vinyl [1,1'-biphenyl]-4-carboxylate | 35374-80-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: vinyl [1,1'-biphenyl]-4-carboxylate
• 英文别名: 4-Phenyl-benzoesaeure-vinylester；biphenyl-4-carboxylic acid vinyl ester；Biphenyl-4-carbonsaeure-vinylester；Ethenyl 4-phenylbenzoate
• CAS: 35374-80-2
• 化学式: C₁₅H₁₂O₂
• 分子量: 224.259
• InChiKey: MHEHAHVCZQKGBW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  vinyl [1,1'-biphenyl]-4-carboxylate 、 在 三异丙基硅烷 、 安息香双甲醚 、 叔壬基硫醇 、 三氟乙酸 作用下， 以 N-甲基吡咯烷酮 为溶剂， 反应 1.0h， 以2.6 mg的产率得到
  参考文献：
  名称：

  使用溶液相CLipPA化学合成Paenipeptin C'类似物。

  摘要：

  我们在此报告了通过使用硫醇-烯类CLipPA（肽或氨基酸上的半胱氨酸脂质化）化学方法安装不同的脂质部分，合成抗菌脂肽，paenipeptin C'的类似物的方法。对革兰氏阴性和革兰氏阳性菌株的生物学评估表明，几种类似物具有有效的广谱抗菌活性。

  DOI：

  10.1039/d0ob00950d
• 作为产物：
  描述：

  乙酸乙烯酯 、 4-苯基苯甲酸 在 mercury(II) diacetate 、 硫酸 作用下， 反应 24.17h， 以63%的产率得到vinyl [1,1'-biphenyl]-4-carboxylate
  参考文献：
  名称：

  使用溶液相CLipPA化学合成Paenipeptin C'类似物。

  摘要：

  我们在此报告了通过使用硫醇-烯类CLipPA（肽或氨基酸上的半胱氨酸脂质化）化学方法安装不同的脂质部分，合成抗菌脂肽，paenipeptin C'的类似物的方法。对革兰氏阴性和革兰氏阳性菌株的生物学评估表明，几种类似物具有有效的广谱抗菌活性。

  DOI：

  10.1039/d0ob00950d

文献信息

• Cross-linking in the polymerization of vinyl benzoate and related compounds
  作者：George E. Ham、Eugene L. Ringwald

  DOI：10.1002/pol.1952.120080107

  日期：1952.1

  Branching and cross-linking are noted in emulsion and mass polymerizations involving vinyl benzoate and nuclearly substituted vinyl benzoates. A theory is proposed to account for this phenomenon based on free radical addition to the benzoate nucleus. Six new vinyl esters of substituted benzoic acids are described.

  在涉及苯甲酸乙烯酯和核取代的苯甲酸乙烯酯的乳液和本体聚合中注意到支化和交联。提出了一种理论来解释这种基于苯甲酸盐核中自由基加成的现象。描述了六种新的取代苯甲酸乙烯基酯。
• PHOTOREACTIVE COMPOSITION, OPTICAL MATERIAL, COMPOSITION FOR FORMING HOLOGRAPHIC RECORDING LAYER, HOLOGRAPHIC RECORDING MATERIAL, AND HOLOGRAPHIC RECORDING MEDIUM
  申请人：Miki Yasuaki

  公开号：US20110092612A1

  公开（公告）日：2011-04-21

  A novel polymerizable high-refractive index compound which is useful as an optical material, and a holographic recording medium using the same, which has high diffraction efficiency, high light transmittance and small rate of shrinkage, are provided. A composition for forming a holographic recording layer containing a reactive compound represented by the following formula 1, a holograph recording material, and a holographic recording medium provided with a recording layer containing the same, are disclosed. (In the formula (1), A is an optionally substituted ring; Ar is an optionally substituted (hetero)aryl group formed by condensation of two or more rings; R is hydrogen or a methyl group; n is an integer of from 1 to 7; and when n is 2 or more, then plural Ars may be the same as or different from each other, provided that when A is an aromatic heterocyclic ring, and Ar is an optionally substituted (hetero)aryl group formed by condensation of two or more rings, then in the structure in which A and Ar are connected with each other, those partial structures that are in the structure of each of A and Ar, and are connected directly with each other, do not contain a heteroatom.)

  提供一种新型可聚合高折射率化合物，可用作光学材料，以及使用该化合物的全息记录介质，其具有高衍射效率、高透光率和小的收缩率。公开了一种含有以下式子1所表示的反应性化合物的全息记录层组成物、全息记录材料以及具有包含该化合物的记录层的全息记录介质。(在式子（1）中，A是可选取代的环；Ar是由两个或多个环缩合形成的可选取代的（杂）芳基基团；R是氢或甲基基团；n是1到7的整数；当n为2或更多时，复数的Ar可以相同或不同，但当A是芳香杂环环时，且Ar是由两个或多个环缩合形成的可选取代的（杂）芳基基团时，在A和Ar相互连接的结构中，直接相连的那些部分结构不包含杂原子。)
• Electrochemically induced Markovnikov-type selective hydro/deuterophosphonylation of electron-rich alkenes
  作者：Weijie Deng、Yunfei Hu、Jinhui Hu、Xinling Li、Yibiao Li、Yubing Huang

