3,3',5,5'-四醛基联苯 | 150443-85-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 3,3',5,5'-四醛基联苯
• 英文名称: [1,1'-biphenyl]-3,3',5,5'-tetracarbaldehyde
• 英文别名: biphenyl-3,3′,5,5′-tetracarbaldehyde；5-(3,5-diformylphenyl)benzene-1,3-dicarbaldehyde
• CAS: 150443-85-9
• 化学式: C₁₆H₁₀O₄
• 分子量: 266.253
• InChiKey: NAAGEIPGMZPBFY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  68.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  (2,4,6-三-叔-丁基苯基)膦 、 3,3',5,5'-四醛基联苯 生成 3,3',5,5'-tetra(tri-t-butylphenyl phosphaethylene) biphenyl
  参考文献：
  名称：

  3,3′,5,5′ tetra(phosphaalkene) biphenyl: Synthesis of a novel bicyclometalating bridging ligand, and structure of its dipalladium complex.

  摘要：

  A biphenyl derivative bearing four phosphaalkene groups in positions 3,3',5,5' has been synthesized and is shown to be a bis-terdentate chelating agent; this novel bridging ligand forms a complex with two palladium ions and the crystal structure of this dinuclear species has been obtained.

  DOI：

  10.1016/s0040-4039(00)79169-6
• 作为产物：
  描述：

  5-溴异苯二醛 在 四(三苯基膦)钯 、 安息香精油 、 caesium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 2.0h， 以35%的产率得到3,3',5,5'-四醛基联苯
  参考文献：
  名称：

  Two-dimensional dual-pore covalent organic frameworks obtained from the combination of two D_2h symmetrical building blocks

  摘要：

  已开发出一种构建具有两种不同孔隙的共价有机框架（COFs）的策略。制备的双孔COFs表现出良好的CO₂和H₂吸附能力。

  DOI：

  10.1039/c6cc06637b

文献信息

• Two-dimensional dual-pore covalent organic frameworks obtained from the combination of two D_2h symmetrical building blocks
  作者：Yuan Tian、Shun-Qi Xu、Cheng Qian、Zhong-Fu Pang、Guo-Fang Jiang、Xin Zhao

  DOI：10.1039/c6cc06637b

  日期：——

  A strategy to construct covalent organic frameworks (COFs) bearing two different kinds of pores has been developed. The as-prepared dual-pore COFs exhibit good adsorption capacities for CO₂ and H₂.

  已开发出一种构建具有两种不同孔隙的共价有机框架（COFs）的策略。制备的双孔COFs表现出良好的CO₂和H₂吸附能力。
• METHODS OF USE COMPRISING A BIOCIDAL POLYAMINE
  申请人：Curza Global, LLC

  公开号：US20150038705A1

  公开（公告）日：2015-02-05

  Compounds, compositions, and methods comprising a polyamine compound are described, which may be used to kill, disperse, treat, reduce biofilms, and/or inhibit or substantially prevent biofilm formation. In certain aspects, the present invention relates to compounds, compositions, and methods comprising polyamine compounds that have antimicrobial or dispersing activity against a variety of bacterial strains capable of forming biofilms.

  本发明描述了包含聚胺化合物的化合物、组合物和方法，可用于杀灭、分散、治疗、减少生物膜和/或抑制或实质性地预防生物膜形成。在某些方面，本发明涉及包含具有抗微生物或分散活性的聚胺化合物的化合物、组合物和方法，用于对能够形成生物膜的各种细菌菌株进行处理。
• METHODS OF USE FOR COMPOSITIONS COMPRISING A BIOCIDAL POLYAMINE
  申请人：The University of Utah

  公开号：US20140350017A1

  公开（公告）日：2014-11-27

  Compounds, compositions, and methods comprising a polyamine compound are described, which may be used to kill, disperse, treat, reduce biofilms, and/or inhibit or substantially prevent biofilm formation. In certain aspects, the present invention relates to compounds, compositions, and methods comprising polyamine compounds that have antimicrobial or dispersing activity against a variety of bacterial strains capable of forming biofilms.

  本发明涉及包含聚胺化合物的化合物、组合物和方法，可用于杀灭、分散、治疗、减少生物膜，以及抑制或几乎完全防止生物膜形成。在某些方面，本发明涉及包含聚胺化合物的化合物、组合物和方法，这些化合物具有抗微生物或分散活性，可对能够形成生物膜的各种细菌菌株产生影响。
• Dual‐Atom Catalysts Derived from a Preorganized Covalent Organic Framework for Enhanced Electrochemical Oxygen Reduction
  作者：Wen‐Da Zhang、Lang Zhou、Ya‐Xiang Shi、Yong Liu、Hanwen Xu、Xiaodong Yan、Yan Zhao、Yuqin Jiang、Jiangwei Zhang、Zhi‐Guo Gu

  DOI：10.1002/anie.202304412

  日期：2023.7.3

  Fe dual-atom catalysts with Fe2N6C8O2 configuration were fabricated through the one-step carbonization of a preorganized covalent organic framework, which exhibited high oxygen reduction activity due to the enhanced adsorption of *OOH, and adjustable d-band center.

  通过预组织共价有机骨架的一步碳化制备了具有Fe 2 N 6 C 8 O 2构型的Fe双原子催化剂，由于*OOH的吸附增强和可调节的d带而表现出高氧还原活性中心。
• COMPOSITIONS COMPRISING A BIOCIDAL POLYAMINE
  申请人：Curza Global, LLC

  公开号：US20160330962A1

  公开（公告）日：2016-11-17

  Compounds, compositions, and methods comprising a polyamine compound are described, which may be used to kill, disperse, treat, or reduce biofilms, or to inhibit or substantially prevent biofilm formation. In certain aspects, the present invention relates to compounds, compositions, and methods comprising polyamine compounds that have antimicrobial or dispersing activity against a variety of bacterial strains capable of forming biofilms.