3,4-二苯基环戊烯 | 175415-61-9

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 中文名称: 3,4-二苯基环戊烯
• 英文名称: 3,4-Diphenylcyclopentene
• 英文别名: 3,4-Diphenyl-cyclopenten；(2-Phenylcyclopent-3-en-1-yl)benzene
• CAS: 175415-61-9
• 化学式: C₁₇H₁₆
• 分子量: 220.314
• InChiKey: RTBDRLYNZOJMMV-UHFFFAOYSA-N

物化性质

• 沸点：
  321.5 °C(Press: 747 Torr)
• 密度：
  1.036 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  3,4-二苯基环戊烯 在 lithium aluminium tetrahydride 、 间氯过氧苯甲酸 作用下， 生成 2,3-Diphenylcyclopentanol
  参考文献：
  名称：

  Quantitative Analyses of the Four Isomers of 3,4-Diphenylcyclopentene by Chiral Gas Chromatography

  摘要：

  The four isomers of 3,4-diphenylcyclopentene are well resolved by chiral gas chromatography on a Cyclodex B column, eluting in the ordered sequence (3S,4R), (3R,4S), (3S,4S), and(3R,4R). Absolute stereochemical assignments were made through chemical correlations relating the 3,4-diphenylcyclopentenes with a known reference compound, (1S,2S)-(+)-cis-2-phenylcyclopentanol.

  DOI：

  10.1021/jo00123a010
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 生成 3,4-二苯基环戊烯
  参考文献：
  名称：

  Kishner, Zhurnal Russkago Fiziko-Khimicheskago Obshchestva, 1915, vol. 47, p. 1839

  摘要：

  DOI：

文献信息

• Kishner, Zhurnal Russkago Fiziko-Khimicheskago Obshchestva, 1915, vol. 47, p. 1839
  作者：Kishner

  DOI：——

  日期：——
• Quantitative Analyses of the Four Isomers of 3,4-Diphenylcyclopentene by Chiral Gas Chromatography
  作者：Lisa A. Asuncion、John E. Baldwin

  DOI：10.1021/jo00123a010

  日期：1995.9

  The four isomers of 3,4-diphenylcyclopentene are well resolved by chiral gas chromatography on a Cyclodex B column, eluting in the ordered sequence (3S,4R), (3R,4S), (3S,4S), and(3R,4R). Absolute stereochemical assignments were made through chemical correlations relating the 3,4-diphenylcyclopentenes with a known reference compound, (1S,2S)-(+)-cis-2-phenylcyclopentanol.