(2E,4E)-2-methyldodeca-2,4-dienoic acid | 1093838-22-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (2E,4E)-2-methyldodeca-2,4-dienoic acid
• CAS: 1093838-22-2
• 化学式: C₁₃H₂₂O₂
• 分子量: 210.316
• InChiKey: RNPDCAAZAYHCFV-HULFFUFUSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  15
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (2E,4E)-2-methyldodeca-2,4-dienoic acid 、 DL-丝氨酸甲酯盐酸盐 在 (benzotriazo-1-yloxy)tris(dimethylamino)phosphonium hexafluorophosphate 、 N,N-二异丙基乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 3.5h， 以96%的产率得到(2E,4E)-3-hydroxy-2-(2-methyldodeca-2,4-dienoylamino)-propionic acid methyl ester
  参考文献：
  名称：

  First Total Synthesis of Cyrmenin B₁

  摘要：

  A short and efficient synthesis of cyrmenin B-1, an antifungal metabolite of myxobacteria Cystobacter armeniaca and Archangium gephyra, is described. The crucial steps of the synthesis included the formation of the dehydroalanine moiety from the corresponding serine acetate and the formation of the beta-methoxyacrylate system via trimethylsilyldiazomethane methylation of the corresponding beta-hydroxy enamide.

  DOI：

  10.1021/jo802209m
• 作为产物：
  描述：

  (2E,4E)-2-methyldodeca-2,4-dienoic acid methyl ester 在 lithium hydroxide monohydrate 、 水 、 盐酸 作用下， 以 四氢呋喃 、 水 为溶剂， 反应 24.0h， 以96%的产率得到(2E,4E)-2-methyldodeca-2,4-dienoic acid
  参考文献：
  名称：

  First Total Synthesis of Cyrmenin B₁

  摘要：

  A short and efficient synthesis of cyrmenin B-1, an antifungal metabolite of myxobacteria Cystobacter armeniaca and Archangium gephyra, is described. The crucial steps of the synthesis included the formation of the dehydroalanine moiety from the corresponding serine acetate and the formation of the beta-methoxyacrylate system via trimethylsilyldiazomethane methylation of the corresponding beta-hydroxy enamide.

  DOI：

  10.1021/jo802209m

文献信息

• Lubricant composition for automatic transmission
  申请人：Nippon Oil Corporation

  公开号：EP1847585A2

  公开（公告）日：2007-10-24

  The invention provides a lubricant composition for automatic transmissions excellent in sustainability of anti-shudder property, low-temperature viscosity characteristics, and oxidation stability, and excellent and well-balanced in durability of friction characteristics, energy-conserving performance, and anti-fatigue performance on gears. The composition contains a base oil having a kinematic viscosity at 100 °C of 3.7-4.1 mm2/s, and composed of base oil having the viscosityof 2.5-4.5 mm2/s, and base oil having the viscosity of 10-40 mm2/s; 1-20 mass% poly(meth)acrylate viscosity index improver having Mw of 15000-30000; 2-4 mass% imide friction modifier having a C8-C30 hydrocarbon group; 0.01-0.04 mass% phosphorus extreme pressure agent in terms of phosphorus; and 0.01-0.04 mass% ashless dispersant having at least one alkyl or alkenyl group of a number average molecular weight of ≥2000 in terms of nitrogen, all with respect to the total amount of the composition, and has the viscosity of 5.6-5.8 mm2/s.

  本发明提供了一种用于自动变速器的润滑油组合物，该组合物在抗抖动性、低温粘度特性和氧化稳定性方面具有优异的持续性，并且在摩擦特性的耐久性、节能性能和齿轮抗疲劳性能方面具有优异且均衡的表现。该组合物包含 100 °C 运动粘度为 3.7-4.1 mm2/s 的基础油，由粘度为 2.5-4.5 mm2/s 的基础油和粘度为 10-40 mm2/s 的基础油组成；1-20 质量％的聚（甲基）丙烯酸酯粘度指数改进剂，其 Mw 为 15000-30000；2-4 质量％的具有 C8-C30 碳氢基团的酰亚胺摩擦改进剂；0.0.01-0.04质量％的磷极压剂；以及0.01-0.04质量％的无灰分散剂，其至少具有一个平均分子量≥2000的烷基或烯基（以氮计），所有这些相对于组合物的总量而言，其粘度为5.6-5.8 mm2/s。
• COCKROACH BAIT FEEDING STIMULI
  申请人：THE CLOROX COMPANY

  公开号：EP0558706A1

  公开（公告）日：1993-09-08
• A GROUP OF NOVEL ANTI-CANCER COMPOUNDS WITH SPECIFIC STRUCTURE
  申请人：Yang, Zhenhua

  公开号：EP1463707A2

  公开（公告）日：2004-10-06
• EP1463707A4
  申请人：——

  公开号：EP1463707A4

  公开（公告）日：2006-02-01
• LUBRICANT COMPOSITION FOR AUTOMATIC TRANSMISSION
  申请人：Itou Masaaki

  公开号：US20070270320A1

  公开（公告）日：2007-11-22

  The invention provides a lubricant composition for automatic transmissions excellent in sustainability of anti-shudder property, low-temperature viscosity characteristics, and oxidation stability, and excellent and well-balanced in durability of friction characteristics, energy-conserving performance, and anti-fatigue performance on gears. The composition contains a base oil having a kinematic viscosity at 100° C. of 3.7-4.1 mm 2 /s, and composed of base oil having the viscosity of 2.5-4.5 mm 2 /s, and base oil having the viscosity of 10-40 mm 2 /s; 1-20 mass % poly(meth)acrylate viscosity index improver having Mw of 15000-300.00; 2-4 mass % imide friction modifier having a C8-C30 hydrocarbon group; 0.01-0.04 mass % phosphorus extreme pressure agent in terms of phosphorus; and 0.01-0.04 mass % ashless dispersant having at least one alkyl or alkenyl group of a number average molecular weight of ≧2000 in terms of nitrogen, all with respect to the total amount of the composition, and has the viscosity of 5.6-5.8 mm 2 /s.