2-[(Aminocarbonyl)oxy]propyl 2-propenoate | 1019330-13-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-[(Aminocarbonyl)oxy]propyl 2-propenoate
• 英文别名: 2-carbamoyloxypropyl prop-2-enoate
• CAS: 1019330-13-2
• 化学式: C₇H₁₁NO₄
• 分子量: 173.169
• InChiKey: GJKMBIAJMOZQCG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  78.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1-methyl-2-hydroxyethyl urethane 、 丙烯酸甲酯（MA） 在 pseudozyma antarctica lipase B 作用下， 生成 2-[(Aminocarbonyl)oxy]propyl 2-propenoate
  参考文献：
  名称：

  产通用酯化催化剂的南极假酶脂肪酶B的合理设计

  摘要：

  旨在完全转化： 具有增加的底物结合位点（如图所示）的南极假酶脂肪酶B突变体能够转化具有高活性的仲醇不利的S对映异构体。

  DOI：

  10.1002/cbic.200900776

文献信息

• Enzymatic production of (meth)acrylic esters that contain urethane groups
  申请人：BASF Aktiengesellschaft

  公开号：US07164037B2

  公开（公告）日：2007-01-16

  Enzymatic preparation of (meth)acrylic esters containing urethane groups, and their use in radiation-curable compositions.

  酶法制备含有脲基的（甲基）丙烯酸酯，并将其用于辐射固化组合物中。
• Thermosetting compositions containing alternating copolymers of isobutylene type monomers
  申请人：——

  公开号：US20030171497A1

  公开（公告）日：2003-09-11

  A thermosetting composition that includes an ungelled copolymer composition and a crosslinking agent. The ungelled copolymer composition includes a functional group-containing copolymer that includes segments of alternating residues derived from a donor monomer composition comprising an acceptor monomer composition. The donor monomer composition includes one or both of isobutylene and diisobutylene, and the acceptor monomer composition includes acrylic monomers and monomers containing functional groups. The ungelled copolymer composition is substantially free of transition metals and Lewis acids, and the copolymer is substantially free of maleate-type monomer residues and fumarate-type monomer residues. The crosslinking agent has at least two functional groups that are reactive with the functional groups of the copolymer. The thermosetting composition may be in liquid, powder, or dispersed form and may be applied by traditional or electrocoating methods.

  一种热固性组合物，包括未胶凝的共聚物组合物和交联剂。未胶凝的共聚物组合物包括一个含有功能性基团的共聚物，其中包括从给体单体组成中得到的交替残基段，该给体单体组成包括受体单体组成。给体单体组成包括异丁烯和二异丁烯中的至少一种，而受体单体组成包括丙烯酸单体和含有功能性基团的单体。未胶凝的共聚物组合物基本上不含过渡金属和路易斯酸，而共聚物基本上不含马来酸型单体残基和富马酸型单体残基。交联剂具有至少两个与共聚物的功能性基团反应的功能性基团。热固性组合物可以是液体、粉末或分散形式，并且可以通过传统或电泳涂覆方法应用。
• Process for Preparing Polymers in Aqueous Solvents
  申请人：Kim Son Nguyen

  公开号：US20090010865A1

  公开（公告）日：2009-01-08

  The present invention relates to methods of producing polymers which comprise, in copolymerized form, 50-95% by weight of at least one ester of (meth)acrylic acid, 5-50% by weight of at least one olefinically unsaturated, free-radically polymerizable anionogenic or anionic compound and 0 to 30% by weight of at least one further free-radically polymerizable compound by free-radical polymerization in an alcohol-comprising solution, where the polymerization initiator used is at least one water-soluble initiator.

  本发明涉及一种在含有醇的溶液中通过自由基聚合的方法生产聚合物的方法，其中所述聚合物以共聚形式包含50-95重量％的至少一种（甲基）丙烯酸酯，5-50重量％的至少一种烯丙基不饱和、自由基聚合的阴离子性或阴离子化合物，以及0-30重量％的至少一种进一步自由基聚合的化合物，所使用的聚合引发剂是至少一种水溶性引发剂。
• COPOLYMERS FOR COSMETIC APPLICATIONS
  申请人：Kim Son Nguyen

  公开号：US20100135918A1

  公开（公告）日：2010-06-03

  The present invention relates to aqueous skin or hair cosmetic preparations which comprise at least one polymer A which comprises, in copolymerized form, at least one ester of (meth)acrylic acid, at least one olefinically unsaturated, free-radically polymerizable anionogenic or anionic compound, at least one free-radically polymerizable olefinically unsaturated urethane-group-containing compound which comprises no silicone groups and, if appropriate, further free-radically polymerizable compounds.

  本发明涉及至少包含一种聚合物A的水基皮肤或头发化妆品制剂，该聚合物A在共聚物形式下包含至少一种丙烯酸酯，至少一种烯丙基不饱和，自由基聚合的阴离子性或阴离子化合物，至少一种不含硅基的自由基聚合烯丙基不饱和脲基含量化合物，如适当的，还包括其他自由基聚合化合物。
• PROCESS FOR PREPARING ACRYLATE COPOLYMERS
  申请人：Kim Son Nguyen

  公开号：US20100174040A1

  公开（公告）日：2010-07-08

  The present invention relates to a method of producing polymers by free-radical polymerization in solution, wherein the polymerization initiator used is an ethanol-soluble initiator, and the solution polymerization is carried out in an alcoholic solvent which comprises 5 to 50% by weight of water.

  本发明涉及一种在溶液中通过自由基聚合生产聚合物的方法，其中所使用的聚合引发剂是乙醇溶性的，且所述溶液聚合是在一种含有5%至50%重量水的醇溶剂中进行的。