9-(pyren-1-yl)-9H-carbazole | 1359821-74-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: 9-(pyren-1-yl)-9H-carbazole
• 英文别名: 9-(pyren-3-yl)-9H-carbazole；9H-carbazol-9-ylpyrene；9-pyren-1-ylcarbazole
• CAS: 1359821-74-1
• 化学式: C₂₈H₁₇N
• 分子量: 367.45
• InChiKey: GJOFCABFXNDEPC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.1
• 重原子数：
  29
• 可旋转键数：
  1
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1-溴芘 、 咔唑 在 2,2'-联吡啶 、 copper(l) iodide 、 1,10-菲罗啉 、 potassium carbonate 作用下， 以 邻二氯苯 为溶剂， 反应 24.0h， 以80%的产率得到9-(pyren-1-yl)-9H-carbazole
  参考文献：
  名称：

  A highly sensitive fluorescent sensor based on small molecules doped in electrospun nanofibers: detection of explosives as well as color modulation

  摘要：

  报道了一种基于PEO/MePyCz复合纳米纤维的新型高灵敏度低成本硝基化合物传感器。这种复合纳米材料还可应用于纳米光电子器件、发光二极管或生物传感器。

  DOI：

  10.1039/c5tc00819k

文献信息

• Light-emitting device material and light-emitting device
  申请人：Murase Seiichiro

  公开号：US20090096356A1

  公开（公告）日：2009-04-16

  A light emitting device material containing a pyrene compound of formula (1) and a light emitting device. In formula (1), R 1 to R 18 are the same or different and are selected from hydrogen, alkyl, cycloalkyl, heterocyclic, alkenyl, cycloalkenyl, alkynyl, alkoxy, alkylthio, arylether, arylthioether, aryl, heteroaryl, halogen, carbonyl, carboxyl, oxycarbonyl, carbamoyl, amino, phosphine oxide and silyl; adjacent substituents among R 1 to R 18 may be combined with each other to form a ring; n represents an integer of 1 to 3; X is —O—, —S— or —NR 19 —; R 19 is selected from hydrogen, alkyl, cycloalkyl, heterocyclic, alkenyl, cycloalkenyl, alkynyl, aryl, heteroaryl or amino; R 19 may be combined with R 11 or R 18 to form a ring; Y is a single bond, arylene or heteroarylene; and n substituents among R 1 to R 10 and any one of R 11 to R 19 are used for linkage with Y

  一种含有式（1）的芘化合物的发光器件材料和发光器件。在式（1）中，R1到R18相同或不同，可从氢、烷基、环烷基、杂环烷基、烯基、环烯基、炔基、烷氧基、烷硫基、芳基醚、芳硫醚、芳基、杂芳基、卤素、羰基、羧基、氧羰基、氨基、膦氧化物和硅基中选择；R1到R18中相邻的取代基可能结合在一起形成环；n代表1至3的整数；X为—O—、—S—或—NR19—；R19从氢、烷基、环烷基、杂环烷基、烯基、环烯基、炔基、芳基、杂芳基或氨基中选择；R19可以与R11或R18结合形成环；Y为单键、芳基或杂芳基；R1到R10中的n个取代基和R11到R19中的任意一个用于与Y连接。
• Synthesis and Electro-Optical Properties of Carbazole-Substituted Pyrene Derivatives
  作者：Seonju Jeong、Sung Hwan Park、Ki-Soo Kim、Younghwan Kwon、Ki-Ryong Ha、Byeong-Dae Choi、Yoon Soo Han

  DOI：10.1166/jnn.2011.3683

  日期：2011.5.1

  Mono and dicarbazole-substituted pyrene derivatives, 9H-carbazol-9-ylpyrene (MCzP) and 1,6-di(9H-carbazol-9-yl)pyrene (DCzP), with dual-purpose function as a blue emitting and charge transporting layer in organic light emitting diodes, were synthesized and characterized. These series of molecules consisted of an electron donating (D) carbazole and an electron accepting (A) pyrene in D-A and D-A-D shapes. Non-doped blue electroluminescent devices with the configurations of ITO (150 nm)/α-NPD (30 nm)/DCzP (40 nm)/LiF (1 nm)/Al (150 nm) (D1) and ITO (150 nm)/2-TNATA (15 nm)/α-NPD (20 nm)/DCzP (40 nm)/BCP (15 nm)/Alq3 (10 nm)/LiF (1 nm)/Al (120 nm) (D2) were fabricated. D1 and D2 devices showed blue emission at 492 nm and 488 nm, and maximum luminance of 840 and 7560 cd/m2 obtained at 13 V and 15 V, respectively.

