1-dodecyl-2,3-dimethylimidazol-1-ium trifluoromethanesulfonate | 1215070-74-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: 1-dodecyl-2,3-dimethylimidazol-1-ium trifluoromethanesulfonate
• 英文别名: 1-Dodecyl-2,3-dimethylimidazol-3-ium;trifluoromethanesulfonate；1-dodecyl-2,3-dimethylimidazol-3-ium;trifluoromethanesulfonate
• CAS: 1215070-74-8
• 化学式: CF₃O₃S*C₁₇H₃₃N₂
• 分子量: 414.533
• InChiKey: LFTCPJLZZIEPDA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  4.59
• 重原子数：
  27
• 可旋转键数：
  11
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  74.4
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  1,2-dimethyl-3-dodecylimidazolium bromide 、 potassium trifluoromethansulfonate 反应 0.17h， 生成 1-dodecyl-2,3-dimethylimidazol-1-ium trifluoromethanesulfonate
  参考文献：
  名称：

  Synthesis of imidazolium and pyridinium-based ionic liquids and application of 1-alkyl-3-methylimidazolium salts as pre-catalysts for the benzoin condensation using solvent-free and microwave activation

  摘要：

  An efficient one-pot procedure for the synthesis of ionic liquids based on nitrogen-containing heterocycles, imidazolium or pyridinium under 'green chemistry' conditions has been described Imidazolium salts and DBU have been found to catalyze efficiently the berizoin condensation giving good yields within very short reaction time using solvent-free microwave activation conditions (C) 2009 Elsevier Ltd All rights reserved

  DOI：

  10.1016/j.tet.2009.11.110

文献信息

• US7455903B2
  申请人：——

  公开号：US7455903B2

  公开（公告）日：2008-11-25
• Synthesis of imidazolium and pyridinium-based ionic liquids and application of 1-alkyl-3-methylimidazolium salts as pre-catalysts for the benzoin condensation using solvent-free and microwave activation
  作者：Audrey Aupoix、Bruce Pégot、Giang Vo-Thanh

  DOI：10.1016/j.tet.2009.11.110

  日期：2010.2

  An efficient one-pot procedure for the synthesis of ionic liquids based on nitrogen-containing heterocycles, imidazolium or pyridinium under 'green chemistry' conditions has been described Imidazolium salts and DBU have been found to catalyze efficiently the berizoin condensation giving good yields within very short reaction time using solvent-free microwave activation conditions (C) 2009 Elsevier Ltd All rights reserved