1-(4'-t-butylbenzoyl)-2-(2",5"-dimethylbenzoyl) hydrazine | 1004679-42-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-(4'-t-butylbenzoyl)-2-(2",5"-dimethylbenzoyl) hydrazine
• 英文别名: N'-(4-tert-butylbenzoyl)-2,5-dimethylbenzohydrazide
• CAS: 1004679-42-8
• 化学式: C₂₀H₂₄N₂O₂
• 分子量: 324.423
• InChiKey: RRYUWWIRBZZTAP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  24
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  58.2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-(4'-t-butylbenzoyl)-2-(2",5"-dimethylbenzoyl) hydrazine 在 N-溴代丁二酰亚胺(NBS) 、 氯化亚砜 、 过氧化苯甲酰 作用下， 以 四氯化碳 、 甲苯 为溶剂， 反应 24.0h， 生成 2-(4'-t-butylphenyl)-5-(2'',5''-dibromomethylphenyl)-1,3,4-oxadiazole
  参考文献：
  名称：

  SYNTHESIS AND ELECTROOPTICAL PROPERTIES OF NOVEL PPV DERIVATIVES CONTAINING 1,3,4-OXADIAZOLE

  摘要：

  Poly[2-{5'-(4"-t-butylphenyl)-1',3',4'-oxadiazole}-1,4-phenylenevinylene (BPOD-PPV)] containing 4-t-butylphenyl-1,3,4-oxadiazole pendant was synthesized by Gilch reaction. Me obtained polymer shows a strong absorption centered around 300 nm and broader peak at about 350-520 nm. The efficiency of ITO/PPV/polymer/Al device is greater than by more than 2 orders of magnitude when compared with the ITO/PPV/Al device.

  DOI：

  10.1080/15421400390263884
• 作为产物：
  描述：

  对叔丁基苯甲酸甲酯 在 吡啶 、 一水合肼 作用下， 以 甲醇 、 甲苯 为溶剂， 反应 12.0h， 生成 1-(4'-t-butylbenzoyl)-2-(2",5"-dimethylbenzoyl) hydrazine
  参考文献：
  名称：

  SYNTHESIS AND ELECTROOPTICAL PROPERTIES OF NOVEL PPV DERIVATIVES CONTAINING 1,3,4-OXADIAZOLE

  摘要：

  Poly[2-{5'-(4"-t-butylphenyl)-1',3',4'-oxadiazole}-1,4-phenylenevinylene (BPOD-PPV)] containing 4-t-butylphenyl-1,3,4-oxadiazole pendant was synthesized by Gilch reaction. Me obtained polymer shows a strong absorption centered around 300 nm and broader peak at about 350-520 nm. The efficiency of ITO/PPV/polymer/Al device is greater than by more than 2 orders of magnitude when compared with the ITO/PPV/Al device.

  DOI：

  10.1080/15421400390263884

文献信息

• SYNTHESIS AND ELECTROOPTICAL PROPERTIES OF NOVEL PPV DERIVATIVES CONTAINING 1,3,4-OXADIAZOLE
  作者：Yun-Hi Kim、Dong-Cheol Shin、Sung-Ouk Jung、Soon-Ki Kwon、Do-Hoon Hwang

  DOI：10.1080/15421400390263884

  日期：2003.1

  Poly[2-5'-(4"-t-butylphenyl)-1',3',4'-oxadiazole}-1,4-phenylenevinylene (BPOD-PPV)] containing 4-t-butylphenyl-1,3,4-oxadiazole pendant was synthesized by Gilch reaction. Me obtained polymer shows a strong absorption centered around 300 nm and broader peak at about 350-520 nm. The efficiency of ITO/PPV/polymer/Al device is greater than by more than 2 orders of magnitude when compared with the ITO/PPV/Al device.