  合成并表征了单咔唑和二咔唑取代的芘衍生物--9H-咔唑-9-基芘（MCzP）和 1,6-二（9H-咔唑-9-基）芘（DCzP），它们在有机发光二极管中具有蓝色发光层和电荷传输层的双重功能。这些系列分子由一个电子供体（D）咔唑和一个电子受体（A）芘组成，呈 D-A 和 D-A-D 两种形状。制备了 ITO (150 nm)/α-NPD (30 nm)/DCzP (40 nm)/LiF (1 nm)/Al (150 nm) (D1) 和 ITO (150 nm)/2-TNATA (15 nm)/α-NPD (20 nm)/DCzP (40 nm)/BCP (15 nm)/Alq3 (10 nm)/LiF (1 nm)/Al (120 nm) (D2) 结构的非掺杂蓝色电致发光器件。D1 和 D2 器件分别在 492 nm 和 488 nm 处发出蓝色光，在 13 V 和 15 V 电压下的最大亮度分别为 840 和 7560 cd/m2。
• LIGHT-EMITTING DEVICE MATERIAL AND LIGHT-EMITTING DEVICE
  申请人：Toray Industries, Inc.

  公开号：US20140061629A1

  公开（公告）日：2014-03-06

  A light emitting device material containing a pyrene compound of general formula (1) and a light emitting device. In formula (1), R 1 to R 18 are the same or different and are selected from hydrogen, alkyl, cycloalkyl, heterocyclic, alkenyl, cycloalkenyl, alkynyl, alkoxy, alkylthio, arylether, arylthioether, aryl, heteroaryl, halogen, carbonyl, a carboxyl, oxycarbonyl, carbamoyl, amino, phosphine oxide and silyl; adjacent substituents among R 1 to R 18 may be combined with each other to form a ring; n is an integer of 1 to 3; X is —O—, —S— or —NR 19 —; R 19 is hydrogen, alkyl, cycloalkyl, heterocyclic, alkenyl, cycloalkenyl, alkynyl, aryl, heteroaryl or amino; R 19 may be combined with R 11 or R 18 to form a ring; Y is a single bond, arylene or heteroarylene; and n substituents among R 1 to R 10 and any one of R 11 to R 19 are used for linkage with Y

  一种含有通式（1）的芘化合物的发光装置材料和发光装置。在式（1）中，R1至R18相同或不同，可选择自氢、烷基、环烷基、杂环、烯基、环烯基、炔基、烷氧基、烷硫基、芳基醚、芳硫醚、芳基、杂芳基、卤素、羰基、羧基、氧羰基、氨基、磷氧化物和硅烷中；相邻的R1至R18取代基可以结合形成环；n是1到3的整数；X是—O—、—S—或—NR19—；R19是氢、烷基、环烷基、杂环、烯基、环烯基、炔基、芳基、杂芳基或氨基；R19可以与R11或R18结合形成环；Y是单键、芳基或杂芳基；R1至R10中的n个取代基和R11至R19中的任意一个取代基用于与Y连接。
• Light emitting device material and light emitting device
  申请人：Toray Industries, Inc.

  公开号：EP2463351A2

  公开（公告）日：2012-06-13

  The present invention relates to a light emitting device material containing a pyrene compound represented by the general formula (1): wherein R1 to R18 may be the same or different and represent a group selected from hydrogen, an alkyl group, a cycloalkyl group, a heterocyclic group, an alkenyl group, a cycloalkenyl group, an alkynyl group, an alkoxy group, an alkylthio group, an arylether group, an arylthioether group, an aryl group, a heteroaryl group, a halogen, a carbonyl group, a carboxyl group, an oxycarbonyl group, a carbamoyl group, an amino group, a phosphine oxide group and a silyl group; adjacent substituents among R1 to R18 may be combined with each other to form a ring; n represents an integer of 1 to 3; X represents -S-; Y represents an arylene group or a heteroarylene group; and n substituents among R1 to R10 and any one of R11 to R19 are used for linkage with Y.

  本发明涉及一种含有通式（1）代表的芘化合物的发光器件材料： 烷硫基、芳基醚基、芳基硫醚基、芳基、杂芳基、卤素、羰基、羧基、氧羰基、氨基甲酰基、氨基、氧化膦基和硅烷基；R1 至 R18 中的相邻取代基可相互结合形成一个环；n 代表 1 至 3 的整数；X 代表-S-；Y 代表芳基或杂芳基；R1 至 R10 中的 n 个取代基和 R11 至 R19 中的任一个取代基用于与 Y 连接。
• A highly sensitive fluorescent sensor based on small molecules doped in electrospun nanofibers: detection of explosives as well as color modulation
  作者：Wei Xue、Yang Zhang、Juanjuan Duan、Dong Liu、Yawei Ma、Naien Shi、Shufen Chen、Linghai Xie、Yan Qian、Wei Huang

  DOI：10.1039/c5tc00819k

  日期：——

  A new type of highly sensitive low-cost sensor towards nitro-compounds based on PEO/MePyCz composite nanofibers is reported. The composite nanomaterials may also be applied in nano-optoelectronics devices, light-emitting diodes or biological sensors.

  报道了一种基于PEO/MePyCz复合纳米纤维的新型高灵敏度低成本硝基化合物传感器。这种复合纳米材料还可应用于纳米光电子器件、发光二极管或生物传感器。