1-Methyl-2-[3-(1-methylimidazol-2-yl)phenyl]imidazole | 949097-24-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 1-Methyl-2-[3-(1-methylimidazol-2-yl)phenyl]imidazole
• CAS: 949097-24-9
• 化学式: C₁₄H₁₄N₄
• 分子量: 238.292
• InChiKey: MZWLDOBMTAYZMC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  35.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-碘-1-甲基-1H-咪唑 、 1,3-双苯二硼酸频那醇酯 在 palladium diacetate 、 三苯基膦 potassium carbonate 作用下， 以 乙二醇二甲醚 、 水 为溶剂， 反应 24.0h， 以34%的产率得到1-Methyl-2-[3-(1-methylimidazol-2-yl)phenyl]imidazole
  参考文献：
  名称：

  Platinum (II) Di (2-Pyrazolyl) Benzene Chloride Analogs and Uses

  摘要：

  合成铂（II）二（2-吡唑基）苯氯化物及类似物包括形成一个1,3-二取代苯，其中包括两个芳香的五元杂环，并将这个1,3-二取代苯与含铂的酸性溶液反应，形成一种发光的铂（II）配合物。这种发光的铂（II）配合物能够发出蓝色和白色光，并可用作发光装置中的发射体。

  公开号：

  US20110301351A1

文献信息

• Single-flask preparation of polyazatriaryl ligands by sequential borylation/Suzuki–Miyaura coupling
  作者：Bertoldo Avitia、Eric MacIntosh、Samuel Muhia、Eric Kelson

  DOI：10.1016/j.tetlet.2011.01.136

  日期：2011.4

  We report a convenient single-flask methodology for the preparation of polyazatriaryl products with relevance to luminescence, catalysis, and pharmacology. The diborylation of 1,3-dibromobenzenes and double Suzuki-Miyaura coupling produces 1,3-diheteroarylbenzenes. Similarly, borylation of heteroaryl halides and double coupling to 2,6-clichloropyridine produces 2,6-diheteroarylpyridines. This methodology appears general in producing challenging polyheteroaryl targets as long as the boronic esters have no ortho heteroatoms and coupling avoids adjacent oxygens. (C) 2011 Elsevier Ltd. All rights reserved.
• Metal complex compound and organic electroluminescence device using the compound
  申请人：Haga Masa-aki

  公开号：US20070210699A1

  公开（公告）日：2007-09-13

  A metal-complex compound which comprises a tridentate chelate ligand having a specified partial structure. An organic electroluminescence device which comprises one or more organic thin film layers having at least one light emitting layer sandwiched between a pair of electrodes, wherein the organic thin film layer comprises the metal-complex compound, which emits light by applying an electric voltage between the pair of electrodes. The present invention provides an organic EL device which emits blue light of high purity and of short wavelength together with a metal-complex compound realizing the organic EL device.