1-pyrenyltrichlorosilane | 136687-79-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: 1-pyrenyltrichlorosilane
• 英文别名: 1-trichlorosilylpyrene；1-trychlorosilylpyrene；1-Trichlorosilylpyrene；trichloro(pyren-1-yl)silane
• CAS: 136687-79-1
• 化学式: C₁₆H₉Cl₃Si
• 分子量: 335.692
• InChiKey: VKELFFBBMBRBHX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.45
• 重原子数：
  20
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  三硅醇苯基-笼形聚倍半硅氧烷 、 1-pyrenyltrichlorosilane 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 以29%的产率得到(1-pyrenyl)phenyl₇Si₈O₁₂
  参考文献：
  名称：

  Asymmetric aryl polyhedral oligomeric silsesquioxanes (ArPOSS) with enhanced solubility

  摘要：

  Four new asymmetric Polyhedral Oligomeric SilSesquioxanes (POSS) with the formula (Aryl)Phenyl(7)-Si(8)O(12), where Aryl = 1-naphthyl, 2-naphthyl, 9-phenanthrenyl, and 1-pyrenyl, have been synthesized in reasonable yield and high purity. These compounds were characterized with (1)H, (13)C, (29)Si NMR and elemental combustion analysis. These compounds possess polycyclic aromatic functionality, which disrupts symmetry to improve solubility in organic solvents and aromatic polymers, without significant impact on thermal stability. Published by Elsevier B. V.

  DOI：

  10.1016/j.jorganchem.2011.03.035
• 作为产物：
  描述：

  1-溴芘 在 正丁基锂 、 四氯化硅 作用下， 以 四氢呋喃 、 乙醚 、 正己烷 为溶剂， 反应 26.0h， 以48%的产率得到1-pyrenyltrichlorosilane
  参考文献：
  名称：

  Synthesis and applications of peripherally asymmetric aryl POSS compounds

  摘要：

  描述了通过苯基三氯硅烷对苯基多面体寡聚硅氧烷（ArPoss）化合物进行“角端封”合成。ArPoss化合物具有化学结构：其中Ph是苯基，R选自以下组合之一：以及它们的混合物。

  公开号：

  US09012673B1

文献信息

• Synthesis and applications of peripherally asymmetric aryl POSS compounds
  申请人：The United States of America, as represented by the Secretary of the Air Force

  公开号：US09012673B1

  公开（公告）日：2015-04-21

  Asymmetric aryl polyhedral oligomeric silsesquioxanes (ArPoss) compounds synthesized by the “corner-capping” of phenyl7Si7O9(OH)3 with aryl trichlorosilanes are described. The ArPoss compounds have the chemical structure: wherein Ph is phenyl and wherein R is selected from the group consisting of: and mixtures thereof.

  描述了通过苯基三氯硅烷对苯基多面体寡聚硅氧烷（ArPoss）化合物进行“角端封”合成。ArPoss化合物具有化学结构：其中Ph是苯基，R选自以下组合之一：以及它们的混合物。
• SYNTHESIS AND APPLICATIONS OF PERIPHERALLY ASYMMETRIC ARYL POSS COMPOUNDS
  申请人：Government of the United States as Represented by the Secretary of the Air Force

  公开号：US20150239915A1

  公开（公告）日：2015-08-27

  A method of synthesizing peripherally asymmetric aryl polyhedral oligomeric silsesquioxane (ArPOSS) compounds. The method comprises: wherein Ph is phenyl and wherein R is 1-napthyl, 2-naphthyl, 9-anthracenyl, 9-phenanthrenyl, 1-pryeyl, and mixtures thereof.

  一种合成外周不对称芳基聚八面体硅氧烷（ArPOSS）化合物的方法。该方法包括：其中Ph是苯基，R是1-萘基，2-萘基，9-蒽基，9-菲基，1-芘基和其混合物。
• Asymmetric aryl polyhedral oligomeric silsesquioxanes (ArPOSS) with enhanced solubility
  作者：Brian M. Moore、Sean M. Ramirez、Gregory R. Yandek、Timothy S. Haddad、Joseph M. Mabry

  DOI：10.1016/j.jorganchem.2011.03.035

  日期：2011.7

  Four new asymmetric Polyhedral Oligomeric SilSesquioxanes (POSS) with the formula (Aryl)Phenyl(7)-Si(8)O(12), where Aryl = 1-naphthyl, 2-naphthyl, 9-phenanthrenyl, and 1-pyrenyl, have been synthesized in reasonable yield and high purity. These compounds were characterized with (1)H, (13)C, (29)Si NMR and elemental combustion analysis. These compounds possess polycyclic aromatic functionality, which disrupts symmetry to improve solubility in organic solvents and aromatic polymers, without significant impact on thermal stability. Published by Elsevier B. V.