2H-,2H-,3H-,3H-全氟癸酸 | 812-70-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 2H-,2H-,3H-,3H-全氟癸酸
• 英文名称: 4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-pentadecafluorodecanoic acid
• 英文别名: 2H,2H,3H,3H-pentadecafluorodecanoic acid；3-(perfluoroheptyl)propanoic acid；3-perfluoroheptylpropanoic acid；7:3 FTCA；2H,2H,3H,3H-pentadecafluoro-decanoic acid；4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Pentadecafluor-decansaeure-(1)；2H,2H,3H,3H-Perfluorodecanoic acid
• CAS: 812-70-4
• 化学式: C₁₀H₅F₁₅O₂
• 分子量: 442.125
• InChiKey: HLBRGVKRZQSQHB-UHFFFAOYSA-N

物化性质

• 沸点：
  229.8±35.0 °C(Predicted)
• 密度：
  1.635±0.06 g/cm3(Predicted)
• 溶解度：
  可溶于DMSO（少许）、甲醇（少许）

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  27
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  17

安全信息

• 危险品标志：
  C
• 海关编码：
  2915900090

反应信息

• 作为反应物：
  描述：

  2H-,2H-,3H-,3H-全氟癸酸 在 lithium aluminium tetrahydride 作用下， 以 乙醚 为溶剂， 反应 16.0h， 生成 1H,1H,2H,2H,3H,3H-全氟-1-十一醇
  参考文献：
  名称：

  Coe,P.L. et al., Journal of the Chemical Society. Perkin transactions I, 1975, p. 654 - 656

  摘要：

  DOI：
• 作为产物：
  描述：

  E-3-F-庚基-2-丙烯腈 在 palladium on activated charcoal 硫酸 、 氢气 作用下， 以 乙醇 为溶剂， 反应 30.0h， 生成 2H-,2H-,3H-,3H-全氟癸酸
  参考文献：
  名称：

  Coe,P.L. et al., Journal of the Chemical Society. Perkin transactions I, 1975, p. 654 - 656

  摘要：

  DOI：

文献信息

• Synthesis and physicochemical evaluation of fluorinated lipopeptide precursors of ligands for microbubble targeting
  作者：Masayori Hagimori、Estefanía E Mendoza-Ortega、Marie Pierre Krafft

  DOI：10.3762/bjoc.17.45

  日期：——

  hydrophobic chains (CnF2n+1, n = 6, 7, 8, 1–3) grafted through a lysine moiety on a hydrophilic chain composed of a lysine–serine–serine (KSS) sequence followed by 5 SG sequences. These F-lipopeptides are precursors of targeting lipopeptide conjugates. A hydrocarbon counterpart with a C10H21 chain (4) was synthesized for comparison. The capacity for the F-lipopeptides to spontaneously adsorb at the

  配体靶向微泡引起了分子成像和化疗药物递送的关注。脂质-肽缀合物（脂肽）具有交替的丝氨酸-甘氨酸（SG） n片段，而不是脂质极性头和靶向配体之间的经典聚（氧乙烯）连接体，被提议用于脂质体介导的抗癌药物的选择性递送。在这里，我们报道了全氟烷基化脂肽（ F-脂肽）的合成，该脂肽带有两条疏水链（C n F 2 n +1 , n = 6, 7, 8, 1 – 3 ），通过赖氨酸部分接枝在由以下组成的亲水链上赖氨酸-丝氨酸-丝氨酸 (KSS) 序列，后跟 5 个 SG 序列。这些F-脂肽是靶向脂肽缀合物的前体。为了比较，合成了具有C 10 H 21链的烃对应物( 4 )。研究了当与二棕榈酰磷脂酰胆碱（DPPC）结合时， F-脂肽自发吸附在空气/水界面并形成单层的能力。 F-脂肽1 – 3表现出在空气/水界面形成单层的显着增强趋势，平衡表面压力达到约 7–10 mN m -1 ，而仅其烃类似物4的平衡表面压力小于
• REINFORCED FLUOROPOLYMER COMPOSITES COMPRISING SURFACE FUNCTIONALIZED NANOCRYSTALLINE CELLULOSE
  申请人：DOOLEY Brynn Mary

  公开号：US20130274406A1

  公开（公告）日：2013-10-17

  A reinforced fluoropolymer composite is presented, which includes a fluoropolymer and a fluoro-functionalized nanocrystalline cellulose in which the outer circumference of the nanocrystalline cellulose has been functionalized with fluorinated substrates. The fluoro-functionalized nanocrystalline cellulose may be used to produce stable dispersions with fluoropolymers exhibiting enhanced adhesion between the nanocrystalline particles and fluoropolymer in a composite material, and decreased surface free energy of the cellulose surface.

