1-acetoxy-2-dodecanone | 123903-27-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 1-acetoxy-2-dodecanone
• 英文别名: 2-oxododecyl acetate
• CAS: 123903-27-5
• 化学式: C₁₄H₂₆O₃
• 分子量: 242.359
• InChiKey: CDNRCUWGUZZXCB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  17
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  43.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  1-O-acetyl-1,2-dodecanediol 在 sodium bromite 、 4-benzyloxy-2,2,6,6-tetramethylpiperidin-1-oxyl 、 碳酸氢钠 作用下， 以 二氯甲烷 、 水 为溶剂， 反应 4.0h， 以95%的产率得到1-acetoxy-2-dodecanone
  参考文献：
  名称：

  A selective and efficient method for alcohol oxidations mediated by N-oxoammonium salts in combination with sodium bromite

  摘要：

  DOI：

  10.1021/jo00289a016

文献信息

• Straightforward and Highly Efficient Synthesis of α-Acetoxy Ketones through Gold-Catalyzed Intermolecular Oxidation of Terminal Alkynes
  作者：Weimin He、Jiannan Xiang、Chao Wu、Zhiwu Liang、Dong Yan

  DOI：10.1055/s-0033-1338513

  日期：——

  corresponding α-acetoxy ketones through gold-catalyzed intermolecular oxidation in the presence of 8-methylquinoline 1-oxide as the oxidant. The reaction probably proceeds through an α-oxo gold carbene intermolecular O–H insertion. A variety of terminal alkynes were efficiently converted into the corresponding α-acetoxy ketones through gold-catalyzed intermolecular oxidation in the presence of 8-methylquinoline

  摘要 在存在8-甲基喹啉1-氧化物作为氧化剂的情况下，通过金催化的分子间氧化将各种末端炔烃有效地转化为相应的α-乙酰氧基酮。该反应可能通过α-氧代金卡宾分子间OH插入而进行。 在存在8-甲基喹啉1-氧化物作为氧化剂的情况下，通过金催化的分子间氧化将各种末端炔烃有效地转化为相应的α-乙酰氧基酮。该反应可能通过α-氧代金卡宾分子间OH插入而进行。
• COMPOSITIONS AND METHODS FOR DIRECTING THE OVIPOSITION OF MOSQUITOES
  申请人：LAURENTIAN UNIVERSITY

  公开号：US20150359215A1

  公开（公告）日：2015-12-17

  Compositions described herein are purposed to attract gravid mosquitoes to oviposit in a preferred environment. The composition for directing the oviposition of mosquitoes comprises one or more attractants and N—P—K additive, wherein the N—P—K additive is mixture that contain chemical elements nitrogen, phosphorus and potassium. The attractants can be modified to provide a composition for facilitating the oviposition of different kind of mosquito. The composition described above, can be modified to provide a composition for facilitating the oviposition of the Anopheles species of Culicidae. The composition can also include cooked whey, n-heneicosane and/or tetradecanoic acid methyl ester to provide a composition for facilitating the oviposition of the Aedes species of Culicidae. The composition can also be modified to provide a composition for facilitating the oviposition of the Culex species of Culicidae.

  本文描述的组合物旨在吸引孕蚊在优选环境中产卵。用于引导蚊子产卵的组合物包括一种或多种诱引剂和N-P-K添加剂，其中N-P-K添加剂是一种混合物，其中包含化学元素氮、磷和钾。诱引剂可以被修改以提供一种促进不同种类蚊子产卵的组合物。上述组合物可以被修改以提供一种促进疟蚊属蚊子产卵的组合物。该组合物还可以包括煮熟的乳清、正十一烷和/或十四酸甲酯，以提供一种促进伊蚊属蚊子产卵的组合物。该组合物还可以被修改以提供一种促进库蚊属蚊子产卵的组合物。
• Compositions and methods for directing the oviposition of mosquitoes
  申请人：Laurentian University of Sudbury

  公开号：US10757933B2

  公开（公告）日：2020-09-01

  Compositions described herein are purposed to attract gravid mosquitoes to oviposit in a preferred environment. The composition for directing the oviposition of mosquitoes comprises one or more attractants and N—P—K additive, wherein the N—P—K additive is mixture that contain chemical elements nitrogen, phosphorus and potassium. The attractants can be modified to provide a composition for facilitating the oviposition of different kind of mosquito. The composition described above, can be modified to provide a composition for facilitating the oviposition of the Anopheles species of Culicidae. The composition can also include cooked whey, n-heneicosane and/or tetradecanoic acid methyl ester to provide a composition for facilitating the oviposition of the Aedes species of Culicidae. The composition can also be modified to provide a composition for facilitating the oviposition of the Culex species of Culicidae.

  本文所述组合物的目的是吸引怀孕的蚊子在优选的环境中产卵。引导蚊子产卵的组合物包括一种或多种引诱剂和 N-P-K 添加剂，其中 N-P-K 添加剂是含有化学元素氮、磷和钾的混合物。引诱剂可以改性，以提供一种促进不同种类蚊子产卵的组合物。可以对上述成分进行改良，以提供一种促进疟蚊产卵的成分。该组合物还可包括熟乳清、正茴香烷和/或十四酸甲酯，以提供一种促进伊蚊排卵的组合物。还可对组合物进行改良，以提供一种促进库蚊的排卵的组合物。
• [EN] COMPOSITIONS AND METHODS FOR DIRECTING THE OVIPOSITION OF MOSQUITOES<br/>[FR] COMPOSITIONS ET PROCÉDÉS D'ORIENTATION DE L'OPPOSITION DES MOUSTIQUES
  申请人：LAURENTIAN UNIVERSITY

  公开号：WO2014113876A8

  公开（公告）日：2014-09-04
• Reed, Kathryn L.; Gupton, John T.; McFarlane, Karyn L., Synthetic Communications, 1989, vol. 19, # 13-14, p. 2595 - 2602
  作者：Reed, Kathryn L.、Gupton, John T.、McFarlane, Karyn L.

  DOI：——

  日期：——