  DOI：10.1039/d2cc04729b

  日期：——

  The regioselective hydro/deuterophosphonylation of electron-rich alkenes with P(O)H compounds has been realized via a metal-free electrochemically induced strategy, accessing various Markovnikov-type adducts in high yields. A series of monodeuterated organophosphorus compounds with high deuterium (D) incorporation are subsequently obtained by adding D2O as the D source. The protocol features broad

  通过无金属电化学诱导策略实现了富电子烯烃与 P(O)H 化合物的区域选择性加氢/氘代膦酰化，以高产率获得各种马尔科夫尼科夫型加合物。随后通过添加D 2 O作为D源，获得了一系列具有高氘（D）掺入的单氘化有机磷化合物。该协议具有广泛的衬底范围、低能耗、高原子经济性和可扩展性。单氘代有机磷酸可通过后期转化合成。
• Nickel-Catalyzed, Enantioselective Hydrofluoromethylation of Olefins: Access to Chiral α-Fluoromethylated Amides and Esters
  作者：Yiming Du、Shuxin Chen、Hexiang Cao、Yichen Zhang、Hongtao Lei、Guoqin Xia、Huicai Huang、Zhaodong Li

  DOI：10.1021/acs.orglett.3c00357

  日期：——

  hydrofluoromethylation of enamides and enol esters with CH2FI as the fluoromethyl source to enable the diversity-oriented synthesis (DOS) of chiral α-fluoromethylated amides as well as esters with features of wide functional group compatibility as well as excellent enantioselectivity. The synthetic value of this protocol was demonstrated by transformations of the resulted α-fluoromethylated amides to

  我们在此报道了以 CH 2 FI 作为氟甲基源的镍催化的烯酰胺和烯醇酯的对映选择性氢氟甲基化，以实现手性 α- 氟甲基化酰胺以及具有广泛官能团相容性特征的酯的多样性导向合成（DOS）以及优异的对映选择性。通过将生成的 α-氟甲基化酰胺转化为不同的支架，包括胺、恶唑啉、噻唑啉和 α-氟甲基化四氢喹啉，证明了该协议的合成价值。
• POLYLACTIC ACID RESIN COMPOSITION, PROCESS FOR PRODUCING THE SAME, BIAXIALLY STRETCHED POLYLACTIC ACID FILM, AND MOLDED ARTICLES THEREOF
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP1609819A1

  公开（公告）日：2005-12-28

  The invention provides a resin composition containing poly (lactic acid) and a cellulosic ester, which are biomass type materials; a resin composition excellent in transparency, mechanical properties, and thermostability; a biaxially drawn film containing poly(lactic acid) and at least one compound selected from cellulosic esters, poly(meth)acrylates, and polyvinyl compounds having a glass transition temperature of 60°C or higher; and a biaxially drawn film excellent in transparency, mechanical properties, and thermostability. The aims of the invention can be achieved by a resin composition obtained by melt-kneading a poly(lactic acid) polymer with a weight average molecular weight of 50,000 or higher and a cellulosic ester; a resin composition excellent in transparency and having luminous transmittance of 40% or higher for visible light with 400 nm; its production method; a molded article and a film made of the resin composition; a poly(lactic acid) biaxially drawn film containing a poly(lactic acid) polymer with a weight average molecular weight of 50, 000 or higher and at least one compound selected from cellulosic esters, poly(meth)acrylates, and polyvinyl compounds having a glass transition temperature of 60°C or higher; a poly(lactic acid) biaxially drawn film excellent in transparency and having film haze of 10% or lower; and a molded article made of the film.

  本发明提供了一种含有聚（乳酸）和纤维素酯的树脂组合物，它们都是生物质类材料；一种透明度、机械性能和热稳定性优异的树脂组合物；一种双轴拉伸薄膜，它含有聚（乳酸）和至少一种选自纤维素酯、聚（甲基）丙烯酸酯和聚乙烯醇化合物的化合物，其玻璃化转变温度为60℃或更高；以及一种透明度、机械性能和热稳定性优异的双轴拉伸薄膜。本发明的目的可以通过以下方法实现：一种通过熔融捏合重量平均分子量为 50,000 或更高的聚乳酸聚合物和纤维素酯而获得的树脂组合物；一种透明度极佳且对波长为 400 纳米的可见光的透光率为 40% 或更高的树脂组合物；其生产方法；由该树脂组合物制成的模塑制品和薄膜；一种聚（乳酸）双轴拉伸薄膜，该薄膜含有重量平均分子量为 50,000 或更高的聚 （乳酸）聚合物和至少一种选自纤维素酯、聚（甲基）丙烯酸酯和玻璃化转变温度为 60°C 或更高的聚乙烯化合物的化合物；一种透明度极佳且薄膜雾度为 10% 或更低的聚 （乳酸）双轴拉伸薄膜；以及一种由该薄膜制成的成型品。