4-[2-[2,5-Didecoxy-4-[2-[2,5-didecoxy-4-[2-tri(propan-2-yl)silylethynyl]phenyl]ethynyl]phenyl]ethynyl]benzaldehyde | 1016560-03-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 4-[2-[2,5-Didecoxy-4-[2-[2,5-didecoxy-4-[2-tri(propan-2-yl)silylethynyl]phenyl]ethynyl]phenyl]ethynyl]benzaldehyde
• 英文别名: 4-[2-[2,5-didecoxy-4-[2-[2,5-didecoxy-4-[2-tri(propan-2-yl)silylethynyl]phenyl]ethynyl]phenyl]ethynyl]benzaldehyde
• CAS: 1016560-03-4
• 化学式: C₇₄H₁₁₄O₅Si
• 分子量: 1111.8
• InChiKey: ODSPLDSZONGOJN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  21.95
• 重原子数：
  80
• 可旋转键数：
  50
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.66
• 拓扑面积：
  54
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  对溴苯甲醛 、 4-[2',5'-bis(decyloxy)-4'-ethynylphenylethynyl]-2,5-bis(decyloxy)phenylethynyl-triisopropylsilane 在 bis-triphenylphosphine-palladium(II) chloride 、 copper(l) iodide 、 三乙胺 作用下， 以 四氢呋喃 为溶剂， 以40%的产率得到4-[2-[2,5-Didecoxy-4-[2-[2,5-didecoxy-4-[2-tri(propan-2-yl)silylethynyl]phenyl]ethynyl]phenyl]ethynyl]benzaldehyde
  参考文献：
  名称：

  Synthesis of a Porphyrin-Fullerene Pinwheel

  摘要：

  We disclose the synthesis of a porphyrin-fullerene pinwheel that was subsequently observed by scanning tunneling microscopy. The molecule was designed to further our understanding of fullerene-surface interactions, directional control, and surface-rolling versus pivoting capabilities of this class of nanomachines. The inner porphyrin provides the square planar configuration that might lead to realization of the pinwheel spiraling motion on surfaces.

  DOI：

  10.1021/ol7029917