pentadecane | 26730-16-5

• 分子结构分类: 有机化合物 - 碳氢化合物 - 饱和烃
• 英文名称: pentadecane
• 英文别名: 6-methyl-tetradecane；6-Methyl-tetradecan；6-Methyltetradecan；6-Methyltetradecane
• CAS: 26730-16-5
• 化学式: C₁₅H₃₂
• 分子量: 212.419
• InChiKey: ONQXEQPEKDADGM-UHFFFAOYSA-N

物化性质

• 沸点：
  134 °C(Press: 12.5 Torr)
• 密度：
  0.7689 g/cm3
• LogP：
  8.194 (est)
• 保留指数：
  1451;1451.6

计算性质

• 辛醇/水分配系数(LogP)：
  8.1
• 重原子数：
  15
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  2-碘庚烷 、 1-辛基氯化镁, 1M IN METHF 在 C₁₈H₂₂ClN₃Ni 作用下， 以87%的产率得到pentadecane
  参考文献：
  名称：

  From Dimethylamine to Pyrrolidine: The Development of an Improved Nickel Pincer Complex for Cross-Coupling of Nonactivated Secondary Alkyl Halides

  摘要：

  Replacement of a dimethyl amino group of the amidobis(amine) nickel(II) pincer complex (1), [((N2N)-N-Me)-Ni-Cl], by a pyrrolidino group resulted in a new nickel(II) pincer complex (2), [((PNNN)-N-yr-N-Me)Ni-Cl]. Complex 2 is an efficient catalyst for Kumada and Suzuki-Miyaura cross-coupling of nonactivated secondary alkyl halides, while complex 1 is largely inactive. The significant activity difference is tentatively attributed to a minimal structural difference, which leads to a more hemilabile ligand.

  DOI：

  10.1021/acscatal.5b02324

文献信息

• Petrow et al., Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1959, p. 1091,1094;engl.Ausg.S.1053,1056
  作者：Petrow et al.

  DOI：——

  日期：——
• From Dimethylamine to Pyrrolidine: The Development of an Improved Nickel Pincer Complex for Cross-Coupling of Nonactivated Secondary Alkyl Halides
  作者：Pablo M. Perez Garcia、Thomas Di Franco、Alexandre Epenoy、Rosario Scopelliti、Xile Hu

  DOI：10.1021/acscatal.5b02324

  日期：2016.1.4

  Replacement of a dimethyl amino group of the amidobis(amine) nickel(II) pincer complex (1), [((N2N)-N-Me)-Ni-Cl], by a pyrrolidino group resulted in a new nickel(II) pincer complex (2), [((PNNN)-N-yr-N-Me)Ni-Cl]. Complex 2 is an efficient catalyst for Kumada and Suzuki-Miyaura cross-coupling of nonactivated secondary alkyl halides, while complex 1 is largely inactive. The significant activity difference is tentatively attributed to a minimal structural difference, which leads to a more hemilabile ligand.