9-phenyl-3-[4-(triphenylen-2-yl)-phenyl]-9H-carbazole | 1369431-21-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 9-phenyl-3-[4-(triphenylen-2-yl)-phenyl]-9H-carbazole
• 英文别名: 9-Phenyl-3-(4-triphenylen-2-ylphenyl)carbazole；9-phenyl-3-(4-triphenylen-2-ylphenyl)carbazole
• CAS: 1369431-21-9
• 化学式: C₄₂H₂₇N
• 分子量: 545.683
• InChiKey: DIMPFZWFNIEZPC-UHFFFAOYSA-N

物化性质

• 密度：
  1.18±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  11.2
• 重原子数：
  43
• 可旋转键数：
  3
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  N-苯基-3-咔唑硼酸 在 palladium diacetate 、 三(邻甲基苯基)磷 potassium carbonate 作用下， 以 四氢呋喃 、 乙醇 、 水 、 甲苯 为溶剂， 反应 49.0h， 生成 9-phenyl-3-[4-(triphenylen-2-yl)-phenyl]-9H-carbazole
  参考文献：
  名称：

  ORGANIC COMPOUND, LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, ELECTRONIC DEVICE, AND LIGHTING DEVICE

  摘要：

  提供一种新型物质，可以实现发光元件寿命和发射效率的提高。提供一种具有通用式（G1）表示的结构的咔唑化合物。请注意，在通用式（G1）中，使取代基的HOMO能级和LUMO能级分别变深和变浅的取代基被用作每个取代基（R1、R2、Ar3和α3）。此外，在通用式（G1)中，使取代基的带隙（Bg）和T1能级分别变宽和变高的取代基被用作每个取代基（R1、R2、Ar3和α3）。

  公开号：

  US20120077987A1

文献信息

• Organic Compound, Light-Emitting Element, Light-Emitting Device, Electronic Device, and Lighting Device
  申请人：Semiconductor Energy Laboratory Co, Ltd.

  公开号：EP2433929A1

  公开（公告）日：2012-03-28

  A novel substance with which an increase in life and emission efficiency of a light-emitting element can be achieved is provided. A carbazole compound having a structure represented by General Formula (G1) is provided. Note that a substituent which makes the HOMO level and the LUMO level of a compound in which a bond of the substituent is substituted with hydrogen deep and shallow, respectively is used as each of substituents in General Formula (G1) (R1, R2, Ar3, and α3). Further, a substituent which makes the band gap (Bg) and the T1 level of a compound in which a bond of the substituent is substituted with hydrogen wide and high is used as each of the substituents in General Formula (G1) (R1, R2, Ar3, and α3).

  本发明提供了一种新型物质，利用该物质可提高发光元件的寿命和发射效率。本发明提供了一种具有通式（G1）所示结构的咔唑化合物。需要注意的是，通式（G1）中的每个取代基（R1、R2、Ar3 和 α3）中都使用了能使其键被氢取代的化合物的 HOMO 水平和 LUMO 水平分别变深和变浅的取代基。此外，通式（G1）（R1、R2、Ar3 和 α3）中的每个取代基都使用了能使其键被氢取代的化合物的带隙（Bg）和 T1 电平变宽和变高的取代基。
• Composition and organic optoelectric device and display device
  申请人：Cheil Industries Inc.

  公开号：EP2821459A2

  公开（公告）日：2015-01-07

  Disclosed are a composition including a first host compound including moieties represented by the Chemical Formulae 1 to 3 that are sequentially bonded with each other and a second host compound including at least one carbazole group with a substituent having hole characteristics, and an organic optoelectric device and a display device to which the composition is applied. In the Chemical Formulae 1 to 3, X1, X2, R1 to R4 and L are the same as described in the detailed description.

  本发明公开了一种组合物，该组合物包括由化学式 1 至 3 所代表的相互依次键合的分子组成的第一宿主化合物和由至少一个咔唑基团与具有孔特征的取代基组成的第二宿主化合物，以及应用该组合物的有机光电设备和显示设备。 在化学式 1 至 3 中，X1、X2、R1 至 R4 和 L 与详细说明中所述相同。
• Organic light-emitting device
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US10020459B2

  公开（公告）日：2018-07-10

  An organic light-emitting device includes: a first electrode, a second electrode facing the first electrode, and an organic layer between the first electrode and the second electrode, the organic layer including: an emission layer, an electron transport region between the second electrode and the emission layer, and a mixed layer between the emission layer and the electron transport region, the mixed layer including a first material and a second material, the first material and the second material being selected from a pyrrolidine-based compound and a C10-C30 polycyclicaromatic hydrocarbon-based compound, and a triplet energy EgT1 of at least one selected from the first material and the second material being 2.2 eV or greater.

  一种有机发光器件包括：第一电极、面向第一电极的第二电极以及位于第一电极和第二电极之间的有机层，有机层包括：发射层、位于第二电极和发射层之间的电子传输区域以及位于发射层和电子传输区域之间的混合层：发射层，第二电极和发射层之间的电子传输区，以及发射层和电子传输区之间的混合层，混合层包括第一材料和第二材料，第一材料和第二材料选自吡咯烷基化合物和 C10-C30 多环芳烃基化合物，以及选自第一材料和第二材料的至少一种材料的三重能 EgT1 为 2.2 eV 或更高。
• Organic compound, light-emitting element, light-emitting device, electronic device, and lighting device
  申请人：SEMICONDUCTOR ENERGY LABORATORY CO., LTD.

  公开号：US10263195B2

  公开（公告）日：2019-04-16

  A novel substance with which an increase in life and emission efficiency of a light-emitting element can be achieved is provided. A carbazole compound having a structure represented by General Formula (G1) is provided. Note that a substituent which makes the HOMO level and the LUMO level of a compound in which a bond of the substituent is substituted with hydrogen deep and shallow, respectively is used as each of substituents in General Formula (G1) (R1, R2, Ar3, and α3). Further, a substituent which makes the band gap (Bg) and the T1 level of a compound in which a bond of the substituent is substituted with hydrogen wide and high is used as each of the substituents in General Formula (G1) (R1, R2, Ar3, and α3).

  本发明提供了一种新型物质，利用该物质可提高发光元件的寿命和发射效率。本发明提供了一种具有通式（G1）所示结构的咔唑化合物。需要注意的是，通式（G1）中的每个取代基（R1、R2、Ar3 和 α3）中都使用了能使其键被氢取代的化合物的 HOMO 水平和 LUMO 水平分别变深和变浅的取代基。此外，通式（G1）（R1、R2、Ar3 和 α3）中的每个取代基都使用了能使其键被氢取代的化合物的带隙（Bg）和 T1 电平变宽和变高的取代基。
• COMPOSITION AND ORGANIC OPTOELECTRIC DEVICE AND DISPLAY DEVICE
  申请人：Cheil Industries Inc.

  公开号：EP2821459B1

  公开（公告）日：2017-10-04