  介绍了一种强化的氟聚合物复合材料，其中包括氟聚合物和氟功能化的纳米晶体纤维素，其中纳米晶体纤维素的外周已经使用氟化底物进行了功能化。氟功能化的纳米晶体纤维素可用于生产稳定的分散体，其中纳米晶体颗粒和氟聚合物之间的粘附性得到增强，并且纤维素表面的自由能降低。
• Methods for preparing reinforced fluoropolymer composites comprising surface functionalized nanocrystalline cellulose
  申请人：Dooley Brynn Mary

  公开号：US08674013B2

  公开（公告）日：2014-03-18

  A method of preparing a reinforced fluoropolymer composite is presented, which includes reacting a surface of a nanocrystalline cellulose with a fluorinated electrophile to form a fluoro-functionalized nanocrystalline in which the outer circumference of the nanocrystalline cellulose has been functionalized with fluorinated substrates, and contacting the fluoro-functionalized nanocrystalline cellulose with a fluoropolymer to form a fluoropolymer composite. Also presented is a method of preparing fluoro-functionalized nanocrystalline cellulose, including reacting a surface of a nanocrystalline cellulose with a fluorinated electrophile forming fluoro-functionalized nanocrystalline cellulose in which the outer circumference of the nanocrystalline cellulose has been functionalized with fluorinated substrates, precipitating the fluoro-functionalized nanocrystalline cellulose and isolating and purifying the fluoro-functionalized nanocrystalline cellulose.

  提供了一种制备增强型氟聚合物复合材料的方法，包括将纳米晶纤维素表面与氟化电子亲合剂反应，形成氟功能化的纳米晶纤维素，其中纳米晶纤维素的外周已经被氟化底物功能化，并将氟功能化的纳米晶纤维素与氟聚合物接触以形成氟聚合物复合材料。还提供了一种制备氟功能化纳米晶纤维素的方法，包括将纳米晶纤维素表面与氟化电子亲合剂反应，形成氟功能化的纳米晶纤维素，其中纳米晶纤维素的外周已经被氟化底物功能化，然后沉淀氟功能化的纳米晶纤维素，分离和纯化氟功能化的纳米晶纤维素。
• Reinforced fluoropolymer composites comprising surface functionalized nanocrystalline cellulose
  申请人：Dooley Brynn Mary

  公开号：US09328256B2

  公开（公告）日：2016-05-03

  A reinforced fluoropolymer composite is presented, which includes a fluoropolymer and a fluoro-functionalized nanocrystalline cellulose in which the outer circumference of the nanocrystalline cellulose has been functionalized with fluorinated substrates. The fluoro-functionalized nanocrystalline cellulose may be used to produce stable dispersions with fluoropolymers exhibiting enhanced adhesion between the nanocrystalline particles and fluoropolymer in a composite material, and decreased surface free energy of the cellulose surface.

  介绍了一种增强型氟聚合物复合材料，其中包括一种氟聚合物和一种具有氟功能化纳米晶体纤维素的材料，其中纳米晶体纤维素的外周已经被氟化底物功能化。氟功能化纳米晶体纤维素可用于与氟聚合物产生稳定的分散液，复合材料中纳米晶体颗粒与氟聚合物之间的附着力得到增强，纤维素表面的自由能降低。
• POLYCARBONATE POLYMER, PRODUCTION THEREOF, AND ELECTROPHOTOGRAPHIC PHOTORECEPTOR MADE THEREFROM
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0582722A1

  公开（公告）日：1994-02-16

  A polycarbonate polymer wherein the repeating unit is a group represented by general formula (I) and the terminal group is a group represented by formulae (I), (II), (III), (IV) or (V). In formula (I) R¹ and R² represent each halogen, alkyl, cycloalkyl or aryl; a and b represent each independently an integer of 0 to 4; x represents a single bond, -O-, -CO-, -S-, -SO-, -SO₂-, -CR³R⁴-, 1,1-cycloalkylidene or α,ω-alkylene; in formulae (II), (III), (IV) and (V) R⁵ represents C₁-C₃₀ perfluoroalkyl which may be substituted; Y represents -CH₂; n represents and integer of 0 to 6; Z represents -O-, -CO-, -OCO-, -S-, -SO-, -SO₂-or -NHCO-; f represents 0 to 1; R⁶ represents halogen, alkyl, cycloalkyl or aryl; and c and d represent each an interger provided that c + d ≦ 5, c = 1 - 5 and d = 0 - 4. An electrophotographic photoreceptor containing the polycarbonate as one component of the photosensitive layer, which is free from the problem of clouding (gelation) of a coating fluid used for making the same, retains excellent mechanical strengths such a plate wear, and can maintain excellent electrophotographic characteristics, thus being practically excellent.

  一种聚碳酸酯聚合物，其中重复单元为通式 (I) 所代表的基团，末端基团为式 (I)、(II)、(III)、(IV) 或 (V) 所代表的基团。在式 (I) 中，R¹ 和 R² 各自代表卤素、烷基、环烷基或芳基；a 和 b 各自独立地代表 0 至 4 的整数；x 代表单键、-O-、-CO-、-S-、-SO-、-SO₂-、-CR³R⁴-、1,1-环烷基亚基或 α,ω-亚烷基；在式(II)、(III)、(IV)和(V)中，R⁵ 代表可能被取代的 C₁-C₃₀ 全氟烷基；Y代表-CH₂；n代表0至6的整数；Z代表-O-、-CO-、-OCO-、-S-、-SO-、-SO₂-或-NHCO-；f代表0至1；R⁶代表卤素、烷基、环烷基或芳基；以及c和d分别代表一个整数，条件是c+d≦5，c＝1-5，d＝0-4。含有聚碳酸酯作为感光层成分之一的电致发光感光体，不存在用于制造该感光体的涂布液混浊（凝胶化）的问题，可保持极佳的机械强度（如板磨损），并可保持极佳的电致发光特性，因此实际上是极佳的。