(2E,5E)-2-(4-methoxybenzylidene)-5-(4-hydroxybenzylidene)cyclopentanone | 1321890-09-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: (2E,5E)-2-(4-methoxybenzylidene)-5-(4-hydroxybenzylidene)cyclopentanone
• 英文别名: (2E,5E)-2-[(4-hydroxyphenyl)methylidene]-5-[(4-methoxyphenyl)methylidene]cyclopentan-1-one
• CAS: 1321890-09-8
• 化学式: C₂₀H₁₈O₃
• 分子量: 306.361
• InChiKey: OCVCLVXMDVZLEC-UNZYHPAISA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  23
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  (E)-2-(4-甲氧基亚苄基)环戊酮 、 对羟基苯甲醛 在 二甲基铵-二甲基 作用下， 以 氯仿 为溶剂， 反应 120.5h， 以76%的产率得到(2E,5E)-2-(4-methoxybenzylidene)-5-(4-hydroxybenzylidene)cyclopentanone
  参考文献：
  名称：

  Synthesis of calixarene-based ketocyanine fluorophores

  摘要：

  Cup-shaped calix[4]arenes bearing one or two ketocyanine fluorophore fragments at the wide rim of the macrocycle are synthesized by condensation of formyl calix[4]arenes with arylmethylene(hetarylmethylene)cyclopentanones in the presence of the ionic liquid, dimethylammonium dimethylcarbamate (DIMCARB) and characterized using UV-vis and fluorescence spectroscopy. Strong positive solvatofluorochromism for the calixarene ketocyanines is observed. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.05.094

文献信息

• Synthesis of calixarene-based ketocyanine fluorophores
  作者：Yuriy Matvieiev、Iuliia Karpenko、Andrii Kulinich、Aleksey Ryabitskii、Vasyl Pivovarenko、Svitlana Shishkina、Oleg Shishkin、Vitaly Kalchenko

  DOI：10.1016/j.tetlet.2011.05.094

  日期：2011.7

  Cup-shaped calix[4]arenes bearing one or two ketocyanine fluorophore fragments at the wide rim of the macrocycle are synthesized by condensation of formyl calix[4]arenes with arylmethylene(hetarylmethylene)cyclopentanones in the presence of the ionic liquid, dimethylammonium dimethylcarbamate (DIMCARB) and characterized using UV-vis and fluorescence spectroscopy. Strong positive solvatofluorochromism for the calixarene ketocyanines is observed. (C) 2011 Elsevier Ltd. All rights reserved.