(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)dibromo(2,4,6-triisopropylphenyl)germane | 162088-75-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)dibromo(2,4,6-triisopropylphenyl)germane
• 英文别名: [[3,5-Bis[bis(trimethylsilyl)methyl]-2-[dibromo-[2,4,6-tri(propan-2-yl)phenyl]germyl]phenyl]-trimethylsilylmethyl]-trimethylsilane
• CAS: 162088-75-7
• 化学式: C₄₂H₈₂Br₂GeSi₆
• 分子量: 988.024
• InChiKey: ZDPRTLUKEQABHZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.92
• 重原子数：
  51
• 可旋转键数：
  14
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)dibromo(2,4,6-triisopropylphenyl)germane 在 LiC₁₀H₈ 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 生成 [2,4,6-tris[bis(trimethylsilyl)methyl]phenyl](2,4,6-triisopropylphenyl)germanethione
  参考文献：
  名称：

  第一个动力学稳定的锗硫酮和锗烯酮：合成、结构和反应性

  摘要：

  合成了第一个动力学稳定的锗硫酮（锗-硫双键物种）和锗烷酮（锗-硒双键物种）。新型 1,2,3,4,5-四硫属元素格尔莫烷 Tbt(Tip)GeX4（Tbt = 2,4,6-三[双（三甲基甲硅烷基）甲基]苯基，Tip = 2,4,6-三异丙基苯基，X）的脱硫= S 或 Se) 与 3 摩尔当量的三苯基膦得到二芳基取代的锗硫酮 Tbt(Tip)GeS 1a 和锗烷硫酮 Tbt(Tip)GeSe 2a 分别为橙黄色晶体和红色晶体，它们在空气中不稳定但热稳定. 锗烯 Tbt(Dis)Ge 的硫氢化作用：导致分离出相应的锗烷硫酮 Tbt(Dis)GeS 1b 和锗烷硫酮 Tbt(Dis)GeSe 2b（Dis = 双（三甲基甲硅烷基）甲基）。锗烷硫酮 1a 和锗烷硫酮 2a 的分子结构，

  DOI：

  10.1021/ja991147x
• 作为产物：
  描述：

  1-bromo-2,4,6-tris[bis(trimethylsilyl)methyl]benzene 在 t-BuLi 、 NH₄Cl 作用下， 以 四氢呋喃 、 水 、 正戊烷 、 苯 为溶剂， 生成 (2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)dibromo(2,4,6-triisopropylphenyl)germane
  参考文献：
  名称：

  Synthesis and Structure of Novel Germanium-Containing Cyclic Polysulfides

  摘要：

  Novel germanium-containing cyclic polysulfides 1,2,3,4,5-tetrathiagermolane 5 (Tbt(Ar)GeS4; Tbt = 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl; Ar = mesityl, 2,6-diethylphenyl, 2,4,6-triisopropylphenyl) have been synthesized, and the molecular structure of Tbt(Mes)GeS4 was determined by X-ray crystallographic analysis. Reaction of the tetrathiagermolanes 5 with diphenyldiazomethane gave 1,2,3,5-tetrathia-4-germacyclopentanes 10, 1,2,4,5-tetrathia-3-germacyclohexanes 11, and 1,2,4-trithia-3-germacyclopentanes 12. The structure of 1,2,3,5-tetrathia-4-germacyclohexane 10a was determined by X-ray structural analysis.

  DOI：

  10.1021/om00002a055

文献信息

• Synthesis and structure of the first germaketenedithioacetal
  作者：Norihiro Tokitoh、Kuniyuki Kishikawa、Renji Okazaki

  DOI：10.1039/c39950001425

  日期：——

  Treatment of an overcrowded diarylgermylene Tbt(Tip)Ge: 1Tbt = 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl, Tip = 2,4,6-triisopropylphenyl} with carbon disulfide affords the first germaketenedithioacetal derivative 3 as a stable orange crystalline compound, for which the molecular structure is established by X-ray crystallographic analysis.

