tri-2-ethylhexanoic acid trimethylol propane ester | 107137-80-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: tri-2-ethylhexanoic acid trimethylol propane ester
• 英文别名: trimethylolpropane 2-ethyl-hexanoate；Hexanoic acid, 2-ethyl-, 2,2-bis(hydroxymethyl)butyl ester；2,2-bis(hydroxymethyl)butyl 2-ethylhexanoate
• CAS: 107137-80-4
• 化学式: C₁₄H₂₈O₄
• 分子量: 260.374
• InChiKey: ARNXQHSHOUZEPR-UHFFFAOYSA-N

物化性质

• 沸点：
  336.4±22.0 °C(Predicted)
• 密度：
  1.007±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  18
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.93
• 拓扑面积：
  66.8
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  三羟甲基丙烷 、 2-乙基-己酸稀土盐 在 sulfonated with conc. sulfuric acid amorphous carbons derived from wood powder 作用下， 以 neat (no solvent) 为溶剂， 反应 24.0h， 以10.4%的产率得到tri-2-ethylhexanoic acid trimethylol propane ester
  参考文献：
  名称：

  用木粉衍生的磺化无定形碳与三羟甲基丙烷进行脂肪酸无溶剂酯化

  摘要：

  通过多元醇和脂肪酸之间的酯化反应合成的多酯是增值的油脂化学产品，广泛用作润滑剂，化妆品和食品添加剂等。但是，尽管均相酸催化剂伴随着相关的能源成本和存在的环境问题，但在其工业生产中仍是优选的。在本文中，我们描述了具有高负载水平的SO 3的木质纤维素衍生无定形碳。H及其在作为生物基非均相酸催化剂的多元醇酯的合成中的应用。这些磺化的无定形碳可以容易地通过（i）在400℃下热处理1小时和（ii）用氯硫酸磺化来制备。XRD和BET分析表明，这些碳质材料不是晶体，而是具有低表面积的无定形结构。通过FT-IR和XPS证实了SO 3 H基团的附着，并通过CHNS元素分析确定了SO 3 H的负载量。与其他硫酸盐化剂（例如浓硫酸）相比，氯硫酸具有更高的SO 3 H负载量。硫酸和发烟硫酸。SO 3较高在无溶剂条件下，H负载的无定形碳对三羟甲基丙烷和脂肪酸之间的酯化反应表现出更大的催化活性。使用该催化剂用三羟甲基

  DOI：

  10.1016/j.catcom.2017.03.015

文献信息

• COMPOSITION CONTAINING A COMPOUND CAPABLE OF ESTABLISHING HYDROGEN BONDS, AND COSMETIC TREATMENT PROCESS
  申请人：CHODOROWSKI-KIMMES Sandrine

  公开号：US20100028277A1

  公开（公告）日：2010-02-04

  Composition containing, in a cosmetically or dermatologically acceptable medium, a compound that may be obtained by reaction between: an oil bearing at least one nucleophilic and/or electrophilic reactive function, and a junction group capable of establishing hydrogen bonds with one or more partner junction groups, the junction group bearing at least one reactive function capable of reacting with the reactive function borne by the oil, and also comprising at least one unit of formula (I) or (II):

  含有一种化合物的成分，可以通过以下反应获得：一个至少带有一个亲核和/或亲电反应功能的油，以及一个能够与一个或多个配对连接基建立氢键的连接基，该连接基至少带有一个能够与油所带反应功能发生反应的反应功能，并且还包括至少一个符合式(I)或(II)的单元的化妆品或皮肤学上可接受的介质。
• [EN] SULFUR-CONTAINING SILANE, FILLED ELASTOMERIC COMPOSITIONS CONTAINING SAME AND ARTICLES MADE THEREFROM<br/>[FR] SILANE CONTENANT DU SOUFRE, COMPOSITIONS ÉLASTOMÈRE CHARGÉES CONTENANT CET ÉLÉMENT ET ARTICLES FAITS DE CET ÉLÉMENT
  申请人：MOMENTIVE PERFORMANCE MAT INC

  公开号：WO2010014238A1

  公开（公告）日：2010-02-04

  Sulfur-containing silane, and/or the partially to substantially complete hydrolyzate(s) of sulfur-containing silane, of general Formula (1): [Y1SG1SiZθ]m[Y2SG2SiZθZβ]n[Y3SG3SiZβ3]o[Y4SG4SiZβ2X]p[Y5SG5SiZβX2]q[X]r (1) are provided wherein the variables have the values as indicated in the claims.

  提供了含硫硅烷和/或硫含硅烷的部分到完全的水解物，其通式为（1）：[Y1SG1SiZθ]m[Y2SG2SiZθZβ]n[Y3SG3SiZβ3]o[Y4SG4SiZβ2X]p[Y5SG5SiZβX2]q[X]r，其中变量的值如权利要求所示。
• COSMETIC TREATMENT PROCESSES AND KIT
  申请人：Dublanchet Anne-Claude

  公开号：US20140155352A1

  公开（公告）日：2014-06-05

  The present invention relates to a cosmetic process for treating keratin materials, which can give them, especially in a long-lasting and reversible manner, interesting cosmetic properties; this process comprising the application to said materials: in a first stage, of a cosmetic composition comprising at least one graftable species, comprising at least one unit of formula (Ia): and in a second stage, of a cosmetic composition comprising at least one cosmetic active agent bearing at least one unit of formula (Ia): The invention also relates to a kit comprising said compositions.

