涉及有机电致发光器件，特别是蓝色发射器件，其中化合物式（1）至（4）的化合物作为发射层中的主体材料或掺杂剂，或作为空穴传输材料和/或电子传输材料。
• MATERIALIEN FÜR ORGANISCHE ELEKTROLUMINESZENZVORRICHTUNGEN
  申请人：Merck Patent GmbH

  公开号：EP2024310A1

  公开（公告）日：2009-02-18
• POLYMERS COMPRISING STRUCTURAL UNITS WHICH CONTAIN ALKYLALKOXY GROUPS, BLENDS COMPRISING THESE POLYMERS, AND OPTO-ELECTRONIC DEVICES COMPRISING THESE POLYMERS AND BLENDS
  申请人：Meyer Frank Egon

  公开号：US20120097938A1

  公开（公告）日：2012-04-26

  The present invention relates to polymers comprising structural units which contain alkylalkoxy groups, and blends which comprise the polymers according to the invention. The invention is also directed to the use of the polymers and blends according to the invention in opto-electronic devices and to these devices themselves.
• US8932732B2
  申请人：——

  公开号：US8932732B2

  公开（公告）日：2015-01-13