2-苄基-1-癸醇 | 107613-29-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 2-苄基-1-癸醇
• 英文名称: 2-benzyl-1-decanol
• 英文别名: (±)-2-benzyl-1-decanol；(+/-)-1-hydroxy-2-benzyl-decane；(+/-)-1-Hydroxy-2-benzyl-decan；2-Benzyldecan-1-ol
• CAS: 107613-29-6
• 化学式: C₁₇H₂₈O
• 分子量: 248.409
• InChiKey: QFCANWDIKLISRL-UHFFFAOYSA-N

物化性质

• 沸点：
  200-201 °C(Press: 15 Torr)
• 密度：
  0.9203 g/cm3(Temp: 17 °C)

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  18
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.65
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-苄基-1-癸醇 在 吡啶 、 ruthenium trichloride 、 高碘酸 、 sodium hydroxide 作用下， 以 四氯化碳 、 二氯甲烷 、 水 、 乙腈 为溶剂， 反应 20.0h， 生成 δ-dodecanolactone
  参考文献：
  名称：

  光学活性β-烷基取代的γ-内酯和威士忌内酯类似物的合成和嗅觉评价

  摘要：

  合成了具有光学活性的β-烷基取代的γ-内酯和威士忌内酯类似物，并评估了其气味特性。在手性中间体的制备过程中，我们发现了3-芳基甲基-2-甲基-1-丙醇的高度对映选择性酯化反应的良好反应条件，以动力学方式将它们拆分。合成内酯的嗅觉评价结果表明，γ-内酯环上的烷基对气味分布起重要作用。

  DOI：

  10.1016/j.tet.2020.130984
• 作为产物：
  描述：

  癸酸乙酯 在 lithium aluminium tetrahydride 、 lithium diisopropyl amide 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 17.75h， 生成 2-苄基-1-癸醇
  参考文献：
  名称：

  光学活性β-烷基取代的γ-内酯和威士忌内酯类似物的合成和嗅觉评价

  摘要：

  合成了具有光学活性的β-烷基取代的γ-内酯和威士忌内酯类似物，并评估了其气味特性。在手性中间体的制备过程中，我们发现了3-芳基甲基-2-甲基-1-丙醇的高度对映选择性酯化反应的良好反应条件，以动力学方式将它们拆分。合成内酯的嗅觉评价结果表明，γ-内酯环上的烷基对气味分布起重要作用。

  DOI：

  10.1016/j.tet.2020.130984

文献信息

• [EN] PREPARATION OF SURFACTANTS VIA CROSS-METATHESIS<br/>[FR] PRÉPARATION DE TENSIOACTIFS PAR MÉTATHÈSE CROISÉE
  申请人：MATERIA INC

  公开号：WO2015126462A1

  公开（公告）日：2015-08-27

  The present invention relates to compositions comprising 2-phenyl linear alkene benzenes or 2-phenyl linear alkene benzene sulfonates or 2-phenyl linear alkylbenzenes or 2-phenyl linear alkylbenzene sulfonates; where the benzene ring is optionally substituted with one or more groups designated R *, where R * is defined herein and to methods for making the same. This invention also relates to compositions, methods of making, use of, and articles of manufacuture comprising 2-ethoxylated hydroxymethylphenyl linear alkyl benzenes or 2-propoxylated hydroxymethylphenyl linear alkyl benzenes.

  本发明涉及包含2-苯基线性烯烃苯或2-苯基线性烯烃苯磺酸盐或2-苯基线性烷基苯或2-苯基线性烷基苯磺酸盐的组合物；其中苯环可以选择性地被一个或多个被指定为R*的基团取代，其中R*在此处被定义，并且涉及制备这些组合物的方法。本发明还涉及包含2-乙氧基羟甲基苯基线性烷基苯或2-丙氧基羟甲基苯基线性烷基苯的组合物、制备方法、使用方法和制造物品。
• Cross β-alkylation of primary alcohols catalysed by DMF-stabilized iridium nanoparticles
  作者：Masaki Kobayashi、Hiroki Yamaguchi、Takeyuki Suzuki、Yasushi Obora

  DOI：10.1039/d1ob00045d

  日期：——

  A simple method for the cross β-alkylation of linear alcohols with benzyl alcohols in the presence of DMF-stabilized iridium nanoparticles was developed. Furthermore, a highly effective catalyst-recycling process was also developed.