  用二硫化碳处理过度拥挤的二芳基锗 Tbt(Tip)Ge：1Tbt = 2,4,6-三[双（三甲基硅基）甲基]苯基，Tip = 2,4,6-三异丙基苯基}与二硫化碳处理后，得到了第一种稳定的橙色结晶化合物--胚芽酮二硫代乙醛衍生物 3，并通过 X 射线晶体分析法确定了其分子结构。
• First oxazagermete: synthesis, structure and thermal cycloreversion into a germanone
  作者：Tsuyoshi Matsumoto、Norihiro Tokitoh、Renji Okazaki

  DOI：10.1039/a703241b

  日期：——

  A novel four-membered ring compound, 1,2,4-oxazagermete, is obtained by the reaction of diarylgermylene tbt(tip)Ge: with mesitonitrile oxide; its thermolysis generates germanone tbt(tip)GeO as evidenced by trapping reactions with dimethylbutadiene and ethanol.

  通过二芳基锗 tbt(tip)Ge：与氧化间苯二腈的反应，得到了一种新的四元环化合物--1,2,4-噁唑锗；通过与二甲基丁二烯和乙醇的捕获反应，证明其热解生成了锗酮 tbt(tip)GeO。
• Matsumoto Tsuyoshi, Kishikawa Kuniyuki, Tokitoh Norihiro, Okazaki Renji, Phosph., Sulfur and Silicon and Relat. Elem., 93-94 (1994) N 1-4, S 177-1+
  作者：Matsumoto Tsuyoshi, Kishikawa Kuniyuki, Tokitoh Norihiro, Okazaki Renji

  DOI：——

  日期：——
• The First Kinetically Stabilized Germanethiones and Germaneselones:  Syntheses, Structures, and Reactivities
  作者：Tsuyoshi Matsumoto、Norihiro Tokitoh、Renji Okazaki

  DOI：10.1021/ja991147x

  日期：1999.9.1

  of the novel 1,2,3,4,5-tetrachalcogenagermolane Tbt(Tip)GeX4 (Tbt = 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl, Tip = 2,4,6-triisopropylphenyl, X = S or Se) with 3 molar equiv of triphenylphosphine gave diaryl-substituted germanethione Tbt(Tip)GeS 1a and germaneselone Tbt(Tip)GeSe 2a as orange−yellow crystals and red crystals, respectively, which were unstable in air but thermally quite stable. Chalcogenation

  合成了第一个动力学稳定的锗硫酮（锗-硫双键物种）和锗烷酮（锗-硒双键物种）。新型 1,2,3,4,5-四硫属元素格尔莫烷 Tbt(Tip)GeX4（Tbt = 2,4,6-三[双（三甲基甲硅烷基）甲基]苯基，Tip = 2,4,6-三异丙基苯基，X）的脱硫= S 或 Se) 与 3 摩尔当量的三苯基膦得到二芳基取代的锗硫酮 Tbt(Tip)GeS 1a 和锗烷硫酮 Tbt(Tip)GeSe 2a 分别为橙黄色晶体和红色晶体，它们在空气中不稳定但热稳定. 锗烯 Tbt(Dis)Ge 的硫氢化作用：导致分离出相应的锗烷硫酮 Tbt(Dis)GeS 1b 和锗烷硫酮 Tbt(Dis)GeSe 2b（Dis = 双（三甲基甲硅烷基）甲基）。锗烷硫酮 1a 和锗烷硫酮 2a 的分子结构，
• Synthesis and Structure of Novel Germanium-Containing Cyclic Polysulfides
  作者：Tsuyoshi Matsumoto、Norihiro Tokitoh、Renji Okazaki、Midori Goto

  DOI：10.1021/om00002a055

  日期：1995.2

  Novel germanium-containing cyclic polysulfides 1,2,3,4,5-tetrathiagermolane 5 (Tbt(Ar)GeS4; Tbt = 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl; Ar = mesityl, 2,6-diethylphenyl, 2,4,6-triisopropylphenyl) have been synthesized, and the molecular structure of Tbt(Mes)GeS4 was determined by X-ray crystallographic analysis. Reaction of the tetrathiagermolanes 5 with diphenyldiazomethane gave 1,2,3,5-tetrathia-4-germacyclopentanes 10, 1,2,4,5-tetrathia-3-germacyclohexanes 11, and 1,2,4-trithia-3-germacyclopentanes 12. The structure of 1,2,3,5-tetrathia-4-germacyclohexane 10a was determined by X-ray structural analysis.