3,4-二苯基苯胺 | 10569-67-2

• 物质功能分类: 化学试剂 - 有机试剂 - 多环化合物
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 3,4-二苯基苯胺
• 英文名称: 4'-amino-o-terphenyl
• 英文别名: 3,4-diphenylaniline；3,4-Diphenyl-anilin；3.4-Diphenyl-anilin；4-Amino-o-terphenyl
• CAS: 10569-67-2
• 化学式: C₁₈H₁₅N
• 分子量: 245.324
• InChiKey: SGNQTSWLIUHTQZ-UHFFFAOYSA-N

物化性质

• 熔点：
  94-95 °C(Solv: ethanol (64-17-5))
• 沸点：
  387.5±21.0 °C(Predicted)
• 密度：
  1.103±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

安全信息

• 海关编码：
  2921499090

反应信息

• 作为反应物：
  描述：

  3,4-二苯基苯胺 在 N-溴代丁二酰亚胺(NBS) 、 四(三苯基膦)钯 、 二异丙胺 、 cesium fluoride 作用下， 以 二氯甲烷 、 乙腈 为溶剂， 反应 24.0h， 生成 3-bromotriphenylen-2-amine
  参考文献：
  名称：

  신규 방향족 아민 화합물 및 이를 이용한 유기전자소자

  摘要：

  新型芳香族胺化合物具有优异的发光效率和热稳定性，提供了其制备方法以及包含上述新型芳香族胺化合物的有机电子器件。

  公开号：

  KR101583349B1
• 作为产物：
  描述：

  4'-nitro-o-terphenyl 在 tin(II) chloride dihydrate 作用下， 以 乙酸乙酯 为溶剂， 反应 2.0h， 生成 3,4-二苯基苯胺
  参考文献：
  名称：

  Structurally Simple Inhibitors of Lanosterol 14α-Demethylase Are Efficacious In a Rodent Model of Acute Chagas Disease

  摘要：

  We report structure-activity studies of a large number of dialkyl imidazoles as inhibitors of Trypanosoma cruzi lanosterol-14 alpha-demethylase (L14DM). The compounds have a simple structure compared to posaconazole, another L14DM inhibitor that is an anti-Chagas drug candidate. Several compounds display potency for killing T cruzi amastigotes in vitro with values of EC50 in the 0.4-10 nM range. Two compounds were selected for efficacy studies in a mouse model of acute Chagas disease. At oral doses of 20-50 mg/kg given after establishment of parasite infection, the compounds reduced parasitemia in the blood to undetectable levels, and analysis of remaining parasites by PCR revealed a lack of parasites in the majority of animals. These dialkyl imidazoles are substantially less expensive to produce than posaconazole and are appropriate for further development toward an anti-Chagas disease clinical candidate.

  DOI：

  10.1021/jm900030h

文献信息

• A New Route to Polycondensed Aromatics: Photolytic Formation of Triphenylene and Dibenzo[<i>fg</i>,<i>op</i>]naphthacene Ring Systems
  作者：Takeo Sato、Shigeru Shimada、Kazuo Hata

  DOI：10.1246/bcsj.44.2484

  日期：1971.9

  triphenylene and dibenzo[fg,op]naphthacene was explored. Three types of reactions were developed: Photocyclodehydrogenation of polyphenyl compounds, photolytic reactions of iodoarenes, and photocyclodehydrohalogenation of halogenopolyaryls. The effects of solvent, oxidant, and wavelength on the photocyclization of o-terphenyl and 2,2′-diphenylbiphenyl to the triphenylene and naphthacene, respectively

  探索了光-芳基偶联反应在三亚苯和二苯并[fg,op]萘合成中的应用。开发了三种类型的反应：多苯基化合物的光环脱氢、碘芳烃的光解反应和卤代多芳基的光环脱氢卤化。考察了溶剂、氧化剂和波长对邻三联苯和 2,2'-二苯基联苯分别光环化为三亚苯和并四苯的影响。在等摩尔量的碘存在下，使用石英或 Vycor 容器在芳族溶剂中进行反应，从而最好地实现转化。从 2,2'-二苯基-联苯（57% 产率）、2,2'-双（2-氯苯基）联苯（67%）、1,2,3 开始形成并四苯，显示了该方法的多功能性-三苯苯 (21%), 或 2,
• 신규한 화합물 및 이를 이용한 유기 발광 소자
  申请人：주식회사 엘지화학

  公开号：KR20220022880A

  公开（公告）日：2022-02-28

  본 발명은 신규한 화합물 및 이를 이용한 유기 발광 소자를 제공한다.

  本发明提供了一种新化合物及其用途于有机发光器件。
• ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：HODOGAYA CHEMICAL CO., LTD.

  公开号：US20220102632A1

  公开（公告）日：2022-03-31

  [Object] An object of the present invention is to provide, as a material for an organic EL device having high efficiency and a high durability, a material for an organic EL device having excellent injection/transport performance of holes, excellent electron blocking capability, excellent stability in a thin-film state, and an excellent durability, and to further provide an organic EL device having high efficiency, a low drive voltage, and a long lifetime by combining the material and various materials for an organic EL device having excellent injection/transport performance of holes and electrons, excellent electron blocking capability, excellent stability in a thin-film state, and an excellent durability so that the properties of the respective materials can be effectively exhibited. [Solving Means] Since an arylamine compound having a specific structure in the present invention has excellent injection/transport performance of holes, excellent stability in a thin-film state, and an excellent durability, holes injected from the anode side can be effectively transported by selecting this arylamine compound having a specific structure as a material of a hole transport layer. Further, various organic EL devices obtained by combining an electron transport material having a specific structure and the like exhibit favorable device properties.

  [目的] 本发明的目的是提供一种用于有机电致发光器件的材料，具有高效率和高耐久性，具有出色的空穴注入/输运性能，优异的电子阻挡能力，薄膜状态下的优异稳定性和优异耐久性，并通过将该材料与具有出色的空穴和电子注入/输运性能、优异的电子阻挡能力、薄膜状态下的优异稳定性和优异耐久性的各种有机电致发光器件材料相结合，以有效展示各种材料的性能，进一步提供高效率、低驱动电压和长寿命的有机电致发光器件。 [解决手段] 由于本发明中具有特定结构的芳基胺化合物具有出色的空穴注入/输运性能、薄膜状态下的优异稳定性和优异耐久性，因此通过选择该具有特定结构的芳基胺化合物作为空穴输运层的材料，可以有效地输运从阳极侧注入的空穴。此外，通过结合具有特定结构的电子输运材料等的各种有机电致发光器件材料，可以获得良好的器件性能。
• N-HETEROARYLENE COMPOUNDS
  申请人：Novaled GmbH

  公开号：EP3527558A1

  公开（公告）日：2019-08-21

  The present invention relates to a compound according to formula 1: suitable for use as a layer material for electronic devices, and to an organic semiconductor layer comprising at least one compound according to formula 1, as well as to an organic electronic device comprising at least one organic semiconductor layer, and a method of manufacturing the same.

  本发明涉及一种符合公式1的化合物，适用于用作电子器件的层材料，以及至少包含一种符合公式1的化合物的有机半导体层，以及至少包含一种有机半导体层的有机电子器件和其制造方法。
• Organic molecules for use in organic devices
  申请人：CYNORA GMBH

  公开号：US11276825B2

  公开（公告）日：2022-03-15

  An organic molecules for use in optoelectronic devices is disclosed having a structure of formula A1: where A, RN, Ra and R2 are as defined herein.

  公开了一种用于光电子器件的有机分子，其结构式为A1:其中A，RN，Ra和R2的定义如本文所述。