  在DMF稳定的铱纳米颗粒存在下，开发了一种用苄醇对线性醇进行交叉β-烷基化的简单方法。此外，还开发了一种高效的催化剂循环利用过程。
• PREPARATION OF SURFACTANTS VIA CROSS-METATHESIS
  申请人：MATERIA, INC.

  公开号：US20160186094A1

  公开（公告）日：2016-06-30

  The present invention relates to compositions comprising alkene benzenes or alkene benzene sulfonates or alkylbenzenes or alkylbenzene sulfonates; methods for making alkene benzenes or alkene benzene sulfonates or alkylbenzenes or alkylbenzene sulfonates; where the benzene ring is optionally substituted with one or more groups designated R*, where R* is defined herein. More particularly, the present invention relates to compositions comprising 2-phenyl linear alkene benzenes or 2-phenyl linear alkene benzene sulfonates or 2-phenyl linear alkylbenzenes or 2-phenyl linear alkylbenzene sulfonates; methods for making 2-phenyl alkene benzenes or 2-phenyl alkene benzene sulfonates or 2-phenyl alkylbenzenes or 2-phenyl alkylbenzene sulfonates; where the benzene ring is optionally substituted with one or more groups designated R*, where R* is defined herein. This invention also relates to compositions, methods of making, use of, and articles of manufacture comprising 2-ethoxylated hydroxymethylphenyl linear alkyl benzenes. This invention also relates to compositions, methods of making, use of, and articles of manufacture comprising 2-propoxylated hydroxymethylphenyl linear alkyl benzenes.

  本发明涉及包含烯烃苯或烯烃苯磺酸盐或烷基苯或烷基苯磺酸盐的组合物；制备烯烃苯或烯烃苯磺酸盐或烷基苯或烷基苯磺酸盐的方法；其中苯环可以选择性地被一个或多个被指定为R*的基团所取代，其中R*在此被定义。更具体地，本发明涉及包含2-苯基线性烯烃苯或2-苯基线性烯烃苯磺酸盐或2-苯基线性烷基苯或2-苯基线性烷基苯磺酸盐的组合物；制备2-苯基烯烃苯或2-苯基烯烃苯磺酸盐或2-苯基烷基苯或2-苯基烷基苯磺酸盐的方法；其中苯环可以选择性地被一个或多个被指定为R*的基团所取代，其中R*在此被定义。本发明还涉及包含2-乙氧基羟甲基苯基线性烷基苯的组合物，制备方法，使用方法和制造物品。本发明还涉及包含2-丙氧基羟甲基苯基线性烷基苯的组合物，制备方法，使用方法和制造物品。
• Removal, Recovery, and Recycling of Triarylphosphonium-Supported Tin Reagents for Various Organic Transformations
  作者：Jean-Christophe Poupon、David Marcoux、Jean-Manuel Cloarec、André B. Charette

  DOI：10.1021/ol701447q

  日期：2007.8.1

  Phosphonium-supported tin reagents and catalysts were prepared and were shown to be effective in Stille couplings, radical dehalogenations, radical cyclizations, and carbonyl allylations. Not only could the tin residues be removed from the crude reaction mixture through a phase separation process but also they could be recovered and recycled.
• Dependence of Finger Flexion Force on the Posture of the Nonperforming Fingers During Key Pressing Tasks
  作者：Zong-Ming Li、Guang H. Yue

  DOI：10.1080/00222890209601951

  日期：2002.12

  The influence of different positions of the non-performing (idle) fingers on the maximal force contraction of flexion (master) fingers during key pressing tasks was investigated. Ten participants performed maximal voluntary flexion contractions with various combinations of the index, middle, ring, and little fingers while the idle fingers rested on or were lifted away from the supporting surface. The effect of idle finger posture on total finger force production of master fingers was dependent on finger combination. In general, force production by master fingers was higher when the idle fingers were lifted away from the supporting surface than when they rested on it. The average increase in total force production by master fingers caused by the lifting of idle fingers was +12.4% (from -8.3% to +30.2%). Force-production capability of individual master fingers can be facilitated (as high as 34.1%), unchanged, or depressed (as high as -29.0%) by lifting the idle fingers. The effect of idle finger posture on finger force production of master fingers led to changes in force deficit. Neural, anatomical, and mechanical factors might account for the dependence of finger flexion force of master fingers on the posture of the idle fingers.