dibenzo[2,3:5,6]pyrrolizino[1,7-bc]indolo[1,2,3-lm]carbazole | 1252605-50-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: dibenzo[2,3:5,6]pyrrolizino[1,7-bc]indolo[1,2,3-lm]carbazole
• 英文别名: dibenzo[2,3:5,6]pyrrolizino[1,7-bc]indolo[1,2,3-lm]carbozole；9,24-Diazanonacyclo[15.13.1.12,9.03,8.010,15.018,23.024,31.025,30.016,32]dotriaconta-1,3,5,7,10,12,14,16(32),17(31),18,20,22,25,27,29-pentadecaene；9,24-diazanonacyclo[15.13.1.12,9.03,8.010,15.018,23.024,31.025,30.016,32]dotriaconta-1,3,5,7,10,12,14,16(32),17(31),18,20,22,25,27,29-pentadecaene
• CAS: 1252605-50-7
• 化学式: C₃₀H₁₆N₂
• 分子量: 404.47
• InChiKey: HAOJIFVWQMJXSX-UHFFFAOYSA-N

物化性质

• 密度：
  1.44±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.6
• 重原子数：
  32
• 可旋转键数：
  0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  8.8
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  2-[11-(2-aminophenyl)indolo[3,2-b]carbazol-5(11H)-yl]aniline 在 硫酸 、 溶剂黄146 、 sodium nitrite 作用下， 以 水 为溶剂， 反应 2.0h， 生成 dibenzo[2,3:5,6]pyrrolizino[1,7-bc]indolo[1,2,3-lm]carbazole
  参考文献：
  名称：

  Dibenzo[2,3:5,6]pyrrolizino[1,7-bc]indolo[1,2,3-lm]carbazole: a new electron donor

  摘要：

  新的杂环系统，二苯并[2,3:5,6]吡咯啉[1,7-bc]吲哚[1,2,3-lm]氮杂蒽3，可以被视为氮杂蒽和对苯二胺的平面杂化物，可以通过商业前体轻松制备，并具有与四烯和五烯相当的高热稳定性和强电子供体特性。

  DOI：

  10.1039/c0nj00100g

文献信息

• ORGANIC ELECTROLUMINESCENT ELEMENT, ELECTRONIC DEVICE, AND COMPOUND
  申请人：IDEMITSU KOSAN CO.,LTD.

  公开号：US20200212315A1

  公开（公告）日：2020-07-02

  An organic electroluminescence device includes: an anode; a cathode and a first organic layer between the anode and the cathode, the first organic layer containing a first compound represented by a formula (2) below. In the formula (2), at least one combination of adjacent two or more of R 201 to R 216 is mutually bonded to form a saturated ring, mutually bonded to form an unsaturated ring, or not mutually bonded, and R 201 to R 216 forming neither the saturated ring nor the unsaturated ring each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group, or the like.

  一种有机电致发光器件，包括：阳极；阴极和第一有机层，在阳极和阴极之间，第一有机层包含一个由下式（2）表示的第一化合物。在式（2）中，相邻的两个或更多的R201到R216中的至少一个组合互相结合形成饱和环，互相结合形成不饱和环，或不互相结合，而R201到R216中既不形成饱和环也不形成不饱和环的各自独立地表示氢原子、取代或未取代的烷基或类似物。
• Organic electroluminescence device and novel compound
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US10680181B2

  公开（公告）日：2020-06-09

  An organic electroluminescence device comprising: a cathode, an anode, and at least one organic layer disposed between the cathode and the anode, wherein at least one layer of the at least one organic layer comprises a compound represented by the following formulas (1-1) and (1-3) or a compound represented by the following formulas (1-2) and (1-3).

  一种有机电致发光装置，包括 一个阴极 阳极，以及 设置在阴极和阳极之间的至少一层有机层，其中 至少一层有机层中的至少一层包括由下列式子（1-1）和（1-3）表示的化合物或由下列式子（1-2）和（1-3）表示的化合物。
• Substituted dibenzo[2,3:5,6]-pyrrolizino[1,7-bc]indolo[1,2,3-lm]carbazoles: a series of new electron donors
  作者：Morgane Rivoal、Laura Bekere、David Gachet、Vladimir Lokshin、Wladimir Marine、Vladimir Khodorkovsky

  DOI：10.1016/j.tet.2013.02.007

  日期：2013.4

  The synthesis and spectroscopic properties of a series of new organic electron donors derived from dibenzo[2,3:5,6]pyrrolizino-[1,7-bc]indolo[1,2,3-lm]carbazole are described. These compounds can be considered as planar hybrids of carbazole and p-phenylenediamine and possess high thermal stability. The electron donating properties and one- and two-photon spectroscopic features of methoxy derivatives are very sensitive to the number and positions of the methoxy groups. The X-ray structure of the 2,11-dimethoxy derivatives features slipped pi-stacks and short interplanar distance between the molecules in the stacks similar to those found in the unsubstituted derivative. (C) 2013 Elsevier Ltd. All rights reserved.
• TWI516490
  申请人：——

  公开号：——

  公开（公告）日：——
• ORGANIC ELECTROLUMINESCENCE DEVICE AND NOVEL COMPOUND
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20190355914A1

  公开（公告）日：2019-11-21

  An organic electroluminescence device comprising: a cathode, an anode, and at least one organic layer disposed between the cathode and the anode, wherein at least one layer of the at least one organic layer comprises a compound represented by the following formulas (1-1) and (1-3) or a compound represented by the following formulas (1-2) and (1-3).