5,5-di(2-thienyl)dipyrromethane | 1343488-05-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: 5,5-di(2-thienyl)dipyrromethane
• 英文别名: 2-[1H-pyrrol-2-yl(dithiophen-2-yl)methyl]-1H-pyrrole
• CAS: 1343488-05-0
• 化学式: C₁₇H₁₄N₂S₂
• 分子量: 310.444
• InChiKey: NYLSFMVXYMBXSY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  88.1
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-吡咯甲酸甲酯 在 三氟化硼乙醚 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 反应 2.0h， 生成 5,5-di(2-thienyl)dipyrromethane
  参考文献：
  名称：

  5,5-Diaryldipyrromethanes: syntheses and anion binding properties

  摘要：

  A two-step synthesis of 5,5-diaryldipyrromethanes in good yields is described. The adopted synthetic strategy can be used to tune the substituent at the meso-carbon very easily by choosing the Grignard reagent of interest. Further, the influence of the incorporation of various diaryl units at the mesa-carbon atom in the inherent anion binding affinities of the dipyrromethanes through hydrogen bonding was discussed. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.08.163

文献信息

• 5,5-Diaryldipyrromethanes: syntheses and anion binding properties
  作者：K.C. Gowri Sreedevi、Ajesh P. Thomas、P.S. Salini、S. Ramakrishnan、K.S. Anju、M.G. Derry Holaday、M.L.P. Reddy、C.H. Suresh、A. Srinivasan

  DOI：10.1016/j.tetlet.2011.08.163

  日期：2011.11

  A two-step synthesis of 5,5-diaryldipyrromethanes in good yields is described. The adopted synthetic strategy can be used to tune the substituent at the meso-carbon very easily by choosing the Grignard reagent of interest. Further, the influence of the incorporation of various diaryl units at the mesa-carbon atom in the inherent anion binding affinities of the dipyrromethanes through hydrogen bonding was discussed. (C) 2011 Elsevier Ltd. All rights reserved.