2,3,5,6-tetrafluoro-4-(2,2,3,3,3-pentafluoropropoxy)styrene | 121247-90-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2,3,5,6-tetrafluoro-4-(2,2,3,3,3-pentafluoropropoxy)styrene
• 英文别名: 1-Ethenyl-2,3,5,6-tetrafluoro-4-(2,2,3,3,3-pentafluoropropoxy)benzene；1-ethenyl-2,3,5,6-tetrafluoro-4-(2,2,3,3,3-pentafluoropropoxy)benzene
• CAS: 121247-90-3
• 化学式: C₁₁H₅F₉O
• 分子量: 324.146
• InChiKey: GFMUMEDUNWXPPZ-UHFFFAOYSA-N

物化性质

• 沸点：
  209.3±40.0 °C(Predicted)
• 密度：
  1.496±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  2,3,4,5,6-五氟苯乙烯 、 2,2,3,3,3-pentafluoro-propan-1-ol; sodium salt 以 四氢呋喃 为溶剂， 反应 19.0h， 以80%的产率得到2,3,5,6-tetrafluoro-4-(2,2,3,3,3-pentafluoropropoxy)styrene
  参考文献：
  名称：

  New Highly Fluorinated Styrene-Based Materials with Low Surface Energy Prepared by ATRP

  摘要：

  2,3,5,6-Tetrafluoro-4-(2,2,3,3,3-pentafluoropropoxy)styrene (TF(F-5)S) and 2,3,5,6-tetrafluoro-4-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctaoxy)styrene (TF(F,5)S) are prepared by nucleophilic substitution of 2,3,4,5,6-pentafluorostyrene. The neat monomers are subjected to atom transfer radical polymerization (ATRP) at 110 degreesC to high conversions in relatively short times, 10-120 min; TF(F-5)S is additionally polymerized at 70 and 90 degreesC. Block copolymers with styrene are prepared by the macroinitiator approach. All polymers, in the number-average molecular weight range from 6000 to 35 000, have polydispersity indexes between 1.08 and 1.37. The homopolymers show glass transitions from 16 to 62 degreesC depending on molecular weight, whereas the block copolymers exhibit phase separation mirrored in two T(g)s, which could be observed when the smallest block constitutes more than 10 mol %. The fluorinated side chains of P(TF(F-5)S) and P(TF(F-15)S) enrich the surface of thin films, which results in an advancing water contact angle of 117degrees and 122degrees, respectively. Both XPS analyses and contact angle measurements strongly imply that the fluorinated parts of the block copolymers migrate to the surface and create low surface energy films.

  DOI：

  10.1021/ma034952b

文献信息

• CN116354804
  申请人：——

  公开号：——

  公开（公告）日：——
• New Highly Fluorinated Styrene-Based Materials with Low Surface Energy Prepared by ATRP
  作者：Sachin Borkar、Katja Jankova、Heinz W. Siesler、Søren Hvilsted

  DOI：10.1021/ma034952b

  日期：2004.2.1

  2,3,5,6-Tetrafluoro-4-(2,2,3,3,3-pentafluoropropoxy)styrene (TF(F-5)S) and 2,3,5,6-tetrafluoro-4-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctaoxy)styrene (TF(F,5)S) are prepared by nucleophilic substitution of 2,3,4,5,6-pentafluorostyrene. The neat monomers are subjected to atom transfer radical polymerization (ATRP) at 110 degreesC to high conversions in relatively short times, 10-120 min; TF(F-5)S is additionally polymerized at 70 and 90 degreesC. Block copolymers with styrene are prepared by the macroinitiator approach. All polymers, in the number-average molecular weight range from 6000 to 35 000, have polydispersity indexes between 1.08 and 1.37. The homopolymers show glass transitions from 16 to 62 degreesC depending on molecular weight, whereas the block copolymers exhibit phase separation mirrored in two T(g)s, which could be observed when the smallest block constitutes more than 10 mol %. The fluorinated side chains of P(TF(F-5)S) and P(TF(F-15)S) enrich the surface of thin films, which results in an advancing water contact angle of 117degrees and 122degrees, respectively. Both XPS analyses and contact angle measurements strongly imply that the fluorinated parts of the block copolymers migrate to the surface and create low surface energy films.