  本发明涉及一种用于处理角蛋白材料的化妆品工艺，可以在长期和可逆的情况下赋予它们有趣的化妆品特性；该工艺包括向所述材料施加以下组成部分的应用：第一阶段，包括至少一种可接枝的物种的化妆品组合物，其中包括至少一个式(Ia)的单元；第二阶段，包括至少一种具有至少一个式(Ia)的化妆品活性剂的化妆品组合物：本发明还涉及包括所述组合物的套件。
• COSMETIC COMPOSITION COMPRISING A SUPRAMOLECULAR COMPOUND CAPABLE OF ESTABLISHING HYDROGEN BONDS, AND A PARTICULAR OIL
  申请人：Barba Claudia

  公开号：US20130022561A1

  公开（公告）日：2013-01-24

  The present invention relates to a cosmetic composition comprising, in a cosmetically acceptable medium, (i) a supramolecular compound that may be obtained by reaction between: at least one oil bearing at least one nucleophilic reactive function chosen from OH and NH 2 , and at least one junction group capable of establishing hydrogen bonds with one or more partner junction groups, each pairing of a junction group involving at least three hydrogen bonds, the said junction group bearing at least one isocyanate or imidazole reactive function capable of reacting with the reactive function borne by the oil, the said junction group also comprising at least one unit of formula (I) or (II): (I) (II) (ii) at least one oil, chosen from apolar hydrocarbon-based oils and silicone oils, (iii) at least one dyestuff. The invention also relates to a cosmetic treatment process comprising the application of the said composition.

  本发明涉及一种化妆品组合物，包括在一种化妆品可接受的介质中，(i) 一种超分子化合物，可以通过以下反应获得：至少含有一种带有至少一个亲核反应基团的油，所述亲核反应基团选择自OH和NH2，以及至少含有一个结合基团，能够与一个或多个配对结合基团建立氢键，每个结合基团的配对涉及至少三个氢键，所述结合基团带有至少一个异氰酸酯或咪唑反应基团，能够与油所带的反应基团反应，所述结合基团还包括至少一个式(I)或(II)的单元：(I) (II) (ii) 至少一种油，选择自非极性碳氢化合物基油和硅油，(iii) 至少一种染料。本发明还涉及一种化妆品处理过程，包括应用所述组合物。
• COSMETIC COMPOSITION COMPRISING A SUPRAMOLECULAR COMPOUND CAPABLE OF ESTABLISHING HYDROGEN BONDS, AND A PARTICULAR ADDITIONAL INGREDIENT
  申请人：Barba Claudia

  公开号：US20130004438A1

  公开（公告）日：2013-01-03

  The present invention relates to a cosmetic composition comprising, in a cosmetically acceptable medium, (i) a supramolecular compound that may be obtained by reaction between: —at least one oil bearing at least one nucleophilic reactive function chosen from OH and NH 2 , and —at least one junction group capable of establishing hydrogen bonds with one or more partner junction groups, each pairing of a junction group involving at least three hydrogen bonds, the said junction group bearing at least one isocyanate or imidazole reactive function capable of reacting with the reactive function borne by the oil, the said junction group also comprising at least one unit of formula (I) or (II): (ii) and at least one additional ingredient preferably chosen from: —silicone elastomers, —polyesters that may be obtained by reacting: a tetraol containing from 4 to 10 carbon atoms; a saturated, linear or branched monocarboxylic acid containing from 9 to 23 carbon atoms; a cyclic dicarboxylic acid containing from 6 to 12 carbon atoms; and an aromatic monocarboxylic acid containing from 7 to 11 carbon atoms, —film-forming agents chosen from silicone resins and film-forming polymers, preferably chosen from the group comprising: a film-forming block ethylenic copolymer, a vinyl polymer comprising at least one carbosiloxane dendrimer-based unit, a dispersion of acrylic or vinyl radical homopolymer or copolymer particles dispersed in the said liquid fatty phase, —structuring agents chosen from semicrystalline polymers and thickeners comprising at least one group and preferably at least two groups capable of establishing hydrogen interactions, chosen from: polymeric thickeners, and organogelling agents. The invention also relates to a cosmetic treatment process comprising the application of the said composition.

  本发明涉及一种化妆品组合物，包括以下成分，均可用于化妆品中：（i）可通过以下反应得到的超分子化合物：至少含有一种带有OH或NH2的亲核反应功能的油，和至少含有一种能够与一种或多种配对结构单元建立氢键的连接基团，每个连接基团的配对都涉及至少三个氢键，所述连接基团带有至少一种异氰酸酯或咪唑反应功能，可与油中的反应功能发生反应，所述连接基团还包括至少一个式（I）或（II）的单元；（ii）至少一种其他成分，优选为以下成分之一：硅弹性体、聚酯物，可通过以下反应得到：含有4至10个碳原子的四元醇，含有9至23个碳原子的饱和线性或支链一元羧酸，含有6至12个碳原子的环状二元羧酸和含有7至11个碳原子的芳香族一元羧酸；膜形成剂，选择自硅树脂和膜形成聚合物，优选自以下组中选择：膜形成块乙烯共聚物、含有至少一个基于碳硅氧烷树枝状分子的乙烯基聚合物、丙烯酸或乙烯基自由基均聚物或共聚物粒子的分散液分散在所述液态脂肪相中；结构调节剂，选择自半晶态聚合物和增稠剂，包括至少一个羟基或酰胺基团，优选包括至少两个能够建立氢键相互作用的羟基或酰胺基团，选择自聚合增稠剂和有机凝胶剂。本发明还涉及一种化妆品处理过程，包括应用所述组合物。