(9Z,11E)-9,11,13-tetradecatrien-1-yl acetate | 129196-62-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (9Z,11E)-9,11,13-tetradecatrien-1-yl acetate
• 英文别名: (Z,E)-9,11,13-tetradecatrien-1-yl acetate；(Z,E)-1-Acetoxy-9,11,13-tetradecatriene；9Z,11E,13-Tetradecatrienyl acetate；[(9Z,11E)-tetradeca-9,11,13-trienyl] acetate
• CAS: 129196-62-9
• 化学式: C₁₆H₂₆O₂
• 分子量: 250.381
• InChiKey: WPJGJVIVVQDMIG-DEQVHDEQSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  18
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1-terbutoxy-9-decyne 在 钯 吡啶 、 甲醇 、 potassium cyanide 、 氢氧化钾 、 三氯化铁 、 锌 作用下， 以 丙醇 、 乙醚 、 水 为溶剂， 反应 39.0h， 生成 (9Z,11E)-9,11,13-tetradecatrien-1-yl acetate
  参考文献：
  名称：

  Stereospecific synthesis of (Z,E)-9,11,13-tetradecatrien-1-yl acetate and aldehyde sex pheromone components of stenoma cecropia and ectomyelois ceratoniae

  摘要：

  DOI：

  10.1016/0040-4039(90)80210-d

文献信息

• An efficient synthesis of 1,3(E),5(Z), 1,3(E),5(E) and 1,3(Z),5(Z)-trienes: Application to the synthesis of galbanolenes and (9Z,11E)-9,11,13-tetradecatrien-1-yl acetate
  作者：Mouâd Alami、Sylvie Gueugnot、Elisa Domingues、Gérard Linstrumelle

  DOI：10.1016/0040-4020(94)00991-3

  日期：1995.1

  The (Pd-Cu)-catalyzed reactions of trimethylsilyl acetylene with (E) or (Z)-chloroenynes, or 1-chloro-(1E,3E)-dienes, followed by desilylation and zinc-reduction of the triple bonds led respectively to (3E,5Z), (3Z,5Z) and (3E,5E)-trienes. Application to the syntheses of galbanolenes and (9Z,11E)-9,11,13-tetradecatrien-1-yl acetate has been realized.

  三甲基甲硅烷基乙炔与（E）或（Z）-氯乙炔或1-氯-（1E，3E）-二烯的（Pd-Cu）催化反应，然后对三键进行甲硅烷基化和锌还原（3E，5Z），（3Z，5Z）和（3E，5E）三烯。已经实现了其在加拉班油烯和乙酸（9Z，11E）-9,11,13-十四碳三烯-1-基酯的合成中的应用。
• Stereospecific synthesis of (Z,E)-9,11,13-tetradecatrien-1-yl acetate and aldehyde sex pheromone components of stenoma cecropia and ectomyelois ceratoniae
  作者：Frédérique Tellier、Charles Descoins

  DOI：10.1016/0040-4039(90)80210-d

  日期：1990.1
• TELLIER, FREDERIQUE;DESCOINS, CHARLES, TETRAHEDRON LETT , 31,(1990) N6, C. 2295-2298
  作者：TELLIER, FREDERIQUE、DESCOINS, CHARLES

  DOI：——

  日期：——
• PHEROMONE DISPENSER
  申请人：Harmsen Sven

  公开号：US20110266361A1

  公开（公告）日：2011-11-03

  The present invention relates to a pheromone dispenser, filled with pheromone or a pheromone-comprising liquid and comprising (a) a deep-drawn plastic film made of a thermoplastic film material and featuring at least one dish-shaped zone for receiving a pheromone, and a planar plastic film made of a thermoplastic film material and which is connected with the deep-drawn plastic film, the planar plastic film together with the at least one dish-shaped zone of the deep-drawn plastic film forming a durably sealed chamber which comprises the pheromone or the pheromone-comprising liquid, and (c) a recess in the zone of the interconnected plastic films, the planar plastic film being permeable to the pheromone. The invention also relates to a process for producing such a pheromone dispenser.
• Sex pheromone ofStenoma cecropia Meyrick (Lepidoptera: Elachistidae)
  作者：Pierre Zagatti、Philippe Lucas、Philippe Genty、Sandra Arango、Christian Malosse、Frédérique Tellier

  DOI：10.1007/bf02027948

  日期：1996.6

  (Z,E)-9,11-tetradecadienal (Z9,E11-14: Ald; 11%), (Z,E)-9,11,13-tetradecatrienal (Z9,E11, 13-14:Ald; 67%), (Z,E)-9,11-tetradecadienyl acetate (Z9,E11-14:Ac, 5.5%), and (Z,E)-9,11, 13-tetradecatrienyl acetate (Z9,E11,13-14:Ac; 16.5%) were identified in the extracts of female pheromone glands of Stenoma cecropia (Lepidoptera: Elachistidae). From electroantennograms and single sensillum recordings, receptors to Z9,E 11,13-14:Ald and Z9,E11-14:Ald were found on male antenna. Behavioral data were obtained from olfactometric tests in the laboratory and field trapping experiments in Colombia. It appeared that a blend of Z9,E11,13-14:Ald (83%) and Z9,E11-14:Ald (17%) was attractive to males. These aldehydes are assumed to be components of the sex pheromone of S. cecropia, whereas the acetates found in gland extracts might be precursors of the pheromone.